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Gọi kim loại cần tìm là R
n Ba(OH)2 = 0,2(mol)
=> n BaCl2 = 0,2(mol)
=> m RCl = 65 - 0,2.208 = 23,4(gam)
Mặt khác :
n R = n RCl
<=> 9,2/R = 23,4/(R + 35,5)
<=> R = 23(Natri)
n H2 = 1/2 n Na = 0,2(mol)
n HCl dư = 2 n Ba(OH)2 = 0,4(mol)
n HCl đã dùng = n NaCl + n HCl dư = 0,4 + 0,4 = 0,8(mol)
=> m dd HCl = 0,8.36,5/14,6% = 200(gam)
=> m dd A = 9,2 + 200 - 0,2.2 = 208,8(gam)
C% HCl = 0,4.36,5/208,8 .100% = 7%
C% NaCl = 23,4/208,8 .100% = 11,2%
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
Sửa thành 2,24 gam cho số đẹp bạn nhé!
Ta có: \(n_{Fe}=\dfrac{2,24}{56}=0,04\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
___0,04__0,08____0,04__0,04 (mol)
Ta có: \(m_{HCl}=0,08.36,5=2,92\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{2,92}{14,6\%}=20\left(g\right)\)
Ta có: m dd sau pư = mFe + m dd HCl - mH2 = 2,24 + 20 - 0,04.2 = 22,16 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{0,04.127}{22,16}.100\%\approx22,9\%\)
Bạn tham khảo nhé!
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.24,79=4,958\left(l\right)\)
b, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow V_{HCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)
c, \(C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(a,V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(b,m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{10}=146\left(g\right)\)
\(c,m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(m_{ddMgCl_2}=4,8+146-\left(0,2.2\right)=150,4\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{150,4}.100\%\approx12,63\%\)
2.
\(n_K=\dfrac{7,8}{39}=0,2\left(mol\right)\)
\(2K+2H_2O\rightarrow2KOH+H_2\uparrow\)
0,2 0,2 0,1
\(m_{KOH}=0,2.56=11,2\left(g\right)\)
\(m_{ddKOH}=7,8+100-\left(0,1.2\right)=107,6\left(g\right)\)
\(C\%=\dfrac{11,2}{107,6}.100\%\approx10,4\%\)
\(n_{Mg}=\dfrac{4.8}{24}=0.2\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.2.....................0.2..........0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng }}=4.8+250-0.2\cdot2=254.4\left(g\right)\)
\(m_{MgCl_2}=0.2\cdot95=19\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{254.4}\cdot100\%=7.47\%\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
____0,2____0,4______0,2____0,2 (mol)
b, \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, Ta có: m dd sau pư = mMg + m dd HCl - mH2 = 4,8 + 250 - 0,2.2 = 254,4 (g)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{0,2.95}{254,4}.100\%\approx7,47\%\)
Bạn tham khảo nhé!
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
\(n_{Mg}=\dfrac{7.2}{24}=0.3\left(mol\right)\)
\(n_{HCl}=\dfrac{200\cdot14.6\%}{36.5}=0.8\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.3.........0.6.........0.3..........0.3\)
\(n_{HCl\left(dư\right)}=0.8-0.6=0.2\left(mol\right)\)
\(KOH+HCl\rightarrow KCl+H_2O\)
\(0.2........0.2\)
\(V_{dd_{KOH}}=\dfrac{0.2}{2}=0.1\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=7.2+200-0.3\cdot2=206.6\left(g\right)\)
\(m_{MgCl_2}=0.3\cdot95=28.5\left(g\right)\)
\(C\%MgCl_2=\dfrac{28.5}{206.6}\cdot100\%=13.8\%\)
\(C\%HCl\left(dư\right)=\dfrac{0.2\cdot36.5}{206.6}\cdot100\%=3.53\%\)