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Em xem lại đề nha sao lại 2 muối BaCl và BaCl2 được nhỉ?
a, Ta có: 27nAl + 56nFe = 0,83 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow n_{Al}=n_{Fe}=0,01\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{0,83}.100\%\approx32,53\%\\\%m_{Fe}\approx67,47\%\end{matrix}\right.\)
b, nH2SO4 = nH2 = 0,025 (mol)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,025.98}{20\%}=12,25\left(g\right)\)
\(n_{Na_2O}=\dfrac{6,2}{62}=0,1 \left(mol\right)\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
0,1 -----------------> 0,1
\(CM_{base}=CM_{NaOH}=\dfrac{0,1}{0,2}=0,5M\)
b
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,05 <------ 0,1
\(V_{H_2SO_4}=\dfrac{0,05}{0,2}=0,25\left(l\right)\Rightarrow V_{dd.H_2SO_4}=\dfrac{0,25.100}{20}=1,25\left(l\right)\)
a, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: 40nNaOH + 56nKOH = 25,44 (1)
\(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}+\dfrac{1}{2}n_{KOH}=0,3.0,9=0,27\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,3\left(mol\right)\\n_{KOH}=0,24\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,3.40=12\left(g\right)\\m_{KOH}=0,24.56=13,44\left(g\right)\end{matrix}\right.\)
b, \(m_{ddH_2SO_4}=300.1,14=342\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{0,27.98}{342}.100\%\approx7,74\%\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
2a______3a__________a_______3a (mol)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
b_______b________b______b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}27\cdot2a+24b=7,8\\3a+b=\dfrac{200\cdot19,6\%}{98}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,1\cdot24=2,4\left(g\right)\\m_{Al}=5,4\left(g\right)\\n_{Al_2\left(SO_4\right)_3}=0,1\left(mol\right)=n_{MgSO_4}\\n_{H_2}=0,4\left(mol\right)\Rightarrow m_{H_2}=0,4\cdot2=0,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=207\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1\cdot342}{207}\cdot100\%\approx16,52\%\\C\%_{MgSO_4}=\dfrac{0,1\cdot120}{207}\cdot100\%\approx5,8\%\end{matrix}\right.\)
\(a.n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ Đặt:\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ \rightarrow\left\{{}\begin{matrix}27a+24b=5,1\\1,5a+b=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \left\{{}\begin{matrix}\%m_{Al}=\dfrac{27.0,1}{5,1}.100\approx52,941\%\\\%m_{Mg}\approx47,059\%\end{matrix}\right.\)
\(b.m_{ddH_2SO_4}=\dfrac{0,25.98.100}{9,8}=250\left(g\right)\\ m_{ddsau}=m_{Al,Mg}+m_{ddH_2SO_4}-m_{H_2}=5,1+250-0,25.2=254,6\left(g\right)\\ C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342}{254,6}.100\approx6,716\%\\ C\%_{ddMgSO_4}=\dfrac{0,1.120}{254,6}.100\approx4,713\%\)
a)
Gọi $n_{CaCO_3} = a ; n_{MgCO_3} = b$
$\Rightarrow 100a + 84b = 4,68(1)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$MgCO_3 + 2HCl \to MgCl_2 +C O_2 + H_2O$
$n_{CO_2} = a + b = 0,05(2)$
Từ (1)(2) suy ra a = 0,03 ; b = 0,02
$\%m_{CaCO_3} = \dfrac{0,03.100}{4,68}.100\% = 64,1\%$
$\%m_{MgCO_3} = 35,9\%$
$m_{CaCl_2} = 0,03.111 = 3,33(gam)$
$m_{MgCl_2} = 0,02.95 = 1,9(gam)$
b)
$n_{HCl} = 2n_{CO_2} = 0,1(mol)$
$C_{M_{HCl}} = \dfrac{0,1}{0,25} = 0,4M$
a) nBaSO4=0,1(mol)
PTHH: Ba(OH)2 + H2SO4 -> BaSO4 + 2 H2O
2 NaOH + H2SO4 -> Na2SO4 + 2 H2O
=> nBa(OH)2= 0,1(mol) => mBa(OH)2=171.0,1=17,1(g)
%mBa(OH)2= (17,1/40).100=42,75%
=>%mNaOH=57,25%
b) mNaOH=22,9(g) => nNaOH= 22,9/40=0,5725(mol)
=> nH2SO4= 0,1+ 0,5725:2= 309/800(mol)
=>mH2SO4=309/800. 98=37,8525(g)
=>C%ddH2SO4= (37,8525/100).100=37,8525%