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\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
nH2 = 2.24/22.4 = 0.1 (mol)
Na + H2O => NaOH + 1/2 H2
0.2....................0.2..........0.1
mNa = 0.2 * 23 = 4.6 (g)
mNa2O = 17 - 4.6 = 12.4 (g)
nNa2O = 12.4/62 = 0.2 (mol)
Na2O + H2O => 2NaOH
0.2........................0.4
nNaOH = 0.2 + 0.4 = 0.6 (mol)
mNaOH = 0.6 * 40 = 24 (g)
nCuO = 24/80 = 0.3 (mol)
CuO + H2 -t0-> Cu + H2O
1...........1
0.3.........0.1
LTL : 0.3/1 > 0.1/1
=> CuO dư
nCu = nH2 = 0.1 (mol)
mCu = 0.1 * 64 = 6.4 (g)
Gọi n Mg = x ( mol )
m Al = y ( mol )
-> 24x + 27 y = 7,5
PTHH :
\(2Mg+O_2\underrightarrow{t^o}2MgO\)
x 0,5x x
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
y 3/4y 0,5y
-> \(0,5x+\dfrac{3}{4}y=n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Ta có Hệ Pt \(\left\{{}\begin{matrix}24x+27y=7,5\\0,5x+0,75y=0,2\end{matrix}\right.\)
Giải hệ PT , ta có :
x=0,05
y= 7/30
\(m_{Mg}=0,05.24=1,2\left(g\right)\)
\(m_{Al}=\dfrac{7}{30}.27=6,3\left(g\right)\)
\(m_{MgO}=0,05.40=2\left(g\right)\)
\(m_{Al_2O_3}=\dfrac{7}{30}.102:2=11,9\left(g\right)\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH:
Ca + 2H2O ---> Ca(OH)2 + H2
0,1<-------------0,1<---------0,1
=> \(\left\{{}\begin{matrix}m_{Ca}=0,1.40=4\left(g\right)\\m_{CaO}=9,6-4=5,6\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{4}{9,6}.100\%=41,67\%\\\%m_{CaO}=100\%-41,67\%=58,33\%\end{matrix}\right.\)
\(n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: CaO + H2O ---> Ca(OH)2
0,1------------------>0,1
=> \(m_{Ca\left(OH\right)_2}=\left(0,1+0,1\right).74=14,8\left(g\right)\)
a, \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(2K+2H_2O\rightarrow2KOH+H_2\)
b, Ta có: \(n_K=\dfrac{3,9}{39}=0,1\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{Na}+\dfrac{1}{2}n_K=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow n_{Na}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na}=\dfrac{0,1.23}{0,1.23+3,9}.100\%\approx37,1\%\\\%m_K\approx62,9\%\end{matrix}\right.\)
