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\(n_{Na_2SO_3}=\dfrac{25,2}{126}=0,2(mol)\\ n_{HCl}=\dfrac{250.7,3\%}{100\%.36,5}=0,5(mol)\\ PTHH:Na_2SO_3+2HCl\to 2NaCl+H_2O+SO_2\uparrow\)
Vì \(\dfrac{n_{Na_2SO_3}}{1}<\dfrac{n_{HCl}}{2}\) nên \(HCl\) dư
\(a,n_{SO_2}=n_{Na_2SO_3}=0,2(mol)\\ \Rightarrow V_{SO_2}=0,2.22,4=4,48(l)\)
\(b,\) Chất tan trong dd sau phản ứng là \(NaCl\)
\(c,n_{NaCl}=2n_{Na_2SO_3}=0,4(mol)\\ \Rightarrow m_{NaCl}=0,4.58,5=23,4(g)\)
Bài 14 :
\(a) n_{CuO} = \dfrac{8}{80} = 0,1(mol)\\ CuO + 2HCl \to CuCl_2 + H_2O\\ n_{HCl} = 2n_{CuO} = 0,2(mol)\\ m_{dd\ HCl} = \dfrac{0,2.36,5}{7,3\%} = 100(gam)\\ b) \text{Chất tan : } CuCl_2\\ n_{CuCl_2} = n_{CuO} = 0,1(mol)\\ m_{CuCl_2} = 0,1.135 = 13,5(gam)\)
Bài 15 :
\(a) n_{Fe_2O_3} =\dfrac{4,8}{160} = 0,03(mol)\\ Fe_2O_3 + 3H_2SO_4 \to Fe_2(SO_4)_3 + 3H_2O\\ n_{H_2SO_4} = 3n_{Fe_2O_3} = 0,09(mol)\\ m_{dd\ H_2SO_4} = \dfrac{0,09.98}{9,8\%} = 90(gam)\\ b) \text{Chất tan : } Fe_2(SO_4)_3\\ n_{Fe_2(SO_4)_3} = n_{Fe_2O_3} = 0,03(mol)\\ m_{Fe_2(SO_4)_3} = 0,03.400 = 12(gam)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2mol\)
\(n_{HCl}=2,5.0,2=0,5mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 < 0,5 ( mol )
0,2 0,4 0,2 0,2 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65g\)
\(V_{H_2}=0,2.22,4=4,48l\)
\(C_{M_{FeCl_2}}=\dfrac{0,2}{0,2}=1M\)
a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(m_{HCl}=36,5.15\%=5,475\left(g\right)\Rightarrow n_{HCl}=\dfrac{5,475}{36,5}=0,15\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,15}{2}\), ta được Mg dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow V_{H_2}=0,075.22,4=1,68\left(l\right)\)
b, \(n_{Mg\left(pư\right)}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow n_{Mg\left(dư\right)}=0,1-0,075=0,025\left(mol\right)\)
\(\Rightarrow m_{Mg\left(dư\right)}=0,025.24=0,6\left(g\right)\)
c, - Cách 1:
\(n_{MgCl_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow m_{MgCl_2}=0,075.95=7,125\left(g\right)\)
- Cách 2:
Theo ĐLBT KL, có: mMg (pư) + mHCl = mMgCl2 + mH2
⇒ mMgCl2 = 2,4 - 0,6 + 5,475 - 0,075.2 = 7,125 (g)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,4
0,1 0,2
0 0,2 0,1 0,1
\(a,V_{H_2}=0,1.22,4=2,24\left(l\right)\\ b,m_{dd}=6,5+0,4.36,5+50-0,1.2=70,9\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,1.136}{70,9}.100\%=19,18\%\)
\(n_{Al}=\frac{2,7}{27}=o,1mol\)
n HCl = o,2 mol
2 Al +6 HCl →2AlCl3 + 3H2
bđ: 0,1
đang bận !
Fe + 2HCl -> FeCl2 + H2
nFe = 5,6/56 = 0,1 mol
=>nH2 = 0,1 mol
=> VH2= 0,1*22,4= 2,24 lít
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,1-->0,2------------------>0,1
=> \(\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,2.36,5}{15\%}=\dfrac{146}{3}\left(g\right)\\V_{H_2}=0,1.22,4=4,48\left(l\right)\end{matrix}\right.\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
Na2SO3+2HCl->2NaCl+H2O+SO2
0,201-------0,402------0,402---------------0.201
n Na2SO3=0,201 mol
m HCl=18,25 g
->n HCl=0,5 mol
=>HCl dư
=>VSO2=0,201.22,4=4,5024l
b)
mNaCl=\(\dfrac{0,402.58,5}{25,4+250-0,201.64}\).100=8,95%
m Hcl dư=\(\dfrac{0,098.36,5}{25,4+250-0,201.64}.100=1,36\%\)