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\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
a/ A+ HCl
CO3 2- + 2H+ ---> H2O+ CO2
dd B trung hòa bởi NaOH--> trong B có Ba(HCO3)2
CO2 + Ba(OH)2 --> BaCO3 + H2O
0.2<---0.25-0.05-------->0.2
2Co2+ Ba(OH)2--> Ba(HCO3)2
0.1<--------0.05<---------0.05
Ba(HCO3)2+ 2NaOH---> BaCO3+ Na2CO3+ 2H2O
0.05<-------------0.1
--> m2= 0.2*197=39,4g
Na2CO3 va K2CO3 : x,y mol
x+y=0.3
138y=106x*2,604
-->x=0.1,y=0.2
--> m1=0.1*106+ 0,2*138=38,2
b/
C%Na2CO3= (0.1*106*100)/ (61,8+ 38,2)=10,6%
C%K2CO3=(0.2*138*100)/(61,8+ 38,2)=27,6%
\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0,2------->0,1--------->0,1
Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư
Trong dung dịch D có:
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)
b
\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)
0,35<---------0,35
\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)
a, \(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\)
Theo PT: \(n_{NaOH}=2n_{Na_2O}=0,5\left(mol\right)\)
\(\Rightarrow CM_{NaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\)
b, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,25.98}{20\%}=122,5\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,46\left(ml\right)\)
