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Đặt \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Zn}=2a\left(mol\right)\\n_{Fe}=3a\left(mol\right)\end{matrix}\right.\)
Ta có: \(m_{t\text{ăng}}=m_{KL}-m_{H_2}\)
\(\Rightarrow m-m_{H_2}=m-2,4\\ \Leftrightarrow m_{H_2}=2,4\left(g\right)\Rightarrow n_{H_2}=\dfrac{2,4}{2}=1,2\left(mol\right)\)
PTHH:
`Mg + 2HCl -> MgCl_2 + H_2`
`Zn + 2HCl -> ZnCl_2 + H_2`
`Fe + 2HCl -> FeCl_2 + H_2`
Theo PTHH:
\(n_{H_2}=n_{Mg}+n_{Zn}+n_{Fe}=a+2a+3a=6a\left(mol\right)\\ \Rightarrow6a=1,2\Leftrightarrow a=0,2\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,2\left(mol\right)\\n_{Zn}=0,2.2=0,4\left(mol\right)\\n_{Fe}=0,2.3=0,6\left(mol\right)\end{matrix}\right.\)
Vậy \(m=0,2.24+0,4.65+0,6.56=64,4\left(g\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\x_{Ca}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}24x+40y=17,6\\x=2y\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,4\\y=0,2\end{matrix}\right.\)
a)\(m_{Mg}=0,4\cdot24=9,6g\)
\(m_{Ca}=0,2\cdot40=8g\)
b)\(2Mg+O_2\underrightarrow{t^o}2MgO\)
\(2Ca+O_2\underrightarrow{t^o}2CaO\)
Từ hai pt: \(\Rightarrow\Sigma n_{O_2}=\dfrac{1}{2}n_{Mg}+\dfrac{1}{2}n_{Ca}=\dfrac{1}{2}\cdot0,4+\dfrac{1}{2}\cdot0,2=0,3mol\)
\(\Rightarrow m_{O_2}=0,3\cdot32=9,6g\)
\(V_{O_2}=0,3\cdot22,4=6,72l\)
\(\Rightarrow V_{kk}=5V_{O_2}=5\cdot6,72=33,6l\)
a)
Có \(\left\{{}\begin{matrix}24.n_{Mg}+40.n_{Ca}=17,6\\n_{Mg}=2.n_{Ca}\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Ca}=0,2\left(mol\right)\\n_{Mg}=0,4\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}m_{Ca}=0,2.40=8\left(g\right)\\m_{Mg}=0,4.24=9,6\left(g\right)\end{matrix}\right.\)
b)
PTHH: 2Ca + O2 --to--> 2CaO
0,2-->0,1
2Mg + O2 --to--> 2MgO
0,4--->0,2
=> \(V_{O_2}=\left(0,1+0,2\right).22,4=6,72\left(l\right)\)
\(V_{kk}=6,72.5=33,6\left(l\right)\)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\) (1)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\) (2)
a) Gọi số mol của Mg là a (mol) \(\Rightarrow n_{Al}=\dfrac{2}{3}a\left(mol\right)\)
\(\Rightarrow24a+27\cdot\dfrac{2}{3}a=6,3\) \(\Rightarrow a=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{MgO}=0,15\left(mol\right)\\n_{Al_2O_3}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgO}=0,15\cdot40=6\left(g\right)\\m_{Al_2O_3}=0,05\cdot102=5,1\left(g\right)\end{matrix}\right.\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,075\left(mol\right)\\n_{O_2\left(2\right)}=0,075\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{O_2}=0,15\left(mol\right)\) \(\Rightarrow V_{O_2}=0,15\cdot22,4=3,36\left(l\right)\)
Gọi số mol Al, Na trong a gam hỗn hợp là x, y (mol)
=> 27x + 23y = a (1)
PTHH: 4Al + 3O2 --to--> 2Al2O3
x---------------->0,5x
4Na + O2 --to--> 2Na2O
y---------------->0,5y
=> 102.0,5x + 62.0,5y = 1,64.a
=> 51x + 31y = 1,64a (2)
(1)(2) => 51x + 31y = 1,64(27x + 23y)
=> 6,72x = 6,72y
=> x = y
\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{27x}{27x+23y}.100\%=54\%\\\%m_{Na}=\dfrac{23y}{27x+23y}.100\%=46\%\end{matrix}\right.\)
PTHH: \(Mg+\dfrac{1}{2}O_2\xrightarrow[]{t^o}MgO\)
\(Cu+\dfrac{1}{2}O_2\xrightarrow[]{t^o}CuO\)
Theo đề bài: \(m_{tăng}=32\left(g\right)=m_{O_2\left(p.ứ\right)}\)
Bảo toàn khối lượng: \(m_{oxit\:}=m_{KL}+m_{O_2}=120\left(g\right)\)
\(\Rightarrow m_{MgO}=\dfrac{120}{3}=40\left(g\right)\) \(\Rightarrow m_{CuO}=80\left(g\right)\)
a, \(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(2Mg+O_2\underrightarrow{t^o}2MgO\)
b, \(\dfrac{m_{CuO}}{m_{MgO}}=\dfrac{2}{1}\Rightarrow\dfrac{n_{CuO}}{n_{MgO}}=\dfrac{2}{1}:\dfrac{80}{40}=1\)
⇒ nCuO = nMgO (1)
Có: m chất rắn tăng = mO2 = 32 (g)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{CuO}+\dfrac{1}{2}n_{MgO}=\dfrac{32}{32}=1\left(mol\right)\left(2\right)\)
Từ (1) và (2) ⇒ nCuO = nMgO = 1 (mol)
⇒ mCuO = 1.80 = 80 (g)
mMgO = 1.40 = 40 (g)