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\(n_{Cu}=\dfrac{6,4}{64}=0,1mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 ( mol )
\(\left\{{}\begin{matrix}m_{CuO}=0,1.80=8g\\m_{FeO}=12-8=4g\end{matrix}\right.\)
Bài 3 :
\(a) n_{CuO} = a(mol) ; n_{Fe_2O_3} = b(mol)\\ \Rightarrow 80a + 160b = 36(1)\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + H_2O\\ n_{Cu} = n_{CuO} = a(mol)\\ n_{Fe} = 2n_{Fe_2O_3} = 2b(mol)\\ \Rightarrow 64a = 4.2b.56(2)\\ (1)(2) \Rightarrow a = 0,35 ; b = 0,05\\ m_{CuO} = 0,35.80 = 28(gam)\\ m_{Fe_2O_3} = 0,05.160 = 8(gam)\\ b) n_{H_2} = a + 3b = 0,5(mol) \Rightarrow V_{H_2} = 0,5.22,4 = 11,2(lít)\)
\(c) Fe + 2HCl \to FeCl_2 + H_2\\ n_{HCl} = 2n_{Fe} = 0,1.2 = 0,2(mol)\\ \Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{10,95\%} = 66,67(gam)\)
Bài 4 :
\(a) Zn + 2HCl \to ZnCl_2 + H_2\\ n_{H_2} = n_{Zn} = \dfrac{1,95}{65} = 0,03(mol)\\ V_{H_2} = 0,03.22,4= 0,672(lít)\\ b) n_{HCl} =2 n_{H_2} = 0,06(mol)\\ \Rightarrow C\%_{HCl} = \dfrac{0,06.36,5}{120}.100\% = 1,825\%\\ m_{dd\ sau\ pư} = 1,95 + 120 - 0,03.2 = 121,89(gam)\\ \Rightarrow C\%_{ZnCl_2} = \dfrac{0,03.136}{121,89}.100\% = 3,35\%\)
PT: Fe2O3+3H2to→2Fe+3H2O
CuO+H2to→Cu+H2O
a, Ta có: mFe2O3=20.60%=12(g)
⇒nFe2O3=\(\dfrac{12}{160}\)=0,075(mol
mCuO=20−12=8(g
⇒nCuO=\(\dfrac{8}{80}\)=0,1(mol)
Theo pT:
nFe=2nFe2O3=0,15(mol)
nCu=nCuO=0,1(mol)
⇒mFe=0,15.56=8,4(g)
mCu=0,1.64=6,4(g)
b, Theo PT: nH2=3nFe2O3+nCuO=0,325(mol)
⇒VH2=0,325.22,4=7,28(l)
c. Zn+2HCl->ZnCl2+H2
0,65----------0,325
=>m HCl=0,65.36,5=23,725g
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,3 0,3 ( mol )
\(m_{CuO}=0,3.80=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\)
\(\%m_{CuO}=\dfrac{24}{40}.100=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,3
\(\Rightarrow n_{CuO}=0,3\Rightarrow m_{CuO}=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\Rightarrow n_{Fe_2O_3}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\%m_{CuO}=\dfrac{24}{40}\cdot100\%=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(m_{CuO}=50.20\%=10\left(g\right)\)
\(n_{CuO}=\dfrac{10}{80}=0,125\left(mol\right)\)
\(m_{Fe_2O_3}=50-10=40\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{40}{160}=0,25\left(mol\right)\)
PTHH :
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,125 0,125 0,125
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,25 0,75 0,5
\(a,V_{H_2}=\left(0,75+0,125\right).22,4=19,6\left(l\right)\)
\(b,m_{Cu}=0,125.64=8\left(g\right)\)
\(m_{Fe}=0,5.56=28\left(g\right)\)
a)
FeO + H2 --to--> Fe + H2O
CuO + H2 --to--> Cu + H2O
b) \(n_{Cu}=\dfrac{6,4}{64}=0,1\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1<--0,1<-----0,1
=> \(m_{FeO}=12-0,1.80=4\left(g\right)\)
=> \(n_{FeO}=\dfrac{4}{72}=\dfrac{1}{18}\left(mol\right)\)
FeO + H2 --to--> Fe + H2O
\(\dfrac{1}{18}\)-->\(\dfrac{1}{18}\)----->\(\dfrac{1}{18}\)
=> \(V_{H_2}=\left(0,1+\dfrac{1}{18}\right).22,4=\dfrac{784}{225}\left(l\right)\)
c) \(m_{Fe}=\dfrac{1}{18}.56=\dfrac{28}{9}\left(g\right)\)
d) \(\left\{{}\begin{matrix}m_{CuO}=0,1.80=8\left(g\right)\\m_{FeO}=4\left(g\right)\end{matrix}\right.\)