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PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\downarrow\)
a+b) Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,2\left(mol\right)=n_{KOH}\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2\cdot36,5}{300}\cdot100\%\approx2,43\%\\C_{M_{KOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)
c) PTHH: \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Theo các PTHH: \(n_{CuO\left(lý.thuyết\right)}=n_{Cu\left(OH\right)_2}=n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow n_{CuO}=0,1\cdot95\%=0,095\left(mol\right)\) \(\Rightarrow m_{CuO}=0,095\cdot80=7,6\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PT: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
a, \(n_{HCl}=6n_{Fe_2O_3}=0,6\left(mol\right)\)
\(\Rightarrow C\%_{HCl}=\dfrac{0,6.36,5}{500}.100\%=4,38\%\)
b, \(n_{FeCl_3}=2n_{Fe_2O_3}=0,2\left(mol\right)\)
PT: \(FeCl_3+3KOH\rightarrow3KCl+Fe\left(OH\right)_{3\downarrow}\)
______0,2_______0,6______________0,2 (mol)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
\(m_{Fe\left(OH\right)_3}=0,2.107=21,4\left(g\right)\)
Đáp án:
m =32,4g
mddH2SO4 = 49g
Giải thích các bước giải:
a) MgCO3 + H2SO4 → MgSO4 + H2O +CO2 ↑
MgSO4 + 2NaOH → Mg(OH)2 + Na2SO4
$Mg{(OH)_2}\buildrel {to} \over
\longrightarrow MgO + {H_2}O$
b) nCO2 = 2,24 : 22,4 = 0,1mol
nMgCO3 = nCO2 = 0,1 mol
nMgO = 12:40=0,3mol
nMgSO4 = nMgO - nMgCO3 = 0,3 - 0,1 = 0,2mol
m = mMgCO3 + mMgSO4
= 0,1 .84+0,2.120=32,4g
nH2SO4 = nCO2 = 0,1 mol
mH2SO4 = 0,1.98=9,8g
mddH2SO4 = 9,8:20.100=49g
chúc bạn học tốt
\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,3mol 0,6mol 0,3mol
\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)
Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)
\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Dung dịch A gồm: CuSO4 và H2SO4 dư
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?
\(a)H_2SO_4+Ba\left(NO_3\right)_2\rightarrow BaSO_4+2HNO_3\\ n_{H_2SO_4}=0,2.1=0,2l\\ n_{Ba\left(NO_3\right)_2}=n_{H_2SO_4}=0,2mol\\ m_{ddBa\left(NO_3\right)_2}=\dfrac{0,2.261}{20}\cdot100=261g\\ V_{ddBa\left(NO_3\right)_2}=\dfrac{261}{1,22}\approx213,9ml\\ c)n_{HNO_3}=0,2.4=0,4mol\\ C_{M_{HNO_3}}=\dfrac{0,4}{0,2+0,2139}\approx0,97M\)
\(n_{H_2}=\dfrac{3,24}{24}=0,135(mol)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{FeSO_4}=0,135(mol)\\ \Rightarrow \begin{cases} C_{M_{H_2SO_4}}=\dfrac{0,135}{0,2}=0,675M\\ C_{M_{FeSO_4}}=\dfrac{0,135}{0,2}=0,675M \end{cases}\)
a) 2NaOH + H2SO4 -- Na2SO4 + 2H2O
b) \(n_{NaOH}=\dfrac{100.20}{100.40}=0,5\left(mol\right)\)
PTHH: 2NaOH + H2SO4 -- Na2SO4 + 2H2O
______0,5----->0,25------>0,25
=> mH2SO4 = 0,25.98 = 24,5 (g)
=> \(m_{ddH_2SO_4}=\dfrac{24,5.100}{19,6}=125\left(g\right)\)
c) mNa2SO4 = 0,25.142 = 35,5 (g)
mdd sau pư = 100 + 125 = 225 (g)
=> \(C\%\left(Na_2SO_4\right)=\dfrac{35,5}{225}.100\%=15,778\%\)
