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co MZn >M Fe -> neu hon hop toan la Fe -> trong 37,2g co nFe > n Fe +nZn hay noi cach khac la so mol chat trong 37,2g Fe lon hon so gam chat trong 37,2 g hon hop Fe,Zn,
neu hon hop toan Fe -> n Fe = 37.2 : 56=0.66 mol
n H2 SO4 = 2x 0.5 = 1 mol
Fe tac dung voi H2 SO4 theo ti le 1:1
-> 37.2g Fe tan het.=> nFe < nH2SO4 hien co.ma nFe> n Fe+n Zn=> hon hop tan het
b.neu dung luong gap doi lan truoc la : 74.4g
gia su hon hop toan Zn -> nZn <n Fe +n Zn
nZn = 74.4 : 65=1.14 mol > n H2SO4 => ko phan ung het,Zn du
ma nZn < n Fe+ n Zn => hon hop ban dau khong tan het
c.n CuO = 0.6 mol
n H2 = n Cuo= 0.6 mol = n Fe + n Zn (1)
nFe x 56 + n Zn x 65 = 37,2 (2)
giai he phuong trinh 1 va 2 => n Fe =0.2 mol => m Fe =11.2g
n Zn= 0.4 mol => m Zn =26
Phần b bạn ko tính số mol của các chất à...vậy tính sao bây h -_-
a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau
=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)
Gọi số mol Al, Zn là a, b (mol)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a------->0,5a----->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b----->b--------->b----->b
=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)
=> 171a = 161b
=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)
Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)
b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)
=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)
\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)
=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)
=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)
a) Do dd sau pư có 3 chát tan với nồng độ % bằng nhau
=> \(m_{Al_2\left(SO_4\right)_3}=m_{ZnSO_4}=m_{H_2SO_4\left(dư\right)}\)
Gọi số mol Al, Zn là a, b (mol)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
a----->1,5a------->0,5a----->1,5a
Zn + H2SO4 --> ZnSO4 + H2
b----->b--------->b----->b
=> \(\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=342.0,5a=171a\left(g\right)\\m_{ZnSO_4}=161b\left(g\right)\end{matrix}\right.\)
=> 171a = 161b
=> \(\dfrac{a}{b}=\dfrac{161}{171}\) (1)
Có: \(\dfrac{m_{Al}}{m_{Zn}}=\dfrac{27.n_{Al}}{65.n_{Zn}}=\dfrac{27}{65}.\dfrac{161}{171}=\dfrac{483}{1235}\)
b) \(n_{H_2}=1,5a+b=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{161}{825}\left(mol\right)\\b=\dfrac{57}{275}\left(mol\right)\end{matrix}\right.\)
=> \(x=\dfrac{161}{825}.27+\dfrac{57}{275}.65=\dfrac{5154}{275}\left(g\right)\)
\(m_{H_2SO_4\left(dư\right)}=m_{Al_2\left(SO_4\right)_3}=342.0,5\dfrac{161}{825}=\dfrac{9177}{275}\left(g\right)\)
=> \(m_{H_2SO_4\left(bđ\right)}=98\left(1,5a+b\right)+\dfrac{9177}{275}=\dfrac{22652}{275}\left(g\right)\)
=> \(y=\dfrac{\dfrac{22652}{275}.100}{10}=\dfrac{45304}{55}\left(g\right)\)
a) \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b) Gọi x,y là số mol Al, Fe
\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
Ta có hệ : \(\left\{{}\begin{matrix}27x+56y=0,83\\\dfrac{3}{2}x+y=0,02\end{matrix}\right.\)
=> \(x=\dfrac{29}{5700};y=\dfrac{47}{3800}\)
\(\%m_{Al}=\dfrac{\dfrac{27}{5700}.27}{0,83}.100=16,55\%\); \(\%m_{Fe}=100-16,55=83,45\%\)
c)Bảo toàn nguyên tố H: \(n_{H_2SO_4}=n_{H_2}=0,02\left(mol\right)\)
=> \(C\%_{H_2SO_4}=\dfrac{0,02.98}{200}.100=0,98\%\)
a, Gọi \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH:
2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
a---->1,5a--------------------------->1,5a
Mg + H2SO4 ---> MgSO4 + H2
b------>b----------------------->b
Hệ pt \(\left\{{}\begin{matrix}27a+24b=6,3\\1,5a+b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,15\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Al}=0,1.27=2,7\left(g\right)\\m_{Mg}=0,15.24=3,6\left(g\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{2,7}{6,3}=42,86\%\\\%m_{Mg}=100\%-42,86\%=57,14\%\end{matrix}\right.\)
b, \(n_{H_2SO_4}=0,1.1,5+0,15=0,3\left(mol\right)\)
\(\rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{0,5}=0,6\left(l\right)=600\left(ml\right)\)
c, đề yêu cầu jv?
