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a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\); \(n_{HCl}=\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,8}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2-->0,6---->0,2----->0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b) \(\left\{{}\begin{matrix}m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\\m_{HCl\left(dư\right)}=\left(0,8-0,6\right).36,5=7,3\left(g\right)\end{matrix}\right.\)
=> mchất tan = 26,7 + 7,3 = 34 (g)
c) mdd sau pư = 5,4 + 200 - 0,3.2 = 204,8 (g)
\(\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{26,7}{204,8}.100\%=13,04\%\\C\%_{HCl\left(dư\right)}=\dfrac{7,3}{204,8}.100\%=3,56\%\end{matrix}\right.\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,2 0,3
\(V_{H_2}=0,3.22,4=6,72L\\ m_{AlCl_3}=133,5.0,2=26,7g\\ m_{\text{dd}}=5,4+200-\left(0,3.2\right)=204,8g\\ C\%=\dfrac{26,7}{204,8}.100\%=13\%\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{H_2SO_4}=0,5.0,1=0,05\left(mol\right)\\ pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(LTL:\dfrac{0,2}{2}>\dfrac{0,05}{3}\)
=> Al dư
\(n_{H_2}=n_{H_2SO_4}=0,05\left(mol\right)\)
\(V_{H_2}=0,05.22,4=1,12l\\
C_M=\dfrac{\dfrac{1}{60}}{0,1}=0,16M\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot29,4\%}{98}=0,6\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,6}{3}\) \(\Rightarrow\) Axit còn dư, Nhôm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,6-0,3=0,3\left(mol\right)\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72 \left(l\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=204,8\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34,2}{204,8}\cdot100\%\approx16,7\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{29,4}{204,8}\cdot100\%\approx14,36\%\end{matrix}\right.\)
a, PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,5.65=32,5\left(g\right)\)
\(\Rightarrow m_{CuO}=72,5-32,5=40\left(g\right)\)
c, Ta có: \(n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Zn}+n_{CuO}=1\left(mol\right)\)
\(\Rightarrow b=C_{M_{H_2SO_4}}=\dfrac{1}{2,5}=0,4M\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnSO_4}=n_{Zn}=0,5\left(mol\right)\\n_{CuSO_4}=n_{CuO}=0,5\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnSO_4}}=\dfrac{0,5}{2,5}=0,2M\\C_{M_{CuSO_4}}=\dfrac{0,5}{2,5}=0,2M\end{matrix}\right.\)
Bạn tham khảo nhé!
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\left(I\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\left(II\right)\)
b, Theo PTHH(1) : \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{Zn}=32,5\left(g\right)\)
\(\Rightarrow m_{CuO}=m_{hh}-m_{Zn}=40\left(g\right)\)
\(\Rightarrow n_{CuO}=\dfrac{m}{M}=0,5\left(mol\right)\)
c, Theo PTHH (1) và (2) : \(n_{H2SO4}=n_{CuO}+n_{Zn}=1\left(mol\right)\)
\(\Rightarrow C_{MH2SO4}=b=\dfrac{n}{V}=\dfrac{1}{2,5}=0,4M\)
d, ( Chắc là thể tích coi như không đổi )
Thấy sau phản ứng thu được A gồm \(0,5molZnSO_4,0,5molCuSO_4\)
\(\Rightarrow C_{MCuSO4}=C_{MZnSO4}=\dfrac{n}{V}=\dfrac{0,5}{2,5}=0,2M\)
Vậy ...
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2...................0.2..........0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{FeCl_2}=0.2\cdot127=25.4\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng}}=11.2+200-0.2\cdot2=210.8\left(g\right)\)
\(C\%_{FeCl_2}=\dfrac{25.4}{210.8}\cdot100\%=12.05\%\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.24,79=7,437\left(l\right)\)
a)
$n_{Zn} = \dfrac{13}{65} = 0,2(mol) ; n_{H_2 SO_4} = 0,5.2 = 1(mol)$
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
Ta thấy :
$n_{Zn} < n_{H_2SO_4}$ nên $H_2SO_4$ dư
$n_{ZnSO_4} = n_{H_2SO_4\ pư} = n_{Zn} = 0,2(mol)$
$m_{ZnSO_4} = 0,2.161=32,2(gam)$
$m_{H_2SO_4\ pư} = 0,2.98 = 19,6(gam)$
b)
$n_{H_2SO_4\ dư} = 1 - 0,2 = 0,8(mol)$
$C_{M_{H_2SO_4\ dư}} = \dfrac{0,8}{0,5} = 1,6M$
$C_{M_{FeSO_4}} = \dfrac{0,2}{0,5} = 0,4M$
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{H_2SO_4}=0,5.2=1\left(mol\right)\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ a.Vì:\dfrac{0,2}{1}< \dfrac{1}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{ZnSO_4}=n_{Zn}=0,2\left(mol\right)\\ m_{H_2SO_4\left(p.ứ\right)}=0,2.98=19,6\left(g\right)\\ m_{ZnSO_4}=161.0,2=32,2\left(g\right)\\ b.V_{ddsau}=V_{ddH_2SO_4}=0,5\left(l\right)\\ C_{MddZnSO_4}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\ C_{MddH_2SO_4\left(dư\right)}=\dfrac{1-0,2}{0,5}=1,6\left(M\right)\)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{200\cdot39.2\%}{98}=0.8\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Lập tỉ lệ :
\(\dfrac{0.2}{2}< \dfrac{0.8}{3}\) => H2SO4 dư
\(n_{H_2}=\dfrac{3}{2}\cdot0.2=0.3\left(mol\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(m_{dd}=5.4+200-0.3\cdot2=204.8\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0.1\cdot342=34.2\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{34.2}{204.8}\cdot100\%=16.7\%\)
hình như câu b có HCl dư nữa