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nFe = 5,04 / 56 = 0,09 ( mol)
3Fe + 2O2 --(t^o)-- > Fe3O4
0,09 0,06 0,03 (mol)
=> mFe3O4 = 0,03 . 232 = 6,9(g)
=> VO2 = 0,06 . 22,4 = 1,344 (l)
=> Vkk = 1,344 . 5 = 6,72(l)
nFe = 16,8 : 56 = 0,3 (mol)
pthh :3 Fe + 2O2 -t--> Fe3O4
0,3--------------> 0,1 (mol)
=> mFe3O4 =0,1 . 232 = 23,2(G)
nH2 = 44,8 : 22,4 = 2 (g)
pthh : Fe3O4 + H2 -t--> Fe + H2O
LTL : 0,1 / 1 < 2 /1
=> H2 du
nH2 (pu) = nFe3O4 = 0,1 (mol)
=> nH2 (d) = 2-0,1 = 1,9 (mol)
mH2 (d) = 1,9 . 2 = 3,8 (g)
a.b.\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 0,2 0,1 ( mol )
\(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
\(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
c. \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 > 0,15 ( mol )
0,225 0,15 0,075 ( mol )
\(m_{Fe_3O_4}=0,075.232=17,4\left(g\right)\)
d. \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
\(Fe_3O_4+4H_2\rightarrow\left(t^o\right)3Fe+4H_2O\)
0,075 < 0,35 ( mol )
0,075 0,3 ( mol )
Chất dư là H2
\(m_{H_2\left(dư\right)}=\left(0,35-0,3\right).2=0,1\left(g\right)\)
\(n_{Fe}=\dfrac{33,6}{56}=0,6mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,6 0,4 0,2 ( mol )
\(V_{kk}=0,4.22,4.5=44,8l\)
\(m_{Fe_3O_4}=0,2.232=46,4g\)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
\(PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ BTKL:m_{O_2}=m_{Fe_3O_4}-m_{Fe}=23,2-16,8=6,4(g)\)
Bài 1:
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
a, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{3}< \dfrac{0,1}{2}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,1-\dfrac{1}{15}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\dfrac{1}{30}.32\approx1,067\left(g\right)\\V_{O_2\left(dư\right)}=\dfrac{1}{30}.2,24\approx0,746\left(l\right)\end{matrix}\right.\)
b, Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)
Bài 2:
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
a, Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{15}.232\approx15,467\left(g\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{15}\left(mol\right)\)
\(\Rightarrow V_{O_2}=\dfrac{2}{15}.22,4\approx2,9867\left(l\right)\)
c, PT: \(2N_2+5O_2\underrightarrow{t^o}2N_2O_5\)
Ta có: \(n_{N_2}=\dfrac{2,8}{28}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{2}>\dfrac{\dfrac{2}{15}}{5}\), ta được N2 dư.
Theo PT: \(n_{N_2O_5}=\dfrac{2}{5}n_{O_2}=\dfrac{4}{75}\left(mol\right)\)
\(\Rightarrow m_{N_2O_5}=\dfrac{4}{75}.108=5,76\left(g\right)\)
Bạn tham khảo nhé!
Bài 1 :
\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)
\(n_{O_2}=\dfrac{2.24}{224}=0.1\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)
\(Bđ:0.1......0.1\)
\(Pư:0.1.......\dfrac{1}{15}...\dfrac{1}{30}\)
\(Kt:0........\dfrac{1}{30}....\dfrac{1}{30}\)
\(V_{O_2\left(dư\right)}=\dfrac{1}{30}\cdot22.4=0.747\left(l\right)\)
\(m_{Fe_3O_4}=\dfrac{1}{30}\cdot232=7.73\left(g\right)\)
Bài 2 :
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)
\(0.2.......0.3.......\dfrac{1}{15}\)
\(V_{O_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(m_{Fe_3O_4}=\dfrac{1}{15}\cdot232=15.47\left(g\right)\)
\(n_{N_2}=\dfrac{2.8}{28}=0.1\left(mol\right)\)
\(2N_2+5O_2\underrightarrow{t^0}2N_2O_5\)
\(0.12......0.3........0.12\)
\(m_{N_2O_5}=0.12\cdot108=12.96\left(g\right)\)
\(n_{O_2}=\dfrac{0.896}{22.4}=0.04\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(0.06......0.04.......0.02\)
\(m_{Fe}=0.06\cdot56=3.36\left(g\right)\)
\(m_{Fe_2O_3}=0.02\cdot232=4.64\left(g\right)\)
3Fe+2O2-to>Fe3O4
0,06----0,04-----0,02 mol
n O2=\(\dfrac{0,896}{22,4}\)=0,04 mol
=>m Fe=0,06.56=3,36g
=>m Fe3O4=0,02.232=4,64g