Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
a. Gọi n là hóa trị của kim loại R
\(2R+2nHCl\rightarrow2RCl_n+nH_2\)
TĐB: \(\dfrac{4,05}{R}\) - \(\dfrac{4,05n}{R}\) - \(\dfrac{4,05}{R}\) - \(\dfrac{2,025n}{R}\) (mol)
\(n_R=\dfrac{m}{M}=\dfrac{4,05}{R}\left(mol\right)\)
\(m_{H_2}=n.M=\dfrac{2,025n}{R}.2=\dfrac{4,05n}{R}\left(g\right)\)
\(m_{ddRCl_n}=m_R+m_{ddHCl}-m_{H_2}\)
\(116,1=4,05+112,5-\dfrac{4,05n}{R}\)
\(\dfrac{4,05n}{R}=116,55-116,1\)
\(\dfrac{4,05n}{R}=0,45\)
\(4,05n=0,45R\)
\(\dfrac{4,05}{0,45}=\dfrac{R}{n}\)
\(9=\dfrac{R}{n}\)
\(9n=R\)
Nếu \(n=1\Rightarrow R=9\) (loại)
\(n=2\Rightarrow R=18\) (loại)
\(n=3\Rightarrow R=27\) (chọn)
Vậy kim loại R là Al
b) Kim loại tìm được là Al (III)
\(2Al+6H_2SO_{4\left(đ,t^0\right)}\rightarrow Al_2\left(SO_4\right)_3+3SO_2+6H_2O\)
TĐB: \(0,15\) - \(0,45\) (mol)
\(n_{Al}=\dfrac{m}{M}=\dfrac{4,05}{27}=0,15\left(mol\right)\)
\(m_{H_2SO_4}=n.M=0,45.98=44,1\left(g\right)\)
m\(m_{ddH_2SO_4}=\dfrac{m_{ct}.100\%}{C\%}=\dfrac{44,1.100\%}{98\%}=45\left(g\right)\)
\(Fe+H_2SO_4 \to FeSO_4+H_2\\ n_{H_2}=0,15(mol)\\ a/\\ n_{Fe}=n_{H_2}=0,15(mol)\\ m_{Fe}=0,15.56=8,4(g)\\ b/\\ n_{H_2SO_4}=n_{H_2}=0,15(mol)\\ CM_{H_2SO_4}=\dfrac{0,15}{2}=0,75M c/\\ n_{FeSO_4}=n_{H_2}=0,15(mol)\\ CM_{FeSO_4}=\dfrac{0,15}{0,2}=0,75M\\\)
nHCl=0,3.2=0,6(mol)
a) PTHH: CuO +2 HCl -> CuCl2 + H2O
0,3_______________0,6___0,3(mol)
b) mCuO=0,3.80=24(g)
c) VddCuCl2=VddHCl=0,3(l)
=>CMddCuCl2=0,3/0,3=1(M)
d) m(muối)=0,3.135=40,5(g)
Bài 9 :
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05--->0,1-------->0,05
a) \(C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)
b) \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)
c) \(C_{MCuCl2}=\dfrac{0,05}{0,1}0,5\left(M\right)\)
Câu 10 :
\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
0,05-->0,1------->0,05
\(m_{ddHCl}=\dfrac{0,1.36,5}{10\%}100\%=36,5\left(g\right)\)
\(m_{ddspu}=3,6+36,5=40,1\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,05.127}{40,1}.100\%=15,84\%\)
\(a,PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\\ \Rightarrow m_{CuSO_4}=0,1\cdot160=16\left(g\right)\\ b,n_{H_2SO_4}=n_{CuO}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{H_2SO_4}}=0,1\cdot98=9,8\left(g\right)\\ \Rightarrow C\%_{H_2SO_4}=\dfrac{9,8}{200}\cdot100\%=4,9\%\)
Câu 1 :
\(n_{HCl}=\dfrac{73\cdot20\%}{36.5}=0.4\left(mol\right)\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(..........0.4.......0.2\)
\(m_{CuCl_2}=0.2\cdot135=27\left(g\right)\)
Câu 2 :
\(n_{Fe_2O_3}=\dfrac{2.4}{160}=0.015\left(mol\right)\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(0.015...........................0.015\)
\(m_{dd}=2.4+300=302.4\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0.015\cdot400}{302.4}\cdot100\%=1.98\%\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2(mol)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{Fe}=n_{H_2SO_4}=n_{Fe(OH)_2}=0,2(mol)\\ a,m_{Fe}=0,2.56=11,2(g)\\ b,C_{M_{H_2SO_4}}=\dfrac{0,2}{0,2}=1M\)
\(c,Ba(OH)_2+FeSO_4\to BaSO_4\downarrow+Fe(OH)_2\downarrow\\ n_{Ba(OH)_2}=\dfrac{250.17,1}{100.171}=0,25(mol)\\ LTL:\dfrac{0,2}{1}<\dfrac{0,25}{1}\Rightarrow Ba(OH)_2\text{ dư}\\ \Rightarrow n_{BaSO_4}=0,2(mol)\\ \Rightarrow m_{BaSO_4}=233.0,2=46,6(g)\)
a,\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: CaCO3 + 2HCl → CaCl2 + CO2 + H2O
Mol: 0,1 0,2 0,1
\(m_{CaCO_3}=0,1.100=10\left(g\right)\)
b,\(C\%_{ddHCl}=\dfrac{0,2.36,5.100\%}{150}=4,87\%\)
c,mdd sau pứ= 10+150-0,1.44 = 151,2 (g)
\(C\%_{ddCaCl_2}=\dfrac{0,1.111.100\%}{151,2}=7,34\%\)
\(n_{CuO}=\dfrac{1,6}{80}=0,02mol\)
CuO+H2SO4\(\rightarrow\)CuSO4+H2O
\(n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,02mol\)
\(m_{H_2SO_4}=0,02.98=1,96gam\)
\(m_{dd_{H_2SO_4}}=\dfrac{1,96.100}{0,98}=200g\)
\(m_{CuSO_4}=0,02.160=3,2g\)
\(m_{dd}=1,6+200=201,6g\)
C%H2SO4=\(\dfrac{3,2}{201,6}.100\%\approx1,6\%\)
a,khi cho CuO tác dụng với dd H2SO4 ta có ptth:
CuO+H2SO4\(\rightarrow\)CuSO4+H2O(1)
theo đề bài và pthh(1) ta có:n CuO=1,6:80=0,02(mol)
nCuO=nH2SO4=0,02(mol)
mH2SO4=0,02\(\times\)98=1,96(g)
mdd H2SO4(0,98%)=1,96:(0,98:100)=200(g)
Vậy khối lượng dd H2SO4 đã dùng là 200(g)
b,theo pthh (1) và đề bài ta lại có:nCuSO4=0,02(mol)
mCuSO4=0,02\(\times\)160=3,2(g)
m dd=1,6+200=201,6(g)
C% CuSO4=\(\dfrac{3,2}{201,6}\)\(\times\)100%\(\approx\)1,59%
vậy nồng độ dd thu được là 1,59%