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\(n_{CO_2}=a\left(mol\right),n_{N_2O}=b\left(mol\right),n_{H_2}=c\left(Mol\right)\)
\(n_A=a+b+c=0.05\left(mol\right)\)
\(\Leftrightarrow44a+44b+44c=2.2\left(1\right)\)
\(m_A=44a+44b+2c=1.78\left(g\right)\left(2\right)\)
\(\Rightarrow c=0.01\)
\(m_B=0.01\cdot2+0.03\cdot X=0.14\left(g\right)\)
\(\Rightarrow X=4\)
\(X:He\)
Trong A :
\(n_{CO_2}=n_X=a\left(mol\right)\)
Trong B:
\(n_{N_2}=2b\left(mol\right),n_{CO_2}=3b\left(mol\right)\)
\(n_A=2a=0.1\left(mol\right)\Rightarrow a=0.05\)
\(n_B=5b=0.05\left(mol\right)\Rightarrow b=0.01\)
\(m=0.05\cdot44+0.05\cdot X+0.02\cdot28+0.03\cdot44=4.18\left(g\right)\)
\(\Rightarrow X=2\)
\(X:H_2\)
a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)
nX = 0,672/22,4 = 0,03 (mol)
Gọi nN2 = a (mol); nO2 = b (mol)
a + b = 0,03
28a + 32b = 0,88
=> a = 0,02 (mol); b = 0,01 (mol)
%VN2 = 0,02/0,03 = 66,66%
%VO2 = 100% - 66,66% = 33,34%
M(X) = 0,88/0,03 = 88/3 (g/mol)
nX = 2,2 : 88/3 = 0,075 (mol)
VH2 = VX = 0,075 . 22,4 = 1,68 (l)
\(a.\)
\(m_{hh}=0.12\cdot90+0.15\cdot58=19.5\left(g\right)\)
\(b.\)
\(V_{hh}=\left(0.25+0.1+0.05\right)\cdot22.4=8.96\left(l\right)\)
\(c.\)
\(n_A=\dfrac{10.08}{22.4}=0.45\left(mol\right)\)
\(M_A=23\cdot2=46\left(\dfrac{g}{mol}\right)\)
\(m_A=0.45\cdot46=20.7\left(g\right)\)
\(d.\)
\(n_{hh}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
Vì CO2 : O2 = 2 : 1
\(\Rightarrow n_{CO_2}=0.2\left(mol\right),n_{O_2}=0.1\left(mol\right)\)
\(m_{hh}=0.2\cdot44+0.1\cdot32=12\left(g\right)\)
\(\overline{M}=\dfrac{12}{0.3}=40\left(\dfrac{g}{mol}\right)\)
a. PTHH: \(C+O_2\rightarrow CO_2\)
\(C+\frac{1}{2}O_2\rightarrow CO\)
b. Có \(\hept{\begin{cases}\overline{M}=18,8.2=37,6\\N_{\text{khí}}=\frac{1,12}{22,4}=0,05mol\end{cases}}\)
Theo sơ đồ chiếu \(\frac{n_{CO_2}}{n_{CO}}=\frac{37,6-28}{44-37,6}=\frac{3}{2}\)
\(\rightarrow\hept{\begin{cases}n_{CO_2}=0,03mol\\n_{CO}=0,02mol\end{cases}}\)
\(\rightarrow\hept{\begin{cases}V_{CO_2}=0,03.22,4=0,672l\\V_{CO}=0,448l\end{cases}}\)
c. Theo phương trình \(n_C=n_{CO_2}+n_{CO}=0,05mol\)
\(\rightarrow m_C=12.0,05=0,6g\)
a) \(\overline{M}_A=5,875.2=11,75\left(g/mol\right)\)
b) Gọi số mol N2, H2 là a, b (mol)
\(\overline{M}_A=\dfrac{28a+2b}{a+b}=11,75\left(g/mol\right)\)
=> 16,25a = 9,75b
=> a = 0,6b
\(\left\{{}\begin{matrix}\%n_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{0,6b}{0,6b+b}.100\%=37,5\%\\\%n_{H_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{0,6b+b}.100\%=62,5\%\end{matrix}\right.\)
c)
1 mol hỗn hợp A chứa \(\left\{{}\begin{matrix}n_{N_2}=\dfrac{1.37,5}{100}=0,375\left(mol\right)\\n_{H_2}=\dfrac{1.62,5}{100}=0,625\left(mol\right)\end{matrix}\right.\)
\(\overline{M}_B=\dfrac{0,375.28+0,625.2+17x}{1+x}=6,4.2=12,8\left(g/mol\right)\)
=> x = 0,25 (mol)
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
