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\(n_{H_3PO_4}=0.2\cdot0.5=0.1\left(mol\right)\)
\(3NaOH+H_3PO_4\rightarrow Na_3PO_4+3H_2O\)
\(0.3..............0.1\)
\(m_{dd_{NaOH}}=\dfrac{0.3\cdot40}{40\%}=30\left(g\right)\)
\(V_{dd_{NaOH}}=\dfrac{30}{1.2}=25\left(ml\right)\)
PTHH: \(3NaOH+H_3PO_4\rightarrow Na_3PO_4+3H_2O\)
Ta có: \(n_{H_3PO_4}=0,5\cdot0,2=0,1\left(mol\right)\) \(\Rightarrow n_{NaOH}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddNaOH}=\dfrac{0,3\cdot40}{40\%}=30\left(g\right)\) \(\Rightarrow V_{ddNaOH}=\dfrac{30}{1,2}=25\left(ml\right)\)
\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)
\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
\(0.1.......................0.1\)
\(m_{dd_{CH_3COOH}}=\dfrac{0.1\cdot60\cdot100}{5}=120\left(g\right)\)
=> B
nH2=\(\frac{6,72}{22,4}=0,3\)mol
PTHH
M+2HCl--> MCl2+H2
0,3mol<---------------0,3mol
=>MM=\(\frac{19,5}{0,3}=64\)
=> km loại là kẽm (Zn)
b) nNaOH=0,2.1=0,2 mol
PTHH
NaOH+HCl-->NaCl + H2O
0,2 mol--> 0,2 mol
---> thể tích HCl 1M đã dùng là V=\(\frac{0,2+0,3}{1}=0,5\)lít
=> CM(ZnCl2)=\(\frac{0,3}{0,5}=0,6M\)
\(n_{NaOH}=0.15\cdot1=0.15\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
\(0.15...........0.15\)
\(V_{dd_{HCl}}=\dfrac{0.15}{0.5}=0.3\left(l\right)\)
\(C\)
a) \(m_{HCl}=200.10,95\%=21,9\left(g\right)\)
b) \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
x_______2x________x____x(mol)
\(n_{HCl}=\dfrac{200.10,95\%}{36,5}=0,6\left(mol\right)\)
Dung dịch A phải có HCl dư mới có thể trung hòa được NaOH.
\(n_{NaOH}=0,05.2=0,1\left(mol\right)\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
y________y______y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}2x+y=0,6\\y=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,25\\y=0,1\end{matrix}\right.\)
\(\Rightarrow a=m_{CaCO_3}=100x=100.0,25=25\left(g\right)\\ V=V_{CO_2\left(đktc\right)}=22,4x=22,4.0,25=5,6\left(l\right)\)
c)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\\ C\%_{ddCaCl_2}=\dfrac{0,25.111}{214}.100\approx12,967\%\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,1.36,5}{214}.100\approx1,706\%\)
a)
$n_{Al_2O_3} = \dfrac{5,1}{102} = 0,05(mol)$
$Al_2O_3 + 6HCl \to 2AlCl_3 + 3H_2O$
$n_{HCl} = 6n_{Al_2O_3} = 0,3(mol)$
$\Rightarrow V = \dfrac{0,3}{4} = 0,075(lít)$
b)
$Al_2O_3 + 2NaOH \to 2NaAlO_2 + 2H_2O$
$n_{NaOH} = 2n_{Al_2O_3} = 0,1(mol)$
$V_{dd\ NaOH} = \dfrac{0,1}{10} = 0,01(lít)$
D.200ml
\(NaOH + HCl \rightarrow NaCl + H_2O\)
\(n_{HCl}= \dfrac{3,65}{36,5}= 0,1 mol\)
Theo PTHH:
\(n_{NaOH}= n_{HCl}= 0,1 mol\)
\(\Rightarrow V_{NaOH}= \dfrac{0,1}{0,5}= 0,2 l = 200 ml\)