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a)
$4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
$S + O_2 \xrightarrow{t^o} SO_2$
b) Gọi $n_P = a(mol) ; n_S = b(mol) \Rightarrow 31a + 32b = 15,6(1)$
Theo PTHH :
$n_{O_2} = \dfrac{5}{4}n_P + n_S = \dfrac{5a}{4} + b = \dfrac{13,44}{22,4} = 0,6(2)$
Từ (1)(2) suy ra : a = 0,4 ; b = 0,1
$m_P = 0,4.31 = 12,4(gam)$
$m_S = 0,1.32 = 3,2(gam)$
c) $n_{P_2O_5} = \dfrac{1}{2}n_P = 0,2(mol) \Rightarrow m_{P_2O_5} = 0,2.142 = 28,4(gam)$
$n_{SO_2} = n_S = 0,1(mol) \Rightarrow V_{SO_2} = 0,1.22,4 = 2,24(lít)$
a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
a)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{H_2O}=\dfrac{1,8}{18}=0,1\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
0,1<-0,05<-------0,1
2CO + O2 --to--> 2CO2
0,2<--0,1-------->0,2
=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\V_{CO}=0,2.22,4=4,48\left(l\right)\end{matrix}\right.\)
b) \(m_{CO_2}=0,2.44=8,8\left(g\right)\)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{H_2O}=\dfrac{1,8}{18}=0,1mol\)
\(2CO+O_2\rightarrow2CO_2\)
a 0,5a a
\(2H_2+O_2\rightarrow2H_2O\)
0,1 0,05 \(\leftarrow\) 0,1
\(\Sigma n_{O_2}=0,5a+0,05=0,15\)
\(\Rightarrow a=n_{O_2\left(CO\right)}=0,2mol\)
\(V_{CO}=2\cdot0,2\cdot22,4=8,96l\)
\(V_{H_2}=0,1\cdot22,4=2,24l\)
\(m_{CO_2}=0,2\cdot44=8,8g\)
a. Ag không phản ứng nên ta có PTHH: \(2Mg+O_2\rightarrow^{t^o}2MgO\)
\(\rightarrow m_{O_2}=m_{hh}-m_{\mu\text{ối}}=18,8-15,6=3,2g\)
\(\rightarrow n_{O_2}=\frac{3,2}{32}=0,1mol\)
b. \(\rightarrow V_{O_2}=n.22,4=22,4.0,1=2,24l\)
\(\rightarrow V_{kk}=4,48.5=11,2l\)
c. Có \(n_{Mg}=2n_{O_2}=0,2l\)
\(\rightarrow m_{Mg}=0,2.24=4,8g\)
\(\rightarrow\%m_{Mg}=\frac{4,8.100}{15,6}\approx30,77\%\)
\(\rightarrow\%m_{Ag}=100\%-30,77\%=69,23\%\)
a) \(n_{SO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: S + O2 --to--> SO2
0,5<-0,5<------0,5
=> mS = 0,5.32 = 16(g)
=> \(\left\{{}\begin{matrix}\%m_S=\dfrac{16}{22,2}.100\%=72,07\%\\\%m_P=\dfrac{22,2-16}{22,2}.100\%=27,93\%\end{matrix}\right.\)
b) \(n_P=\dfrac{22,2-16}{31}=0,2\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
0,2-->0,25----->0,1
=> \(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,5<-------------------0,75
=> \(m_{KClO_3}=0,5.122,5=61,25\left(g\right)\)
a) PTHH:
\(S+O_2\rightarrow\left(t^o\right)SO_2\\ 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\)
- Chất khí mùi hắc là SO2
- Chất rắn sau phản ứng có m(g) là P2O5
Đặt: nS=a(mol); nP=b(mol) (a,b>0) (nguyên, dương)
\(\Rightarrow\left\{{}\begin{matrix}32a+31b=22,2\\22,4a=11,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,2\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_S=\dfrac{0,5.32}{22,2}.100\approx72,072\%\\\%m_P\approx100\%-72,072\%\approx27,928\%\end{matrix}\right.\)
b)
