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a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{H_2SO_4} = n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)$
$V = 0,3.22,4 = 6,72(lít)$
$C_{M_{H_2SO_4}} = \dfrac{0,3}{0,25} = 1,2M$
b)
$n_{CuO} = \dfrac{16}{80} = 0,2(mol)$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$n_{CuO} < n_{H_2}$ nên $H_2$ dư
$n_{Cu} = n_{CuO} = 0,2(mol)$
$m_{Cu} = 0,2.64 = 12,8(gam)$
\(n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ PT:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,3 0,3 0,3 (mol)
a) V= n. 22,4 = 0,3 . 22,4 = 6,72(l)
\(C\%=\dfrac{m_{H_2SO_4}}{m_{dd}}.100\%=\dfrac{0,3.98}{200}.100\%=11,76\%\)
b) PT: \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
0,3 0,3
=> mCu=n.M=0,3.64=19,2(g)
\(n_{Al}=\dfrac{16,2}{27}=0,6\left(mol\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ 0,6........0,9...........0,3........0,9\left(mol\right)\\ a.V_{H_2\left(đktc\right)}=0,9.22,4=20,16\left(l\right)\\ b.C_{MddH_2SO_4}=\dfrac{0,9}{0,5}=1,8\left(M\right)\\ c.C_{MddX}=C_{MddAl_2\left(SO_4\right)_3}=\dfrac{0,3}{0,5}=0,6\left(M\right)\)
a,\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1 0,1 0,1
b,\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c,\(C_{M_{ddH_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
d,\(C_{M_{ddFeSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ a,Zn+2HCl\to ZnCl_2+H_2\\ \Rightarrow n_{Zn}=0,15(ml);n_{HCl}=0,3(mol)\\ a,m_{Zn}=0,15.65=9,75(g)\\ b,C_{M_{HCl}}=\dfrac{0,3}{0,1}=3M\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1 0,1 0,1
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(C_{M_{ddH_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ddFeSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(n_{Fe}=\dfrac{1,12}{56}=0,02\left(mol\right)\)
\(n_{H2SO4}=0,05.1=0,05\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a) Xét tỉ lệ : \(0,02< 0,05\Rightarrow H2SO4dư\)
Theo Pt : \(n_{FeSO4}=n_{H2}=n_{Fe}=0,02\left(mol\right)\)
\(\Rightarrow V_{H2\left(dktc\right)}=0,02.22,4=0,448\left(l\right)\)
b) \(n_{H2SO4\left(dư\right)}=0,05-0,02=0,03\left(mol\right)\)
\(V_{ddH2SO4\left(dư\right)}=\dfrac{0,03}{1}=0,03\left(l\right)=30\left(ml\right)\)
c) \(C_{MFeSO4}=\dfrac{0,02}{0,05}=0,4\left(M\right)\)
\(C_{MH2SO4\left(dư\right)}=\dfrac{\left(0,05-0,02\right)}{0,05}=0,6\left(M\right)\)
Chúc bạn học tốt
Cậu sửa lại giúp tớ câu b) :
\(n_{H2SO4\left(pư\right)}=n_{Fe}=0,02\left(mol\right)\)
\(V_{H2SO4\left(pư\right)}=\dfrac{0,02}{1}=0,02\left(l\right)=20\left(ml\right)\)
\(n_{H_2}=\dfrac{3,24}{24}=0,135(mol)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{FeSO_4}=0,135(mol)\\ \Rightarrow \begin{cases} C_{M_{H_2SO_4}}=\dfrac{0,135}{0,2}=0,675M\\ C_{M_{FeSO_4}}=\dfrac{0,135}{0,2}=0,675M \end{cases}\)