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a) nH2SO4= 19,6/98=0,2(mol)
nCO2= (3.1023)/(6.1023)=0,5(mol)
nO2= 1,12/22,4=0,05(mol)
b) nN2=5,6/28=0,2(mol)
nO2=(1,8.1023)/(6.1023)=0,3 (mol)
=> V(khí đktc)=V(N2,đktc)+V(O2,đktc)=0,2.22,4+0,3.22,4=11,2(l)
a) \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,05-->0,1------->0,05
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,125<--0,3125<----0,25
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,05}{0,05+0,125}.100\%=28,57\%\\\%V_{C_2H_2}=\dfrac{0,125}{0,05+0,125}.100\%=71,43\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{0,05.16+0,125.26}.100\%=19,753\%\\\%m_{C_2H_2}=\dfrac{0,125.26}{0,05.16+0,125.26}.100\%=80,247\%\end{matrix}\right.\)
b) \(n_{O_2}=0,1+0,3125=0,4125\left(mol\right)\)
=> \(V_{O_2}=0,4125.22,4=9,24\left(l\right)\)
=> Vkk = 9,24.5 = 46,2 (l)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
2CO + O2 --to--> 2CO2
0,2<---0,1<--------0,2
2H2 + O2 --to--> 2H2O
0,4<--0,2<-------0,2
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\\%V_{H_2}=100\%-33,33\%=66,67\%\end{matrix}\right.\)
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,3<--0,15<------0,3
2H2 + O2 --to--> 2H2O
0,1<--0,05
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\%n_{CO}=\dfrac{0,3}{0,3+0,1}.100\%=75\%\\\%V_{H_2}=100\%-75\%=25\%\end{matrix}\right.\)
\(a.\)
\(n_{CO_2}=\dfrac{11}{44}=0.25\left(mol\right)\)
\(b.\)
\(n_{H_2}=\dfrac{9\cdot10^{23}}{6\cdot10^{23}}=1.5\left(mol\right)\)
\(V_{H_2}=1.5\cdot22.4=33.6\left(l\right)\)
nX = 0,672/22,4 = 0,03 (mol)
Gọi nN2 = a (mol); nO2 = b (mol)
a + b = 0,03
28a + 32b = 0,88
=> a = 0,02 (mol); b = 0,01 (mol)
%VN2 = 0,02/0,03 = 66,66%
%VO2 = 100% - 66,66% = 33,34%
M(X) = 0,88/0,03 = 88/3 (g/mol)
nX = 2,2 : 88/3 = 0,075 (mol)
VH2 = VX = 0,075 . 22,4 = 1,68 (l)
$n_{CO_2} = \dfrac{11}{44} = 0,25(mol)$
$n_{H_2} = \dfrac{16,8}{22,4} = 0,75(mol)$
$n_{CH_4} = \dfrac{1,8.10^{23}}{6.10^{23}} = 0,3(mol)$
$\Rightarrow V_{hh} = (0,25 + 0,75 + 0,3).22,4 = 29,12(lít)$