\(n_{O_2}=a+\dfrac{5}{4}b=0,5+\dfrac{5}{4}.0,2=0,75\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,75.22,4=16,8\left(l\right)\)
c)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2.0,75}{3}=0,5\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.0,5=61,25\left(g\right)\)
\(n_{CO_2}=\dfrac{8.8}{44}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{9.6}{32}=0.3\left(mol\right)\)
\(2CO+O_2\underrightarrow{t^0}2CO_2\)
\(0.2.......0.1.......0.2\)
\(2H_2+O_2\underrightarrow{t^0}2H_2O\)
\(0.4......0.3-0.1\)
\(\%m_{CO}=\dfrac{0.2\cdot28}{0.2\cdot28+0.4\cdot2}\cdot100\%=87.5\%\)
\(\%m_{H_2}=100-87.5=12.5\%\)
a)
\(2CO + O_2 \xrightarrow{t^o} 2CO_2(1)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O(2) \)
b)
\(n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)\)
Theo PTHH :
\(n_{CO} = n_{CO_2} = 0,2(mol)\\ n_{O_2(1)} = \dfrac{1}{2}n_{CO_2} = 0,1(mol)\\ n_{H_2} = 2n_{O_2(2)} = 2(0,3-0,1) = 0,4(mol)\)
Vậy :
\(\%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\% = 87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
a/ \(2CO\left(0,2\right)+O_2\left(0,1\right)\rightarrow2CO_2\left(0,2\right)\)
\(2H_2\left(0,1\right)+O_2\left(0,05\right)\rightarrow2H_2O\left(0,1\right)\)
\(n_{H_2O}=\frac{1,8}{18}=0,1\)
\(n_{O_2}=\frac{3,36}{22,4}=0,15\)
Số mol O2 phản ứng ở phản ứng đầu là: \(0,15-0,05=0,1\)
\(\Rightarrow m_{CO_2}=0,2.44=8,8\)
b/ \(m_{CO}=0,2.28=5,6\)
\(m_{H_2}=0,1.2=0,2\)
c/ \(\%CO=\frac{0,2}{0,3}.100\%=66,67\%\)
\(\Rightarrow\%H_2=100\%-66,67\%=33,33\%\)
\(m_{Al}=27,8.19,2\%=5,4\left(g\right)\\ m_{Fe}=27,8-5,4=22,4\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\end{matrix}\right.\)
PTHH:
4Al + 3O2 --to--> 2Al2O3
0,2-->0,15------->0,1
3Fe + 2O2 --to--> Fe3O4
0,4-->4/15--------->2/15
\(\rightarrow\left\{{}\begin{matrix}V_{kk}=\left(0,15+\dfrac{4}{15}\right).22,4.5=\dfrac{140}{3}\left(l\right)\\m_{Cran}=0,1.102+\dfrac{2}{15}.232=\dfrac{617}{15}\left(g\right)\end{matrix}\right.\)
mAl=27,8.19,42%=5,4g
⇒nAl=\(\dfrac{5,4}{27}\)=0,2mol
⇒nFe=\(\dfrac{27,8-5,4}{56}\)=0,4mol
4Al+3O2to→2Al2O34
3Fe+2O2to→Fe3O4
⇒nO2=\(\dfrac{3}{4}\)nAl+\(\dfrac{2}{3}\)nFe=\(\dfrac{5}{12}\)mol
⇒Vkk=\(\dfrac{5}{12}\).22,4.5=46,67l
b,
mrắn=27,8+mO2=27,8+\(\dfrac{5}{12}\)32=41,1g
\(a)\\ 2CO + O_2 \xrightarrow{t^o} 2CO\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{H_2} = n_{H_2O} = \dfrac{1,8}{18} = 0,1(mol)\\ \)
Theo PTHH :
\(2n_{O_2} = n_{CO} + n_{H_2}\\ \Leftrightarrow 2.\dfrac{3,36}{22,4} = n_{CO} + 0,1\\ \Leftrightarrow n_{CO} = 0,2(mol)\\ \%V_{H_2} = \dfrac{0,1}{0,1+ 0,2}.100\% = 33,33\%\\ \%V_{CO} = 100\%-33,33\% = 66,67\%\\ c) Cách\ 1 :\\ n_{CO_2} = n_{CO} = 0,2(mol)\\ m_{CO_2} = 0,2.44 = 8,8(gam)\\ Cách\ 2 : \\ m_{hh} = m_{CO} + m_{H_2} = 0,2.28 + 0,1.2 = 5,8(gam) \)
Bảo toàn khối lượng :
\(m_{hh} + m_{O_2} = m_{H_2O} + m_{CO_2}\\ \Rightarrow m_{CO_2} = 5,8 + 0,15.32 - 1,8 = 8,8(gam)\)
