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\(Mg+2HCl\rightarrow MgCl_2+H_2\)
x 2x x x
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
y 2y y y
\(\left\{{}\begin{matrix}x+y=0,5\\24x+56y=23,2\end{matrix}\right.\)
\(\Leftrightarrow x=0,15;y=0,35\)
\(a,m_{Mg}=0,15.24=3,6\left(g\right)\)
\(m_{Fe}=19,6\left(g\right)\)
\(b,m_{HCl}=\left(0,3+0,7\right).36,5=36,5\left(g\right)\)
\(m_{ddHCl}=1,14.200=228\left(g\right)\)
\(C\%=\dfrac{36,5}{228}.100\%=16\%\)
\(a.n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\\ n_{Mg}=a;n_{Fe}=b\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+56b=23,2\\a+b=0,5\end{matrix}\right.\\ \Rightarrow a=0,15;b=0,35mol\\ m_{Mg}=0,15.24=3,6g\\ m_{Fe}=23,2-3,6=19,6g\\ b.m_{HCl}=\left(0,15+0,35\right).2.36,5=36,5g\\ m_{ddHCl}=1,14.200=228g\\ C_{\%HCl}=\dfrac{36,5}{228}\cdot100=16,01\%\)
a, Gọi: \(\left\{{}\begin{matrix}n_{Ca\left(OH\right)_2}=x\left(mol\right)\\n_{KOH}=y\left(mol\right)\end{matrix}\right.\) ⇒ 74x + 56y = 7,62 (1)
PT: \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
\(KOH+HCl\rightarrow KCl+H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}+n_{KOH}=2x+y=\dfrac{31,025.30\%}{36,5}=0,17\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,05\left(mol\right)\\y=0,07\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Ca\left(OH\right)_2}=0,05.74=3,7\left(g\right)\\m_{KOH}=0,07.56=3,92\left(g\right)\end{matrix}\right.\)
b, \(V_{ddHCl}=\dfrac{31,025}{1,04}\approx29,83\left(ml\right)=0,02983\left(l\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,17}{0,02983}\approx5,7\left(M\right)\)
\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,25\left(mol\right)\)
a, \(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c, \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{20\%}=91,25\left(g\right)\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,25.56=14\left(g\right)\)
mCu = 20,4 - 14 = 6,4 (g)
b, \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{14}{20,4}.100\%\approx68,63\%\\\%m_{Cu}\approx31,37\%\end{matrix}\right.\)
c, Theo PT: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)
\(\Rightarrow C\%_{HCl}=\dfrac{0,5.36,5}{200}.100\%=9,125\%\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2-->0,4----->0,2------->0,2
a
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b
\(CM_{MgCl_2}=\dfrac{0,2}{0,2}=1M\)
c
\(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
0,2------>0,4
\(V_{dd.NaOH}=\dfrac{0,4}{2}=0,2\left(l\right)\)
Bài 2
Gọi x, y là số mol củaCuO và ZnOmol HCl=3.0,1=0,3mol(100ml=0,1l)
CuO+2HCl->CuCl2+H2O (1)
xmol 2xmol
ZnO+2HCl->ZnCl2+H2O(2)
ymol 2ymol
Từ 1 và 2 ta co hệ phương trình
2x+2y=0,3 ->x=0,05=molCuO
80x+81y=12,1 ->y=0,1=molZnO
=>mCuO=0,05.80=4g
->%CuO=(4.100)/12,1=33,075%
->%ZnO=100-33,075=66,943%
b. CuO+H2SO4->CuSO4+H2O (3)
Theo ptpu 3 taco nH2SO4=nCuO=0,05 mol
ZnO+H2SO4->ZnSO4+H2O (4)
Theo ptpu 4 ta co nH2SO4=nZnO=0,1mol
