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\(Fe_2O_3 + 6HCl \rightarrow 2FeCl_3 + 3H_2O\)
\(CuO + 2HCl \rightarrow CuCl_2 + H_2O\)
\(NaOH + HCl \rightarrow NaCl + H_2O\)
\(n_{NaOH} = 0,2 . 1 = 0,2 mol\)
\(n_{HCl dư} = n_{NaOH}= 0,2 mol\)
\(\Rightarrow n_{HCl pư}= n_{HCl ban đầu} - n_{HCl dư}= 1,4- 0,2 = 1,2 mol\)
Gọi n\(Fe_2O_3\) và n\(CuO\) là x, y
\(\begin{cases} 160x + 80y=40\\ 6x + 2y= 1,2 \end{cases} \)
\(\begin{cases} x=0,1\\ y=0,3 \end{cases} \)
\(\Rightarrow m_{Fe_2O_3}= 0,1 . 160= 16g\)
\(m_{CuO} = 0,3 . 80=24g\)
a. PTHH: Cu + HCl ---x--->
Zn + 2HCl ---> ZnCl2 + H2 (1)
b. Đổi 100ml = 0,1 lít
Ta có: \(C_{M_{HCl}}=\dfrac{n_{HCl}}{0,1}=3M\)
=> nHCl = 0,3(mol)
Theo PT(1): \(n_{Zn}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.0,3=0,15\left(mol\right)\)
=> mZn = 65 . 0,15 = 9,75(g)
=> mCu = 12,1 - 9,75 = 2,35(g)
=> \(\%_{m_{Zn}}=\dfrac{9,75}{12,1}.100\%=80,6\%\)
\(\%_{m_{Cu}}=100\%-80,6\%=19,4\%\)
c. PTHH: Cu + H2SO4 ---x--->
Zn + H2SO4 ---> ZnSO4 + H2 (2)
Theo PT(2): \(n_{Zn}=n_{H_2SO_4}=0,15\left(mol\right)\)
=> \(m_{H_2SO_4}=0,15.98=14,7\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{14,7}{m_{dd_{H_2SO_4}}}.100\%=20\%\)
=> \(m_{dd_{H_2SO_4}}=73,5\left(g\right)\)
a) Đặt nAl=a(mol) ; nFe=b(mol) (a,b>0)
nHCl= (365.12%)/36,5=1,2(mol)
PTHH: 2Al + 6 HCl -> 2AlCl3 +3 H2
a________3a_________2a____1,5a(mol)
Fe + 2 HCl -> FeCl2 + H2
b_____2b____b____b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}27a+56b=22,2\\3a+2b=1,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\)
b) => %mAl= [(0,2.27)/22,2].100=24,324%
=>%mFe= 75,676%
c) mFeCl2=127. 0,3=38,1(g)
mAlCl3= 133,5. 0,2= 26,7(g)
mddsau= 22,2+365 - 1,2.2=384,8(g)
=>C%ddFeCl2= (38,1/384,8).100=9,901%
C%ddAlCl3= (26,7/384,8).100=6,939%
\(a)n_{HCl}=0,2.1,5=0,3mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}2n_{CaO}+2n_{CuO}=0,3\\56n_{CaO}+80n_{CuO}=10,8\end{matrix}\right.\\ \Rightarrow n_{CaO}=n_{CaCl_2}=0,05mol;n_{CuO}=n_{CuCl_2}=0,1mol\\ \%m_{CaO}=\dfrac{0,05.56}{10,8}\cdot100=25,93\%\\ \%m_{CuO}=100-25,93=74,07\%\\ b)C_{M_{CaCl_2}}=\dfrac{0,05}{0,2}=0,25M\\ C_{M_{CuCl_2}}=\dfrac{0,1}{0,2}=0,5M\)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
x 2x x x
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
y 2y y y
\(\left\{{}\begin{matrix}56x+80y=10,8\\2x+2y=0,2.1,5=0,3\end{matrix}\right.\)
\(\Rightarrow x=0,05;y=0,1\)
\(a,\%m_{CaO}=0,05.56:10,8.100\%=25,93\left(\%\right)\)
\(\%m_{CuO}=100\%-25,93\%=74,07\%\)
\(b,C_{M\left(CaCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(C_{M\left(CuCl_2\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
\(n_{HCl}=3.0,2=0,6(mol)\\ PTHH:Fe_2O_3+6HCl\to 2FeCl_3+3H_2O\\ \Rightarrow n_{Fe_2O_3}=\dfrac{1}{6}n_{HCl}=0,1(mol)\\ \Rightarrow m_{Fe_2O_3}=0,1.160=16(g)\\ \Rightarrow \%_{Fe_2O_3}=\dfrac{16}{20}.100\%=80\%\\ \Rightarrow \%_{Cu}=100\%-80\%=20\%\)
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
b) Ta có: \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,1mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
c) Theo PTHH: \(n_{Zn}=n_{H_2}=0,05mol\)
\(\Rightarrow m_{Zn}=0,05\cdot65=3,25\left(g\right)\)
\(\Rightarrow\%m_{Zn}=\dfrac{3,25}{8,37}\cdot100\%\approx38,83\%\) \(\Rightarrow\%m_{Cu}=61,17\%\)
\(a,PTHH:CuO+2HCl\to CuCl_2+H_2O\\ b,n_{HCl}=0,2.1=0,2(mol)\\ \Rightarrow n_{CuO}=0,2(mol)\Rightarrow m_{CuO}=0,2.80=16(g)\\ \Rightarrow \%_{CuO}=\dfrac{16}{20,8.}100\%=76,92\%\\ \Rightarrow \%_{Cu}=100\%-76,92\%=23,08\%\)