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a) 2Al + 6HCl -> 2AlCl3 + 3H2

Al2O3 + 6HCl -> 2AlCl3 + 3H2O

nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol

=>%mAl=20,93% =>%mAl2O3 = 79,07%

b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g

mddY=12,9+100-0,15.2=112,6g

mAlCl3=22,5g=>C%=19,98%

23 tháng 2 2022

giúp em vs ạ

 

30 tháng 5 2023

a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b, 24nMg + 27nAl = 6,12 (1)

Theo PT: \(n_{H_2}=n_{Mg}+\dfrac{3}{2}n_{Al}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,12\left(mol\right)\\n_{Al}=0,12\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,12.24}{6,12}.100\%\approx47,06\%\\\%m_{Al}\approx52,94\%\end{matrix}\right.\)

23 tháng 2 2022

Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\) => 65a + 56b + 27c = 10,65 (1)

PTHH: Zn + 2HCl --> ZnCl2 + H2

            Fe + 2HCl --> FeCl2 + H2

            2Al + 6HCl --> 2AlCl3 + 3H2

=> \(n_{H_2}=a+b+1,5c=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) (2)

PTHH: Zn + Cl2 --to--> ZnCl2

            2Fe + 3Cl2 --to--> 2FeCl3

            2Al + 3Cl2 --to--> 2AlCl3

=> \(n_{Cl_2}=a+1,5b+1,5c=\dfrac{5,6}{22,4}=0,25\left(mol\right)\) (3)

(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,05\left(mol\right)\\c=0,05\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_{Zn}=0,1.65=6,5\left(g\right)\\m_{Fe}=0,05.56=2,8\left(g\right)\\m_{Al}=0,05.27=1,35\left(g\right)\end{matrix}\right.\)

a) \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{6,5}{10,65}.100\%=61,033\%\\\%m_{Fe}=\dfrac{2,8}{10,65}.100\%=26,291\%\\\%m_{Al}=\dfrac{1,35}{10,65}.100\%=12,676\%\end{matrix}\right.\)

b) nHCl = 2a + 2b + 3c = 0,45 (mol)

=> mHCl = 0,45.36,5 = 16,425 (g)

=> \(a\%=C\%=\dfrac{16,425}{200}.100\%=8,2125\%\)

c) mdd sau pư = 10,65 + 200 - 0,225.2 = 210,2 (g)

=> \(\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{210,2}.100\%=6,47\%\\C\%_{FeCl_2}=\dfrac{0,05.127}{210,2}.100\%=3,02\%\\C\%_{AlCl_3}=\dfrac{0,05.133,5}{210,2}.100\%=3,176\%\end{matrix}\right.\)

3 tháng 3 2022

Fe+2HCl->FeCl2+H2

x---2x-----------x

Mg+2HCl->MgCl2+H2

y------2y-----------y

Ta có :

\(\left\{{}\begin{matrix}56x+24y=24\\x+y=\dfrac{13,44}{22,4}\end{matrix}\right.\)

=>x=0,3 mol, y=0,3 mol

=>%m Fe=\(\dfrac{0,3.56}{24}.100\)=70%

=>%m Mg=100-70=30%

=>VHCl=\(\dfrac{0,3.2+0,3.2}{2}\)=0,6l=600ml

b)

 XCl2+2AgNO3->2AgCl+X(NO3)2

0,6--------------------1,2mol

=>m AgCl=1,2.143,5=172,2g

 

11 tháng 9 2021

a)\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2

Mol:       x                                                     1,5x

PTHH: Mg + H2SO4 → MgSO4 + H2

Mol:      y                                                 y

Ta có: \(\left\{{}\begin{matrix}27x+24y=5,1\\1,5x+y=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{0,1.27.100\%}{5,1}=52,94\%;\%m_{Mg}=100-52,94=47,06\%\)

b) 

PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2

Mol:      0,1      0,15                  0,05                            

PTHH: Mg + H2SO4 → MgSO4 + H2

Mol:     0,1       0,1                 0,1

\(m_{ddH_2SO_4}=\dfrac{\left(0,1+0,15\right).98.100}{9,8}=250\left(g\right)\)

mdd sau pứ = 5,1+250-0,15.2 = 254,8(g)

\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{254,8}=6,71\%\)

\(C\%_{ddMgSO_4}=\dfrac{0,1.120.100\%}{254,8}=4,71\%\)

a) 

Gọi số mol Mg, Al là a, b (mol)

=> 24a + 27b = 26,25 (1)

\(n_{H_2}=\dfrac{30,8}{22,4}=1,375\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl2 + H2

             a-->2a--------->a------>a

            2Al + 6HCl --> 2AlCl3 + 3H2

             b---->3b------->b------>1,5b

=> a + 1,5b = 1,375 (2)

(1)(2) => a = 0,25 (mol); b = 0,75 (mol)

=> \(\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,25.24}{26,25}.100\%=22,857\%\\\%m_{Al}=\dfrac{0,75.27}{26,25}.100\%=77,143\%\end{matrix}\right.\)

b)

nHCl = 2a + 3b = 2,75 (mol)

=> mHCl = 2,75.36,5 = 100,375 (g)

=> \(m_{dd.HCl}=\dfrac{100,375.100}{10}=1003,75\left(g\right)\)

c) 

mdd sau pư = 1003,75 + 26,25 - 1,375.2 = 1027,25 (g)

\(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,25.95}{1027,25}.100\%=2,312\%\\C\%_{AlCl_3}=\dfrac{0,75.133,5}{1027,25}.100\%=9,747\%\end{matrix}\right.\)