=>nH2SO4=0.05+0,1=0,15mol
->mH2SO4=0,15.98=14,7g
=>mddH2SO4=(14,7.100)/20=73,5g
Bài 1
a/. Phương trình phản ứng hoá học:
Fe + 2HCl --> FeCl2 + H2
b/. nH2 = V/22,4 = 3,36/22,4 = 0,15 (mol)
....... Fe.....+ 2HCl --> Fecl2 + H2
TPT 1 mol....2 mol.................1 mol
TDB x mol....y mol................0,15 mol
nFe = x = (0,15x1)/1 = 0,15 (mol)
mFe = n x M = 0,15 x 56 = 8,4 (g)
c/. nHCl = y = (0,15x2)/1 = 0,3 (mol)
CMHCl = n/V = 0,3/0,05 = 6 (M)
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
b+c) Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,3\left(mol\right)\\n_{HCl}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{HCl}=0,6\cdot36,5=21,9\left(g\right)\\V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\end{matrix}\right.\)
d) PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) HCl còn dư, NaOH p/ứ hết
\(\Rightarrow\) Dung dịch sau p/ứ làm quỳ tím hóa đỏ
Theo PTHH: \(\left\{{}\begin{matrix}n_{NaCl}=0,5\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,5\cdot58,5=29,25\left(g\right)\\m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddHCl}+m_{NaOH}=\dfrac{0,6\cdot36,5}{5\%}+20=458\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{NaCl}=\dfrac{29,25}{458}\cdot100\%\approx6,39\%\\C\%_{HCl\left(dư\right)}=\dfrac{3,65}{458}\cdot100\%\approx0,8\%\end{matrix}\right.\)
a) PTHH : \(Mg+2HCl-->MgCl_2+H_2\) (1)
\(Fe+2HCl-->FeCl_2+H_2\) (2)
Theo PTHH (1) và (2) : \(n_{HCl}=2n_{H2}=2.\dfrac{4,48}{22,4}=0.4\left(mol\right)\)
\(\Rightarrow n_{HCl\left(can.dung\right)}=0,4:100.\left(100+10\right)=0,44\left(mol\right)\)
\(\Rightarrow C_{M\left(ddHCl\right)}=\dfrac{0,44}{0,1}=4,4M\)
b) Có : \(n_{HCl\left(dư\right)}=0,44-0,4=0,04\left(mol\right)\)
Đặt \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\) => 24x + 56y = 8 (*)
Theo pthh (1) và (2) : \(\Sigma n_{H2}=n_{Mg}+n_{Fe}\)
\(\Rightarrow\dfrac{4,48}{22,4}=0,2=x+y\) (**)
Từ (*) và (**) suy ra : \(\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
Theo PTHH (1) và (2) :
\(n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\)
\(n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M\left(MgCl2\right)}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M\left(FeCl2\right)}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M\left(HCl.dư\right)}=\dfrac{0,04}{0,1}=0,4\left(M\right)\end{matrix}\right.\)
Mg + 2HCl → MgCl2 + H2
Fe + 2HCl → FeCl2 + H2
nH2 = \(\dfrac{4,48}{22,4}\)=0,2 mol
Đặt số mol Mg, Fe lần lượt là x và y mol ta có hệ pt:
\(\left\{{}\begin{matrix}x+y=0,2\\24x+56=8\end{matrix}\right.\)=> x = y = 0,1 mol
Theo pt => nHCl cần dùng = 0,1.2 + 0,1.2 = 0,4 mol
Nồng độ HCl cần dùng = \(\dfrac{0,4}{0,1}\)= 4M
b)
CFeCl2 = \(\dfrac{n}{V}\)= \(\dfrac{0,1}{0,1}\)= 1M , CMgCl2 = \(\dfrac{0,1}{0,1}\)= 1M
HCl dùng dư 10% so với lượng cần phản ứng là 0,4mol => nHCl dư = 0,4.10% = 0,04 mol
=> CHCl dư = \(\dfrac{0,04}{0,1}\)= 0,4 M