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a
PTHH của phản ứng xảy ra:
\(Na_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2NaCl\)
b
\(n_{Na_2SO_4}=0,1.0,5=0,05\left(mol\right)\)
\(\Rightarrow n_{BaSO_4}=n_{Na_2SO_4}=0,05\left(mol\right)\) (dựa theo PTHH)
\(\Rightarrow m_{\downarrow}=m_{BaSO_4}=233.0,05=11,65\left(g\right)\)
c
Theo PTHH có: \(n_{BaCl_2\left(đã.dùng\right)}=n_{Na_2SO_4}=0,05\left(mol\right)\)
\(\Rightarrow CM_{BaCl_2}=\dfrac{n}{V}=\dfrac{0,05}{50:1000}=1M\)
a) Zn + 2HCl → ZnCl2 + H2
b) 25oC và 1bar ⇒ đkc
nZn = \(\dfrac{19,5}{65}\)= 0,3(mol)
nH2 = \(\dfrac{0,3.1}{1}\)=0,3(mol)
VH2 = 0,3 . 24,79 = 7,437(l)
c) 200 ml = 0,2l
CM ZnCl2 = \(\dfrac{0,3}{0,2}\)=1,5M
\(n_{H_2}=\dfrac{9,196}{24,79}=0,4\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{HCl}=2n_{H_2}=2.0,4=0,8\left(mol\right)\\ n_{Fe}=n_{H_2}=0,4\left(mol\right)\\ m_{Fe}=0,4.56=22,4\left(g\right)\\ C_{MddHCl}=\dfrac{0,8}{0,2}=4\left(M\right)\)
\(a.n_{Fe_2O_3}=\dfrac{32}{160}=0,2mol\\ Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,2 0,6 0,2 0,6
\(m_{Fe_2\left(SO_4\right)_3}=0,2.400=80g\\ b.m_{H_2SO_4}=0,6.98=58,8g\\ c)Fe_2\left(SO_4\right)_3+6NaOH\rightarrow3Na_2SO_3+2Fe\left(OH\right)_3\)
\(n_{Fe\left(OH\right)_3}=2.0,2=0,4mol\\ m_{Fe\left(OH\right)_3}=0,4.107=42,8g\)
`n_(Fe_2O_3)=m/M=32/160=0,2(mol)`
\(PTHH:Fe_2O_3+3H_2SO_4->Fe_2\left(SO_4\right)_3+3H_2O\)
tỉ lệ 1 : 3 : 1 ; 3
n(mol) 0,2--------->0,6------------>0,2------------->0,6
\(m_{Fe_2\left(SO_4\right)_3}=n\cdot M=0,2\cdot400=80\left(g\right)\)
\(m_{H_2SO_4}=n\cdot M=0,6\cdot98=58,8\left(g\right)\)
\(PTHH:Fe_2\left(SO_4\right)_3+6NaOH->2Fe\left(OH\right)_3+3Na_2SO_4\)
tỉ lệ 1 : 6 ; 2 ; 3
n(mol) 0,2------------->1,2------------->0,4---------->0,6
\(m_{Fe\left(OH\right)_3}=n\cdot M=0,4\cdot107=42,8\left(g\right)\)
Bài 1:
\(a)Mg+2HCl\rightarrow MgCl_2+H_2\\ Mg+H_2SO_4\rightarrow MgSO_4+H_2\\ b)Zn+2HCl\rightarrow ZnCl_2+H_2\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
Bài 2:
\(a)Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b)n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\\ n_{Fe}=n_{H_2SO_4}=n_{H_2}=0,15mol\\ m_{Fe}=0,15.56=8,4g\\ c)C_{M_{H_2SO_4}}=\dfrac{0,15}{0,05}=3M\)
\(Fe_2O_3=\dfrac{24}{160}=0,15\left(mol\right)\\ PTHH:Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,15\left(mol\right)\\ a,m_{Fe_2\left(SO_4\right)_3}=400.0,15=60\left(g\right)\\ b,n_{H_2SO_4}=3n_{Fe_2O_3}=3.0,15=0,45\left(mol\right)\\ C_{MddH_2SO_4}=\dfrac{0,45}{0,2}=2,25\left(M\right)\\ c,V_{ddsau}=V_{ddH_2SO_4}=0,2\left(l\right)\\ C_{MddFe_2\left(SO_4\right)_3}=\dfrac{0,15}{0,2}=0,75\left(M\right)\)