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Câu 1 :
\(n_{Mg}=\dfrac{8.4}{24}=0.35\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.35.......0.7.........0.35..........0.35\)
\(C\%_{HCl}=\dfrac{0.7\cdot36.5}{146}\cdot100\%=17.5\%\)
\(m_{\text{dung dịch sau phản ứng}}=8.4+146-0.35\cdot2=153.7\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{0.35\cdot95}{153.7}\cdot100\%=21.6\%\)
Câu 2 :
\(n_{CaCO_3}=\dfrac{10}{100}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{114.1\cdot8\%}{36.5}=0.25\left(mol\right)\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(1................2\)
\(0.1.............0.25\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.25}{2}\Rightarrow HCldư\)
\(m_{\text{dung dịch sau phản ứng}}=10+114.1-0.1\cdot44=119.7\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{\left(0.25-0.2\right)\cdot36.5}{119.7}\cdot100\%=1.52\%\)
\(C\%_{CaCl_2}=\dfrac{0.2\cdot111}{119.7}\cdot100\%=18.54\%\)
`a)PTHH:`
`Fe + 2HCl -> FeCl_2 + H_2`
`0,15` `0,3` `0,15` `0,15` `(mol)`
`n_[Fe]=[8,4]/56=0,15(mol)`
`b)V_[H_2]=0,15.22,4=3,36(l)`
`c)V_[dd HCl]=[0,3]/[0,5]=0,6(l)`
`=>C_[M_[FeCl_2]]=[0,15]/[0,6]=0,25(M)`
\(a,n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,15-->0,3----->0,15--->0,15
b, VH2 = 0,15.22,4 = 3,36 (l)
\(c,V_{dd}=\dfrac{0,3}{0,5}=0,6\left(l\right)\\ \rightarrow C_{M\left(FeCl_2\right)}=\dfrac{0,15}{0,6}=0,25M\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
a) Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\) \(\Rightarrow n_{HCl}=0,2mol\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,2\cdot36,5}{10,95\%}\approx66,67\left(g\right)\)
b) Theo PTHH: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,1mol\)
\(\Rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,1\cdot136=13,6\left(g\right)\\m_{H_2}=0,1\cdot2=0,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Zn}+m_{ddHCl}-m_{H_2}=72,97\left(g\right)\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{13,6}{72,97}\cdot100\%\approx18,64\%\)
1.
nAl=\(\dfrac{5,4}{27}\)=0,2 mol
mHCl=\(\dfrac{175.14,6}{100}\)=25,55g
nHCl=\(\dfrac{25,55}{36,5}\)=0,7
2Al + 6HCl → 2AlCl3 + 3H2↑
n trước pứ 0,2 0,7
n pứ 0,2 →0,6 → 0,2 → 0,3 mol
n sau pứ hết dư 0,1
Sau pứ HCl dư.
mHCl (dư)= 36,5.0,1=3,65g
mcác chất sau pư= 5,4 +175 - 0,3.2= 179,8g
mAlCl3= 133,5.0,2=26,7g
C%ddHCl (dư)= \(\dfrac{3,65.100}{179,8}=2,03%\)%
C%ddAlCl3 = \(\dfrac{26,7.100}{179,8}\)= 14,85%
2.
200ml= 0,2l
mMg= \(\dfrac{4,2}{24}=0,175mol\)
Mg + 2HCl → MgCl2 + H2↑
0,175→ 0,35 → 0,175→0,175 mol
a) VH2= 0,175.22,4=3,92l.
b)C%dHCl= \(\dfrac{0,35}{0,2}=1,75\)M
Fe+H2SO4->FeSO4+H2
0,15---0,15-----0,15---0,15 mol
n Fe=8,4\56=0,15 mol
=>VH2=0,15.22,4=3,36l
=>m H2SO4=0,15.98=14,7g
=>C% H2SO4=14,7\245 .100=6%
=>m dd muối=8,4+245-0,15.2=253,1g
=>C% muối =0,15.152\253,1 .100=9%
\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\\ a,PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{FeCl_2}=n_{Fe}=0,05\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\\ V_{H_2\left(đkc\right)}=0,05.24,79=1,2395\left(l\right)\\ b,n_{HCl}=0,1.3=0,3\left(mol\right)\\ Vì:\dfrac{0,05}{1}< \dfrac{0,3}{2}\Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,3-0,05.2=0,2\left(mol\right)\\ n_{FeCl_2}=n_{Fe}=0,05\left(mol\right)\\ V_{ddsau}=V_{ddHCl}=0,1\left(l\right)\\ b,C_{MddFeCl_2}=\dfrac{0,05}{0,1}=0,5\left(M\right);C_{MddHCl\left(dư\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)
a. \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(n_{Fe}=\frac{11,2}{56}=0,2mol\)
b. Theo phương trình \(n_{HCl}=n_{Fe}.2=0,2.2=0,4mol\)
\(\rightarrow V_{ddHCl}=\frac{0,4}{2}=0,2l=200ml\)
c. Theo phương trình \(n_{FeCl_2}=n_{Fe}=0,2mol\)
\(\rightarrow C_{M_{ddFeCl_2}}=\frac{0,2}{0,2}=1M\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\); \(n_{HCl}=\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,8}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2-->0,6---->0,2----->0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b) \(\left\{{}\begin{matrix}m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\\m_{HCl\left(dư\right)}=\left(0,8-0,6\right).36,5=7,3\left(g\right)\end{matrix}\right.\)
=> mchất tan = 26,7 + 7,3 = 34 (g)
c) mdd sau pư = 5,4 + 200 - 0,3.2 = 204,8 (g)
\(\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{26,7}{204,8}.100\%=13,04\%\\C\%_{HCl\left(dư\right)}=\dfrac{7,3}{204,8}.100\%=3,56\%\end{matrix}\right.\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,2 0,3
\(V_{H_2}=0,3.22,4=6,72L\\ m_{AlCl_3}=133,5.0,2=26,7g\\ m_{\text{dd}}=5,4+200-\left(0,3.2\right)=204,8g\\ C\%=\dfrac{26,7}{204,8}.100\%=13\%\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(m_{HCl}=245.16,7\%=40,915\left(g\right)\Rightarrow n_{HCl}=\dfrac{40,915}{36,5}=1,121\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{1,121}{2}\), ta được HCl dư.
Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{H_2}=n_{Fe}=0,1\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)
⇒ nHCl dư = 1,121 - 0,2 = 0,921 (mol)
Ta có: m dd sau pư = 5,6 +245 - 0,1.2 = 250,4 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,1.127}{250,4}.100\%\approx5,07\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,921.36,5}{250,4}.100\%\approx13,43\%\end{matrix}\right.\)