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PTHH: Ba(OH)2 + 2HCl ===> BaCl2 + 2H2O
Ta có: nBa(OH)2 = 0,05 x 0,04 = 0,002 (mol)
nHCl = 0,06 x 0,15 = 0,009 (mol)
Lập tỉ lệ số mol: \(\frac{0,002}{1}< \frac{0,009}{2}\)
=> HCl dư, Ba(OH)2 hết
=> Tính theo số mol Ba(OH)2
Theo PTHH: nBaCl2 = nBa(OH)2 = 0,0002 (mol)
=> CM(BaCl2) = \(\frac{0,002}{0,2}=0,01M\)
\(n_{Ba\left(OH\right)_2}=0,05.0,04=0,002mol\\ n_{HCl}=0,15.0,06=0,009mol\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ \Rightarrow\dfrac{0,002}{1}< \dfrac{0,009}{2}\Rightarrow HCl.dư\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
0,002 0,004 0,002
\(C_{M_{BaCl_2}}=\dfrac{0,002}{0,05+0,15}=0,01M\\ C_{M_{HCl.dư}}=\dfrac{0,009-0,004}{0,05+0,15}=0,025M\)
Ba(OH)2 + 2HCl → BaCl2 + 2H2O
\(n_{Ba\left(OH\right)_2}=0,05\times0,5=0,025\left(mol\right)\)
\(n_{HCl}=0,15\times0,1=0,015\left(mol\right)\)
Theo PT: \(n_{Ba\left(OH\right)_2}=\dfrac{1}{2}n_{HCl}\)
Theo bài: \(n_{Ba\left(OH\right)_2}=\dfrac{5}{3}n_{HCl}\)
Vì \(\dfrac{5}{3}>\dfrac{1}{2}\) ⇒ \(Ba\left(OH\right)_2\) dư
Dung dịch A gồm: Ba(OH)2 dư và BaCl2
Theo PT: \(n_{Ba\left(OH\right)_2}pư=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}\times0,015=0,0075\left(mol\right)\)
\(\Rightarrow n_{Ba\left(OH\right)_2}dư=0,025-0,0075=0,0175\left(mol\right)\)
\(\Rightarrow C_{M_{Ba\left(OH\right)_2}}dư=\dfrac{0,0175}{0,2}=0,0875\left(M\right)\)
Theo PT: \(n_{BaCl_2}=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}\times0,015=0,0075\left(mol\right)\)
\(\Rightarrow C_{M_{BaCl_2}}=\dfrac{0,0075}{0,2}=0,0375\left(M\right)\)
theo đề bài:
nHCl=0,3.0,5=0,15mol
nBa(OH)2=0,2.A(mol)
CMHCl=\(\dfrac{n_{HCl_{dư}}}{0,5}=0,02M\)
=>\(n_{HCl_{du}}\)=0,02.0,5=0,01mol
\(n_{HCl_{pu}}=0,15-0,01=0,14mol\)
PTPU
2HCl+Ba(OH)2->BaCl2+2H2O
0,14..........0,7
\(n_{Ba\left(OH\right)_2}=0,7mol\)
\(=>C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,7}{0,2}=3,5M\)
nHCl=0,5.0,3=0,15(mol)
nBa(OH)2=0,2A
nHCl dư=0,5.0,02=0,01(mol)
=>nHCl p/ứ=0,15-0,01=0,14(mol)
pt: 2HCl+Ba(OH)2--->BaCl2+2H2O
Theo pt: nBa(OH)2=1/2nHCl=0,07(mol)
=>0,2A=0,07=>A=0,35(M)
\(n_{NaOH}=0,2.1=0,2\left(mol\right)\\ n_{H_2SO_4}=0,3.1,5=0,45\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0,2------->0,1--------->0,1
Xét \(\dfrac{0,2}{2}< \dfrac{0,45}{1}\Rightarrow\) \(H_2SO_4\)dư
Trong dung dịch D có:
\(\left\{{}\begin{matrix}n_{H_2SO_4}=0,45-0,1=0,35\left(mol\right)\\n_{Na_2SO_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}CM_{H_2SO_4}=\dfrac{0,35}{0,5}=0,7M\\CM_{Na_2SO_4}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)
b
\(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)
0,35<---------0,35
\(V_{Ca\left(OH\right)_2}=\dfrac{0,35.74}{1,2}=\dfrac{259}{12}\approx21,58\left(ml\right)\\ \Rightarrow V_{dd.Ca\left(OH\right)_2}=\dfrac{\dfrac{259}{12}.100\%}{10\%}=\dfrac{1295}{6}\approx215,83\left(ml\right)\)
a, \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
\(n_{HCl}=0,2.2=0,4\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Fe}=0,15\left(mol\right)\Rightarrow V_{H_2}=0,15.22,4=3,36\left(l\right)=3360\left(ml\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{Fe}=0,15\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{FeCl_2}}=\dfrac{0,15}{0,2}=0,75\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)
c, Ta có: \(m_{ddHCl}=1,25.200=250\left(g\right)\)
⇒ m dd sau pư = 8,4 + 250 - 0,15.2 = 258,1 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%\approx7,38\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{258.1}.100\%\approx1,41\%\end{matrix}\right.\)
HCl 1 : Vdd(1) = mdd/D => mdd= Vdd. D
=> mHCl = (mdd . C%)/100 => số mol HCl
HCl 2 : số mol HCl 2 = CM. Vdd(2)
=> số mol tổng , Vtổng =Vdd1 + Vdd2
=> CM
bài này bạn xem lại dữ liệu khối lượng riêng nhé
\(a,n_{Na_2SO_4}=0,2\cdot0,2=0,04\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\cdot0,1=0,02\left(mol\right)\\ PTHH:Na_2SO_4+Ba\left(OH\right)_2\rightarrow2NaOH+BaSO_4\downarrow\\ TL:....1.....1......2......1\left(mol\right)\\ BR:.......0,02.....0,02......0,04......0,02\left(mol\right)\)
Vì \(\dfrac{n_{Na_2SO_4}}{1}>\dfrac{n_{Ba\left(OH\right)_2}}{1}\) nên \(Na_2SO_4\) dư, \(Ba\left(OH\right)_2\) hết
\(b,C_{M_{NaOH}}=\dfrac{0,04}{0,2+0,2}=0,1M\)
Ba(OH)2 + 2HCl ( ightarrow)BaCl2 + 2H2O
nBa(OH)2=0,05.0,05=0,0025(mol)
nHCl=0,15.0,1=0,015(mol)
Vậy HCl dư
Theo PTHH ta có:
nBa(OH)2=nBaCl2=0,0025(mol)
CM=(dfrac{0,0025}{0,2}=0,0125M)
\(Ba\left(OH\right)_2\left(0,002\right)+2HCl\left(0,004\right)\rightarrow BaCl_2\left(0,002\right)+2H_2O\)
\(n_{Ba\left(OH\right)_2}=0,04.0,05=0,002\)
\(n_{HCl}=0,15.0,06=0,009\)
Ta có: \(\frac{0,002}{1}< \frac{0,009}{2}\) nên Ba(OH)2 phản ứng hết còn HCl dư
\(\Rightarrow C_M=\frac{0,004}{0,2}=0,02M\)