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a, \(2HCl+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)
b, \(n_{HCl}=0,06.0,1=0,006\left(mol\right)\)
Theo PT: \(n_{Ba\left(OH\right)_2}=\dfrac{1}{2}n_{HCl}=0,003\left(mol\right)\)
\(\Rightarrow V_{Ba\left(OH\right)_2}=\dfrac{0,003}{0,2}=0,015\left(l\right)=15\left(ml\right)\)
c, \(n_{BaCl_2}=\dfrac{1}{2}n_{Ba\left(OH\right)_2}=0,003\left(mol\right)\Rightarrow C_{M_{BaCl_2}}=\dfrac{0,003}{0,06+0,015}=0,04\left(M\right)\)
PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\downarrow\)
a+b) Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,2\left(mol\right)=n_{KOH}\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2\cdot36,5}{300}\cdot100\%\approx2,43\%\\C_{M_{KOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)
c) PTHH: \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Theo các PTHH: \(n_{CuO\left(lý.thuyết\right)}=n_{Cu\left(OH\right)_2}=n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow n_{CuO}=0,1\cdot95\%=0,095\left(mol\right)\) \(\Rightarrow m_{CuO}=0,095\cdot80=7,6\left(g\right)\)
Gọi: \(\left\{{}\begin{matrix}n_{FeCl_3}=x\left(mol\right)\\n_{MgCl_2}=y\left(mol\right)\end{matrix}\right.\)
PT: \(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_{3\downarrow}+3KCl\)
______x_________3x_________x (mol)
\(MgCl_2+2KOH\rightarrow Mg\left(OH\right)_{2\downarrow}+2KCl\)
____y_________2y_________y (mol)
Ta có: \(n_{KOH}=0,2.2,5=0,5\left(mol\right)\)
⇒ 3x + 2y = 0,5 (1)
m kết tủa = 16,5 ⇒ 107x + 58y = 16,5 (2)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
\(\Rightarrow C_{M_{FeCl_3}}=C_{M_{MgCl_2}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)
\(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_3\downarrow+3KCl\\ MgCl_2+2KOH\rightarrow Mg\left(OH\right)_2\downarrow+2KCl\)
\(n_{KOH}=0,2\cdot2,5=0,5\left(mol\right)\)
Đặt nFeCl₃ trong 500ml X là a mol, nMgCl₂ trong 500ml X là b mol
\(\Rightarrow\left\{{}\begin{matrix}3a+2b=0,5\\107a+58b=16,5\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow C_MFeCl_3=\dfrac{0,1}{0,5}=0,2\left(M\right)\\ C_MMgCl_2=\dfrac{0,1}{0,5}=0,2\left(M\right)\)
a, \(n_{KOH}=0,3.1=0,3\left(mol\right)\)
PT: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Theo PT: \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,15\left(mol\right)\)
\(\Rightarrow m_{K_2SO_4}=0,15.174=26,1\left(g\right)\)
b, \(C_{M_{K_2SO_4}}=\dfrac{0,3}{0,3+0,2}=0,6\left(M\right)\)
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(n_{KOH}=0,2\cdot0,5=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=n_{K_2SO_4}=0,05\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\\C_{M_{K_2SO_4}}=\dfrac{0,05}{0,2+0,1}\approx0,17\left(M\right)\end{matrix}\right.\)
Bài 1 :
200ml = 0,2l
100ml = 0,1l
\(n_{KOH}=0,5.0,2=0,1\left(mol\right)\)
a) Pt : \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O|\)
2 1 1 2
0,1 0,05 0,05
b) \(n_{H2SO4}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(C_{M_{ddH2SO4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
c) \(n_{K2SO4}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{ddspu}=0,2+0,1=0,3\left(l\right)\)
\(C_{M_{K2SO4}}=\dfrac{0,05}{0,3}=\dfrac{1}{6}\left(M\right)\)
Chúc bạn học tốt
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
1 1 1 1
0,3 0,3 0,3 0,3
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
a). \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
⇒\(V_{H2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
b). \(80ml=0,08l\)
\(n_{H2SO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{0,08}=3,75\left(M\right)\)
c). \(n_{MgSO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{MgSO4}=n.22,4=0,3.22,4=6,72\left(l\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{6,72}=0,04\left(M\right)\)
d). \(MgSO_4+Ba\left(OH\right)_2\rightarrow Mg\left(OH\right)_2+BaSO_4\downarrow\)
1 1 1 1
0,3 0,3 0,3
\(n_{BaSO4\uparrow}=\dfrac{0,3.1}{1}\)=0,3(mol)
→\(m_{BaSO4\downarrow}=n.M=0,3.233=69,9\left(g\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{0,3.1}{1}\)=0,3(mol)
\(\rightarrow V_{ddBa\left(OH\right)_2}=\dfrac{n}{C_M}=\dfrac{0,3}{1,6}=0,1875\left(l\right)\)
a, \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(FeCl_3+3KOH\rightarrow3KCl+Fe\left(OH\right)_{3\downarrow}\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=6n_{Fe_2O_3}=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
b, \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=2n_{Fe_2O_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{Fe\left(OH\right)_3}=0,2.107=21,4\left(g\right)\)
\(n_{KOH}=3n_{FeCl_3}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
a, \(H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
b, \(n_{KOH}=0,12.0,4=0,048\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,024\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,024}{0,08}=0,3\left(M\right)\)
c, \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,024\left(mol\right)\)
\(\Rightarrow C_{M_{K_2SO_4}}=\dfrac{0,024}{0,08+0,12}=0,12\left(M\right)\)