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\(V_{O_2\left(thu.được\right)}=28=0,1=2,8\left(l\right)\)
=> \(V_{O_2\left(sinh.ra\right)}=\dfrac{2,8.100}{80}=3,5\left(l\right)\)
=> \(n_{O_2\left(sinh.ra\right)}=\dfrac{3,5}{22,4}=0,15625\left(mol\right)\)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,3125<------------------------0,15625
=> mKMnO4 = 0,3125.158 = 49,375 (g)
\(n_{CH_4\left(dktc\right)}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ PTHH:CH_4+2O_2-^{t^o}>CO_2+2H_2O\)
Tỉ lệ: 1 : 2 : 1 : 2
n(mol) 0,2---->0,4-------->0,2----->0,4
\(m_{O_2}=n\cdot M=0,4\cdot32=12,8\left(g\right)\)
\(a,PTHH:S+O_2\underrightarrow{t^o}SO_2\left(1\right)\)
\(n_S=\dfrac{m}{M}=\dfrac{9,6}{32}=0,3\left(mol\right)\)
\(Theo.PTHH\left(1\right):n_O=n_S=0,3\left(mol\right)\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\\ Theo.PTHH\left(2\right):n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ m_{KClO_3}=n.M=0,2.122,5=24,5\left(g\right)\)
\(b,V_{O_2\left(đktc\right)}=n.22,4=0,2.22,4=4,48\left(l\right)\\ \Rightarrow V_{kk\left(đktc\right)}=5.V_{O_2}=5.4,48=22,4\left(l\right)\)
a, \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=11,2\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
\(n_{H_2}=\dfrac{V}{24,79}=\dfrac{11,2}{24,79}\approx0,45\left(mol\right)\)
a) \(PTHH:2H_2+O_2\underrightarrow{t^o}2H_2O\)
2 1 2
0,45 0,225 0,45
b) \(m_{O_2}=n.M=0,225.\left(16.2\right)=7,2\left(g\right)\\ V_{O_2}=n.24,79=0,225.24,79=5,57775\left(l\right)\)
c) \(PTHH:2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)
2 1 1 1
0,45 0,225 0,225 0,225
\(m_{KMnO_4}=n.M=0,45.\left(39+55+16.4\right)=71,1\left(g\right).\)
a, \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{O_2}=0,25.32=8\left(g\right)\)
\(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,5\left(mol\right)\Rightarrow m_{KMnO_4}=0,5.158=79\left(g\right)\)
a.\(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{19,5}{65}=0,3mol\)
\(2Zn+O_2\rightarrow\left(t^o\right)2ZnO\)
0,3 0,15 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)
b.\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,1 0,15 ( mol )
\(m_{KClO_3}=n_{KClO_3}.M_{KClO_3}=0,1.122,5=12,25g\)
a) PTHH: 2Zn + O2 → 2ZnO
2 1 2
0,3 0,15 0,3
nZn = \(\dfrac{m}{M}\) = \(\dfrac{19,5}{65}\) = 0,3 (mol)
mO2 = n.M = 0,15 . 16 = 2,4 (g)
VO2 = m . 22,4 = 2,4 . 22,4 = 53,76 (l)
b) 2KClO3 → 2KCl + 3O2 ↑
0,1 0,1 0,15
mKClO3 = n . M = 0,1 . 122,5 = 12,25 (g)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
\(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\\
2H_2+O_2\xrightarrow[]{t^o}2H_2O\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=2.\dfrac{1}{2}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
