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a) PTHH: 3H2 + Fe2O3 \(\underrightarrow{T^o}\) 2Fe + 3H2O
n\(Fe_2O_3\) = \(\frac{12}{160}=0,075\left(mol\right)\)
Theo PT: n\(H_2\) = 3n\(Fe_2O_3\) = 3.0,075 = 0,225 (mol)
=> V\(H_2\) = 0,225.22,4 = 5,04(l)
b) Theo PT: nFe = 2n\(Fe_2O_3\) = 2.0,075 = 0,15 (mol)
=> mFe = 0,15.56 = 8,4 (g)
c) PTHH: Zn + 2HCl\(\rightarrow\) ZnCl2 + H2\(\uparrow\)
nZn =\(\frac{22,75}{65}=0,35\left(mol\right)\)
nHCl = \(\frac{29,2}{36,5}=0,8\left(mol\right)\)
Ta có tỉ lệ: \(\frac{n_{Zn}}{1}=\frac{0,35}{1}=0,35< \frac{n_{HCl}}{2}=\frac{0,8}{2}=0,4\)
=> Zn hết, HCl dư
=> Tính số mol các chất cần tìm theo Zn
Theo PT: nHCl = 2nZn = 2.0,35 = 0,7 (mol)
=> nHCl dư = 0,8-0,7 = 0,1 (mol)
=> mHCl dư = 0,1.36,5 = 3,65 (g)
PT: Fe2O3+3H2to→2Fe+3H2O
CuO+H2to→Cu+H2O
a, Ta có: mFe2O3=20.60%=12(g)
⇒nFe2O3=\(\dfrac{12}{160}\)=0,075(mol
mCuO=20−12=8(g
⇒nCuO=\(\dfrac{8}{80}\)=0,1(mol)
Theo pT:
nFe=2nFe2O3=0,15(mol)
nCu=nCuO=0,1(mol)
⇒mFe=0,15.56=8,4(g)
mCu=0,1.64=6,4(g)
b, Theo PT: nH2=3nFe2O3+nCuO=0,325(mol)
⇒VH2=0,325.22,4=7,28(l)
c. Zn+2HCl->ZnCl2+H2
0,65----------0,325
=>m HCl=0,65.36,5=23,725g
\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
a)\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,6 0,3
\(C_M=\dfrac{0,6}{0,4}=1,5M\)
b)\(n_{CuO}=\dfrac{32}{80}=0,4mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,4 0,3 0,3
Sau phản ứng CuO dư và dư \(\left(0,4-0,3\right)\cdot80=8g\)
\(m_{rắn}=m_{Cu}=0,3\cdot64=19,2g\)
1. \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
2. \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
3. Ta có: \(n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\)
PT: \(Fe_3O_4+4H_2\underrightarrow{^{t^o}}3Fe+4H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{4}\), ta được Fe3O4 dư.
Theo PT: \(n_{Fe_3O_4\left(pư\right)}=\dfrac{1}{4}n_{H_2}=0,05\left(mol\right)\Rightarrow n_{Fe_3O_4\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4\left(dư\right)}=0,05.232=11,6\left(g\right)\)
1. \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
2. \(n_{zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PTHH: \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow m_{ZnCl_2}=n_{ZnCl_2}.M_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
\(\Rightarrow n_{H_2}=n_{Zn}=0,2\left(mol\right)\)
3. \(2H_2+Fe_3O_4\rightarrow3Fe+2H_2O\)
2 mol------1 mol------3 mol--2 mol
\(n_{Fe_3O_4}=\dfrac{m_{Fe_3O_4}}{M_{Fe_3O_4}}=\dfrac{23,2}{232}=0,1\left(mol\right)\)
\(\dfrac{n_{Fe_3O_4}}{1}=\dfrac{0,1}{1}\)
\(\dfrac{n_{H_2}}{2}=\dfrac{0,2}{2}\)
\(\dfrac{n_{Fe_3O_4}}{1}=\dfrac{n_{H_2}}{2}\)
Vậy không có chất nào dư cả
a) \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1-------------->0,1------>0,1
\(\Rightarrow m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b) \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c) \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
0,1<---0,1
\(\Rightarrow m_{CuO}=0,1.80=8\left(g\right)\)
a: Zn+2HCl->ZnCl2+H2
0,2 0,4 0,2 0,2
mZnCl2=0,2*136=27,2(g)
b: V=0,2*22,4=4,48(lít)
a, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
c, \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\Rightarrow m_{Fe}=\dfrac{2}{15}.56=\dfrac{112}{15}\left(g\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,2}{3}\), ta được H2 dư.
Theo PT: \(n_{H_2\left(pư\right)}=3n_{Fe_2O_3}=0,12\left(mol\right)\Rightarrow n_{H_2\left(dư\right)}=0,2-0,12=0,08\left(mol\right)\)
\(\Rightarrow m_{H_2\left(dư\right)}=0,08.2=0,16\left(g\right)\)
Theo PT: \(n_{Fe}=2n_{Fe_2O_3}=0,08\left(mol\right)\Rightarrow m_{Fe}=0,08.56=4,48\left(g\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,2\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)
nH2SO4=0,5(mol)
nZn=0,2(mol)
a) PTHH: Zn + H2SO4 -> ZnSO4 + H2
ta có: 0,5/1 > 0,2/1
=> Zn hết, H2SO4 dư, tính theo nZn
b) m(H2SO4 dư)= (0,5-0,2).98=29,4(g)
c) nH2= nZn=0,2(mol)
=>V(H2,đktc)=0,2.22,4=4,48(l)
