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a, PTHH:
H2 + ZnO → Zn + H2O
nZnO = 8,1 / 81 = 0,1 ( mol)
Thep PTHH nH2 = nZnO = 0,1( mol)
nzn = nZnO = 0,1 (mol)
VH2 = 0,1 x 22,4 = 2,24 (l)
b, mZn = 0,1 x 65 = 6,5 (g)
c, Zn + 2HCl → ZnCl2 + H2
mHCl = 200 x 7,3 % = 14,6 ( g)
nHCl = 14,6 / 36,5 = 0,4 ( mol)
Theo PTHH nH2 = 1/2nHCl= 0,4 /2 = 0,2( mol)
VH2 = 0,2 x 22,4 = 4,48( l)
d, y H2 + FexOy → x Fe + yH2O
Theo câu a nH2 = 0,1 ( mol)
Theo PTHH nFexOy= 1/ynH2 = 0,1 /y ( mol)
mFexOy = 0,1/y( 56x + 16y)= 3,24 (g)
đoạn này bạn tự tính nhé!
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\n_{HCl}=0,25\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,25}{2}\) \(\Rightarrow\) HCl còn dư, Kẽm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,1\left(mol\right)\\n_{HCl\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=22,4\cdot0,1=2,24\left(l\right)\\m_{HCl\left(dư\right)}=0,05\cdot36,5=1,825\left(g\right)\end{matrix}\right.\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(n_{HCl}=\dfrac{14,6}{36,5}=0,4mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 < 0,4 ( mol )
0,1 0,2 0,1 0,1 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,4-0,2\right).36,5=7,3g\)
\(V_{H_2}=0,1.22,4=2,24l\)
\(m_{FeCl_2}=0,1.127=12,7g\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\
n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,1}{1}< \dfrac{0,4}{1}\)
=> H2SO4 d
\(n_{H_2SO_4\left(pu\right)}=n_{Fe}=0,1\left(mol\right)\\
m_{H_2SO_4\left(d\right)}=\left(0,4-0,1\right).98=29,4g\)
\(n_{H_2}=n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\)
\(V_{H_2}=0,1.22,4=2,24l\\
m_{FeSO_4}=0,1.152=15,2g\)
a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Ta có: \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Mg}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{Fe_2O_3}=\dfrac{48}{160}=0,3\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,3}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe_2O_3\left(pư\right)}=\dfrac{1}{3}n_{H_2}=0,1\left(mol\right)\Rightarrow n_{Fe_2O_3\left(dư\right)}=0,3-0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,2.160=32\left(g\right)\)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,1.98=9,8\left(g\right)\)
b, \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,5 0 0
0,2 0,4 0,2 0,2
0 0,1 0,2 0,2
Sau phản ứng, axit HCl còn dư và dư \(m=0,1\cdot36,5=3,65g\)
\(m_{ZnCl_2}=0,2\cdot136=27,2g\)
\(V_{H_2}=0,2\cdot22,4=4,48l\)
\(a.n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ b.n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ CuO+H_2-^{t^o}\rightarrow Cu+H_2O\\ LTL:\dfrac{0,15}{1}< \dfrac{0,2}{1}\\ \Rightarrow H_2dưsauphảnứng\\ n_{Cu}=n_{H_2\left(pứ\right)}=n_{H_2O}=n_{CuO}=0,15\left(mol\right)\\ m_{Cu}=0,15.64=9,6\left(g\right)\\ m_{H_2\left(dư\right)}=\left(0,2-0,15\right).2=0,1\left(g\right)\\ m_{H_2O}=0,15.18=2,7\left(g\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,2}{3}\), ta được H2 dư.
Theo PT: \(n_{H_2\left(pư\right)}=3n_{Fe_2O_3}=0,12\left(mol\right)\Rightarrow n_{H_2\left(dư\right)}=0,2-0,12=0,08\left(mol\right)\)
\(\Rightarrow m_{H_2\left(dư\right)}=0,08.2=0,16\left(g\right)\)
Theo PT: \(n_{Fe}=2n_{Fe_2O_3}=0,08\left(mol\right)\Rightarrow m_{Fe}=0,08.56=4,48\left(g\right)\)