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\(a.2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ b.n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\\ n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\\ \Rightarrow CM_{H_2SO_4}=\dfrac{0,25}{0,1}=2,5M\\ c.n_{Na_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\\ \Rightarrow m_{Na_2SO_4}=0,25.142=35,5\left(g\right)\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1 0,1 0,1
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(C_{M_{ddH_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ddFeSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
Bài 2 :
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH :
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1 0,3
\(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
\(b,V_{ddH_2SO_4}=\dfrac{0,3}{2}=0,15\left(l\right)\)
\(c,C_{M\left(Fe_2\left(SO_4\right)_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\)
Bài 3 :
\(n_{Mg}=\dfrac{4.8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2O\)
0,2 0,2 0,2 0,2
\(m_{MgSO_4}=0,2.120=24\left(g\right)\)
\(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(c,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(d,C_{M\left(MgSO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Bài 4 :
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
PTHH :
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
0,3 0,45 0,15 0,45
\(V_{H_2}=0,45.24,79=11,1555\left(l\right)\)
\(m_{H_2SO_4}=0,45.98=44,1\left(g\right)\)
\(C\%_{H_2SO_4}=\dfrac{44,1}{300}.100\%=14,7\%\)
\(m_{Al_2\left(SO_4\right)_3}=0,15.342=51,3\left(g\right)\)
\(m_{dd}=8,1+300-\left(0,45.2\right)=307,2\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{51,3}{307,2}.100\%\approx16,7\%\)
Bài 5 :
\(n_{H_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(C_{M\left(HCl\right)}=\dfrac{0,4}{0,2}=2\left(M\right)\)
\(C_{M\left(FeCl_2\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(a,n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\\ PTHH:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(b,\) Theo PT: \(n_{H_2}=n_{Mg}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2\left(đktc\right)}=0,3\cdot22,4=6,72\left(l\right)\)
\(c,n_{H_2SO_4}=n_{Mg}=0,3\left(mol\right)\\ \Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5M\)
Ta có: \(n_{SO_3}=\dfrac{8}{80}=0,1\left(mol\right)\)
a. PTHH: SO3 + H2O ---> H2SO4 (1)
b. Theo PT(1): \(n_{H_2SO_4}=n_{SO_3}=0,1\left(mol\right)\)
Đổi 250ml = 0,25 lít
=> \(C_{M_{H_2SO_4}}=\dfrac{0,1}{0,25}=0,4\left(M\right)\)
c. PTHH: H2SO4 + 2KOH ---> K2SO4 + 2H2O
Theo PT(2): \(n_{KOH}=2.n_{H_2SO_4}=2.0,1=0,2\left(mol\right)\)
=> \(m_{KOH}=0,2.56=11,2\left(g\right)\)
Ta có: \(C_{\%_{KOH}}=\dfrac{11,2}{m_{dd_{KOH}}}.100\%=5,6\%\)
=> \(m_{dd_{KOH}}=200\left(g\right)\)
Ta có: \(d_{KOH}=\dfrac{200}{V_{dd_{KOH}}}=1,045\)(g/ml)
=> \(V_{dd_{KOH}}=191,4\left(ml\right)\)
a, \(n_{Na_2O}=\dfrac{7,75}{62}=0,125\left(mol\right)\)
PTHH: Na2O + H2O → 2NaOH
Mol: 0,125 0,25
b, \(C_{M_{ddNaOH}}=\dfrac{0,25}{0,25}=1M\)
c,
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,25 0,125
\(m_{ddH_2SO_4}=\dfrac{0,125.98.100}{20}=61,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,14}=53,728\left(ml\right)\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ 0,2........0,3...........0,1...........0,3\left(mol\right)\\ a.C_{MddH_2SO_4}=\dfrac{0,3}{0,3}=1\left(M\right)\\ b.m_{Al_2\left(SO_4\right)_3}=342.0,1=34,2\left(g\right)\\ c.V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,3}=1M\)
b) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\)
\(\Rightarrow m_{Al_2\left(SO_4\right)_3}=n.M=0,1.342=34,2\left(g\right)\)
c) \(n_{H_2}=n_{H_2SO_4}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)
\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)
a) $Fe + H_2SO_4 \to FeSO_4 + H_2$
b) Theo PTHH : $n_{H_2SO_4} = n_{Fe} = \dfrac{8,4}{56} = 0,15(mol)$
$C_{M_{H_2SO_4}} = \dfrac{0,15}{0,05} = 3M$