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a, \(V_{O_2}=61,6.20\%=12,32\left(l\right)\Rightarrow n_{O_2}=\dfrac{12,32}{22,4}=0,55\left(mol\right)\)
PT: \(2C_2H_6+7O_2\underrightarrow{t^o}4CO_2+6H_2O\)
\(C_3H_4+4O_2\underrightarrow{t^o}3CO_2+2H_2O\)
Ta có: \(n_{C_2H_6}+n_{C_3H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)
Theo PT: \(n_{O_2}=\dfrac{7}{2}n_{C_2H_6}+4n_{C_3H_4}=0,55\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_6}=0,1\left(mol\right)\\n_{C_3H_4}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_6}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{C_3H_4}\approx33,33\%\end{matrix}\right.\)
b, \(C_3H_4+2Br_2\rightarrow C_3H_4Br_4\)
Ta có: \(n_{Br_2}=2n_{C_3H_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{Br_2}=0,1.60=16\left(g\right)\Rightarrow m_{ddBr_2}=\dfrac{16}{8\%}=200\left(g\right)\)
n Br2=\(\dfrac{32}{160}\)=0,2 mol
C2H2+2Br2->C2H2Br4
0,1------0,2 mol
=>%VC2H2=\(\dfrac{0,1.22,4}{5,6}\).100=40%
=>%VCH4=100-40=60%
=>n CH4=\(\dfrac{5,6-0,1.22,4}{22,4}\)=0,15 mol
CH4+2O2-to>CO2+2H2O
0,15----0,3
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
0,1-----0,25 mol
=>VO2=(0,3+0,25).22,4=12,32l
CH4+2O2-to>CO2+2H2O
x------2x---------x
C2H4+3O2-to>2CO2+2H2O
y----------3y--------2y
=>\(\left\{{}\begin{matrix}x+y=\dfrac{5,6}{22,4}\\2x+3y=\dfrac{13,44}{22,4}\end{matrix}\right.\)
=>x=0,15 mol , y=0,1 mol
=>%VCH4=\(\dfrac{0,15.22,4}{5,6}\).100=60%
=>%VC2H4=100-60=40%
b)
VCO2=(0,15+0,1.2).22,4=7,84l
mhh khí = 5,6/22,4 = 0,25 (mol)
nO2 = 13,44/22,4 = 0,6 (mol)
Gọi nC2H4 = a (mol); nCH4 = b (mol)
a + b = 0,25 (1)
PTHH:
C2H4 + 3O2 -> (t°) 2CO2 + 2H2O
Mol: a ---> 3a ---> 2a
CH4 + 2O2 -> (t°) CO2 + 2H2O
Mol: b ---> 2b ---> b
3a + 2b = 0,6 (2)
(1)(2) => a = 0,1 (mol); b = 0,15 (mol)
%VC2H4 = 0,1/0,25 = 40%
%VCH4 = 100% - 40% = 60%
VCO2 = (0,1 . 2 + 0,15) . 22,4 = 7,84 (l)
a, \(n_{CH_4}=\dfrac{33,6.60\%}{22,4}=0,9\left(mol\right)\)
\(n_{C_2H_6}=\dfrac{33,6.40\%}{22,4}=0,6\left(mol\right)\)
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(2C_2H_6+7O_2\underrightarrow{t^o}4CO_2+6H_2O\)
Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{7}{2}n_{C_2H_6}=3,9\left(mol\right)\Rightarrow V_{O_2}=3,9.22,4=87,36\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=436,8\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{CO_2}=n_{CH_4}+2n_{C_2H_6}=2,1\left(mol\right)\\n_{H_2O}=2n_{CH_4}+3n_{C_2H_6}=3,6\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{CO_2}=2,1.44=92,4\left(g\right)\)
\(m_{H_2O}=3,6.18=64,8\left(g\right)\)
c, \(\overline{M_X}=\dfrac{0,9.16+0,6.30}{0,9+0,6}=21,6\left(g/mol\right)\)
\(\Rightarrow d_{X/H_2}=\dfrac{21,6}{2}=10,8\)
\(28ml=0,028l\)
\(67,2ml=0,0672l\)
Giả sử ta đo ở đktc
Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_2}=y\end{matrix}\right.\)
\(n_{hh}=\dfrac{0,028}{22,4}=0,00125mol\)
\(n_{O_2}=\dfrac{0,0672}{22,4}=0,003mol\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
x 2x ( mol )
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
y 5/2 y ( mol )
Ta có:
\(\left\{{}\begin{matrix}x+y=0,00125\\2x+\dfrac{5}{2}y=0,003\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,00025\\y=0,001\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,00025}{0,00125}.100=20\%\\\%V_{C_2H_2}=100\%-20\%=80\%\end{matrix}\right.\)
=> Chọn A
nBr2= 16/160=0,1 mol
Chỉ có etilen bị hấp thụ bởi brom nên có pt
C2H4+br2---->c2h4br2
0,1<---0,1
nc2h4=0,1 =>Vc2h4= 0,1.22,4=2,24
%Vc2h4= 2,24/5,6 .100%=40%
=>% Vch4=100%-40%=60%
m c2h4=0,1.28=2,8 gam
\(n_{hh.khí}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\\ n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right)\\ C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Khí metan không tác dụng với dd Br2
\(n_{C_2H_4}=n_{Br_2}=0,025\left(mol\right)\)
Vì số mol tỉ lệ thuận với thể tích. Nên:
\(\%V_{C_2H_4}=\%n_{C_2H_4}=\dfrac{0,025}{0,125}.100=20\%\\ \Rightarrow\%V_{CH_4}=100\%-20\%=80\%\)
Vậy chọn D
Chúc em học tốt và có được POP!
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(n_{Br_2}=\dfrac{4}{160}=0,025mol\)
\(V_{Br_2}=0,025.22,4=0,56l\)
\(\%V_{C_2H_4}=\dfrac{0,56.100}{2,8}=20\%\)
\(n_{hh}=\dfrac{2,8}{22,4}=0,125mol\)
\(n_{Br_2}=\dfrac{4}{160}=0,025mol\)
\(n_{Br_2}=n_{C_2H_4}=0,025mol\)
\(\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100=20\%\)
\(V_{CH_4}=100\%-20\%=80\%\)
=> Chọn D
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> a + b = \(\dfrac{1,68}{22,4}=0,075\left(mol\right)\) (1)
\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
=> a + 2b = 0,1 (2)
(1)(2) => a = 0,05 (mol); b = 0,025 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,075}.100\%=66,67\%\\\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100\%=33,33\%\end{matrix}\right.\)
c)
PTHH: C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,025-->0,0625
=> VO2 = (0,15 + 0,0625).22,4 = 4,76 (l)
a.b.\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)
\(n_{hh}=\dfrac{1,68}{22,4}=0,075mol\)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
x 2x ( mol )
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\2x+y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,025\\y=0,05\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100=33,33\%\)
\(\%V_{C_2H_4}=100\%-33,33\%=66,67\%\)
c.
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,025 0,0625 ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,05 0,15 ( mol )
\(V_{O_2}=\left(0,0625+0,15\right).22,4=4,76l\)
