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Sửa đề: 3,785 (l) → 3,7185 (l)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)
c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)
Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)
d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)
e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)
Câu 1:
a) CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
CaO + 2HCl --> CaCl2 + H2O
b)
\(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
PTHH: CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
_____0,4<---------0,8<-----------------0,4
=> mCaCO3 = 0,4.100 = 40(g)
=> mCaO = 62,4 - 40 = 22,4 (g)
c) \(n_{CaO}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
CaO + 2HCl --> CaCl2 + H2O
_0,4-->0,8
=> nHCl = 0,8 + 0,8 = 1,6(mol)
=> \(C_{M\left(HCl\right)}=\dfrac{1,6}{0,25}=6,4M\)
Câu 1:
\(a,CaO+2HCl\to CaCl_2+H_2O\\ CaCO_3+2HCl\to CaCl_2+H_2O+CO_2\uparrow\\ b,n_{CO_2}=\dfrac{8,96}{22,4}=0,4(mol)\\ \Rightarrow n_{CaCO_3}=0,4(mol)\\ \Rightarrow m_{CaCO_3}=0,4.100=40(g)\\ \Rightarrow m_{CaO}=62,4-40=22,4(g)\\ c,n_{CaO}=\dfrac{22,4}{56}=0,4(mol)\\ \Rightarrow \Sigma n_{HCl}=0,4.2+0,4.2=1,6(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{1,6}{0,25}=6,4M\)
Câu 2: Đề thiếu
a) nH2=0,2(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,2______0,4_______0,2_____0,2(mol)
PTHH: MgO +2 HCl -> MgCl2 + H2O
b) mMgO= 8,8 - 0,2.24=4(g)
%mMgO= (4/8,8).100= 45,455%
=>%Mg=54,545%
c) nHCl(tổng)= 2. nMg + 2. nMgO= 2. 0,2+ 0,1.2=0,6(mol)
=> mHCl= 0,6.36,5=21,9(g)
=>mddHCl=(21,9.100)/7,3=300(g)
d) mddMgCl2= mddHCl + m(hỗn hợp ban đầu) - mH2
<=>mddHCl= 300+ 8,8- 0,2.2= 308,4(g)
nMgCl2=0,3(mol) => mMgCl2= 0,3.95=28,5(g)
=>C%ddMgCl2= (28,5/308,4).100=9,241%
a. PTHH: Cu + HCl ---x--->
Zn + 2HCl ---> ZnCl2 + H2 (1)
b. Đổi 100ml = 0,1 lít
Ta có: \(C_{M_{HCl}}=\dfrac{n_{HCl}}{0,1}=3M\)
=> nHCl = 0,3(mol)
Theo PT(1): \(n_{Zn}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.0,3=0,15\left(mol\right)\)
=> mZn = 65 . 0,15 = 9,75(g)
=> mCu = 12,1 - 9,75 = 2,35(g)
=> \(\%_{m_{Zn}}=\dfrac{9,75}{12,1}.100\%=80,6\%\)
\(\%_{m_{Cu}}=100\%-80,6\%=19,4\%\)
c. PTHH: Cu + H2SO4 ---x--->
Zn + H2SO4 ---> ZnSO4 + H2 (2)
Theo PT(2): \(n_{Zn}=n_{H_2SO_4}=0,15\left(mol\right)\)
=> \(m_{H_2SO_4}=0,15.98=14,7\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{14,7}{m_{dd_{H_2SO_4}}}.100\%=20\%\)
=> \(m_{dd_{H_2SO_4}}=73,5\left(g\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (2)
a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)
c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)
\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)
Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)
\(a.n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ Đặt:\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ \rightarrow\left\{{}\begin{matrix}27a+24b=5,1\\1,5a+b=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \left\{{}\begin{matrix}\%m_{Al}=\dfrac{27.0,1}{5,1}.100\approx52,941\%\\\%m_{Mg}\approx47,059\%\end{matrix}\right.\)
\(b.m_{ddH_2SO_4}=\dfrac{0,25.98.100}{9,8}=250\left(g\right)\\ m_{ddsau}=m_{Al,Mg}+m_{ddH_2SO_4}-m_{H_2}=5,1+250-0,25.2=254,6\left(g\right)\\ C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342}{254,6}.100\approx6,716\%\\ C\%_{ddMgSO_4}=\dfrac{0,1.120}{254,6}.100\approx4,713\%\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
2a______3a__________a_______3a (mol)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
b_______b________b______b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}27\cdot2a+24b=7,8\\3a+b=\dfrac{200\cdot19,6\%}{98}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,1\cdot24=2,4\left(g\right)\\m_{Al}=5,4\left(g\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)=n_{MgSO_4}\\n_{H_2}=0,4\left(mol\right)\Rightarrow m_{H_2}=0,4\cdot2=0,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=207\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1\cdot342}{207}\cdot100\%\approx16,52\%\\C\%_{MgSO_4}=\dfrac{0,1\cdot120}{207}\cdot100\%\approx5,8\%\end{matrix}\right.\)
a) Đặt nAl=a(mol) ; nFe=b(mol) (a,b>0)
nHCl= (365.12%)/36,5=1,2(mol)
PTHH: 2Al + 6 HCl -> 2AlCl3 +3 H2
a________3a_________2a____1,5a(mol)
Fe + 2 HCl -> FeCl2 + H2
b_____2b____b____b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}27a+56b=22,2\\3a+2b=1,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\)
b) => %mAl= [(0,2.27)/22,2].100=24,324%
=>%mFe= 75,676%
c) mFeCl2=127. 0,3=38,1(g)
mAlCl3= 133,5. 0,2= 26,7(g)
mddsau= 22,2+365 - 1,2.2=384,8(g)
=>C%ddFeCl2= (38,1/384,8).100=9,901%
C%ddAlCl3= (26,7/384,8).100=6,939%