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\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1 0,1 0,1
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(C_{M_{ddH_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ddFeSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(n_{H_2}=\dfrac{3,24}{24}=0,135(mol)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{FeSO_4}=0,135(mol)\\ \Rightarrow \begin{cases} C_{M_{H_2SO_4}}=\dfrac{0,135}{0,2}=0,675M\\ C_{M_{FeSO_4}}=\dfrac{0,135}{0,2}=0,675M \end{cases}\)
a)
Gọi $n_{Fe} = a(mol) ; n_{Al} =b (mol) \Rightarrow 56a + 27b = 11(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : $n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,1 ; b = 0,2
$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,9\%$
$\%m_{Al} = 100\% - 50,9\% = 49,1\%$
b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,8}{0,4} = 2M$
c)
$C_{M_{FeCl_2}} = \dfrac{0,1}{0,4} = 0,25M$
$C_{M_{AlCl_3}} =\dfrac{0,2}{0,4} = 0,5M$
nAl = 5.4/27 = 0.2 (mol)
2Al + 3H2SO4 => Al2(SO4)3 + 3H2
0.2____0.3_________________0.3
VH2 = 0.3*22.4 = 6.72(l)
CM H2SO4 = 0.3/0.1 = 3 M
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow n_{H_2}=0,3mol=n_{H_2SO_4}\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{H_2SO_4}}=\dfrac{0,3}{0,1}=3\left(M\right)\end{matrix}\right.\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,3\left(mol\right)\\n_{ZnCl_2}=0,15\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{ZnCl_2}=0,15\cdot136=20,4\left(g\right)\\C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
$n_{H_2SO_4} = n_{H_2} = n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)$
$V = 0,3.22,4 = 6,72(lít)$
$C_{M_{H_2SO_4}} = \dfrac{0,3}{0,25} = 1,2M$
b)
$n_{CuO} = \dfrac{16}{80} = 0,2(mol)$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$n_{CuO} < n_{H_2}$ nên $H_2$ dư
$n_{Cu} = n_{CuO} = 0,2(mol)$
$m_{Cu} = 0,2.64 = 12,8(gam)$
\(n_{Fe}=\dfrac{m}{M}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ PT:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,3 0,3 0,3 (mol)
a) V= n. 22,4 = 0,3 . 22,4 = 6,72(l)
\(C\%=\dfrac{m_{H_2SO_4}}{m_{dd}}.100\%=\dfrac{0,3.98}{200}.100\%=11,76\%\)
b) PT: \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)
0,3 0,3
=> mCu=n.M=0,3.64=19,2(g)
a, Ta có: 27nAl + 56nFe = 27,8 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Fe}=0,4\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%\approx19,42\%\\\%m_{Fe}\approx80,58\%\end{matrix}\right.\)
b, \(n_{H_2SO_4}=n_{H_2}=0,7\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,7}{0,5}=1,4\left(M\right)\)
đề bài sai ko có giá trị m