Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Ta có \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(m_{NaOH}=100.16\%=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Theo PT: \(n_{Na}=2n_{H_2}=0,2\left(mol\right)\)
\(n_{NaOH}=n_{Na}+2n_{Na_2O}\Rightarrow n_{Na_2O}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na}=\dfrac{0,2.23}{0,2.23+0,1.62}.100\%\approx42,6\%\\\%m_{Na_2O}\approx57,4\%\end{matrix}\right.\)
\(n_{BaSO_4}=\dfrac{23.3}{233}=0.1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4+H_2O\)
\(n_{BaO}=n_{Ba\left(OH\right)_2}=n_{BaSO_4}=0.1\left(mol\right)\)
\(m_{BaO}=0.1\cdot153=15.3\left(g\right)\)
\(m_{Na_2O}=24.6-15.3=9.3\left(g\right)\)
\(n_{Na_2O}=\dfrac{9.3}{62}=0.15\left(mol\right)\)
\(\%BaO=62.2\%\)
\(\%Na_2O=37.8\%\)
\(2.\)
\(m_{ddX}=24.6+73.7=98.3\left(g\right)\)
\(n_{H_2SO_4}=\dfrac{0.15}{2}+0.1=0.175\left(mol\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{0.175\cdot98\cdot100}{19.6}=87.5\left(g\right)\)
\(m_{ddY}=m_{ddX}+m_{ddH_2SO_4}-m_{\downarrow}=98.3+87.5-23.3=162.5\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{0.075\cdot142}{162.5}\cdot100\%=6.55\%\)
PTHH :
\(Na_2O+H_2O\rightarrow2NaOH\)
0,04 0,08
\(n_{NaOH}=0,2.0,4=0,08\left(mol\right)\)
\(m_{Na_2O}=0,04.62=2,48\left(g\right)\)
Do CuO ko tác dụng với H2O nên 4gam chất rắn = KL CuO
Ta có :
m = 2,48 + 4 = 6,48 (g)
Coi hỗn hợp kim loại trên là R có hóa trị n
\(4R + nO_2 \xrightarrow{t^o} 2R_2O_n\\ m_{O_2} = 17-10,2 = 6,8(gam) \Rightarrow n_{O_2} = \dfrac{6,8}{32} = 0,2125(mol)\\ n_R = \dfrac{4}{n}n_{O_2} = \dfrac{0,85}{n}(mol)\\ 2R + 2nHCl \to 2RCl_n + nH_2\\ n_{H_2} = \dfrac{n}{2}n_R = 0,425(mol)\\ \Rightarrow V = 0,425.22,4 = 9,52(lít)\\ n_{HCl} = 2n_{H_2} = 0,85(mol)\\ \text{Bảo toàn khối lượng : }\\ m_{muối} = m_{kim\ loại} + m_{HCl} - m_{H_2} = 10,2 + 0,85.36,5 - 0,425.2 = 40,375(gam)\)
\(n_{Mg\left(OH\right)_2}=a\left(mol\right)\)
\(n_{Fe\left(OH\right)_3}=b\left(mol\right)\)
\(m_{hh}=58a+107b=16.9\left(g\right)\left(1\right)\)
\(Mg\left(OH\right)_2\underrightarrow{^{^{t^0}}}MgO+H_2O\)
\(a.............a\)
\(2Fe\left(OH\right)_3\underrightarrow{^{^{t^0}}}Fe_2O_3+3H_2O\)
\(b.............\dfrac{b}{2}\)
\(m_{Cr}=40a+160\cdot\dfrac{b}{2}=12.4\left(g\right)\left(1\right)\)
\(\left(1\right),\left(2\right):a=0.07,b=0.12\)
\(\%m_{Mg\left(OH\right)_2}=\dfrac{0.07\cdot40}{16.9}\cdot100\%=16.57\%\)
\(\%m_{Fe\left(OH\right)_3}=83.43\%\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
80 gam dung dịch A chứa 3,52 gam NaOH
=> 200 gam dung dịch A chứa 3,52.200/80 = 8,8 gam
n NaOH = 8,8/40 = 0,22(mol)
Gọi n Na = a(mol) ; n Na2O = b(mol)
=> 23a + 62b = 6,02(1)
$2Na + 2H_2O \to 2NaOH + H_2$
$Na_2O + H_2O \to 2NaOH$
n NaOH = a + 2b = 0,22(2)
Từ (1)(2) suy ra a= 0,1 ; b = 0,06
n H2 = 0,5a = 0,05(mol)
=> m H2O = 200 + 0,05.2 - 6,02 =194,08(gam)
%m Na = 0,1.23/6,02 .100% = 38,2%
%m Na2O = 100% -38,2% = 61,8%