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\(n_{H_2SO_4}=0.1\cdot2=0.2\left(mol\right)\)
\(m_{dd_{H_2SO_4}}=100\cdot1.2=120\left(g\right)\)
\(n_{BaCl_2}=0.1\cdot1=0.1\left(mol\right)\)
\(m_{dd_{BaCl_2}}=100\cdot1.32=132\left(g\right)\)
\(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)
\(0.1................0.1.........0.1...............0.2\)
\(\Rightarrow H_2SO_4dư\)
\(m_{BaSO_4}=0.1\cdot233=23.3\left(g\right)\)
\(V_{dd}=0.1+0.1=0.2\left(l\right)\)
\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.2-0.1}{0.2}=0.5\left(M\right)\)
\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)
\(m_{\text{dung dịch sau phản ứng}}=120+132-23.3=228.7\left(g\right)\)
\(C\%_{H_2SO_4\left(dư\right)}=\dfrac{0.1\cdot98}{228.7}\cdot100\%=4.28\%\)
\(C\%_{HCl}=\dfrac{0.2\cdot36.5}{228.7}\cdot100\%=3.2\%\)
a/
\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,15 0,3 (mol)
\(m_{NaOH}=0,3.40=12\left(g\right)\)
\(m_A=90,7+9,3=100\left(g\right)\)
\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)
b/
m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)
\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)
\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)
bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)
pư: 0,3 0,15 0,15 0,15 (mol)
dư: 0 \(\dfrac{23}{380}\) (mol)
\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)
\(m_C=100+200-13,5=286,5\left(g\right)\)
\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)
\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)
\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)
\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)
\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)
\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)
\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\\ n_{H_2SO_4}=\dfrac{19,6\%.200}{98}=0,4\left(mol\right)\\a, ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\\ b,Vì:\dfrac{0,1}{1}< \dfrac{0,4}{1}\\ \Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{ZnSO_4}=n_{ZnO}=0,1\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,4-0,1=0,3\left(mol\right)\\ \Rightarrow m_{H_2SO_4\left(dư\right)}=98.0,3=29,4\left(g\right)\\ c,n_{ZnSO_4}=0,1.161=16,1\left(g\right)\\ m_{ddsau}=m_{ZnO}+m_{ddH_2SO_4}=8,1+200=208,1\left(g\right)\\ \Rightarrow C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{29,4}{208,1}.100\approx14,128\%\\ C\%_{ddZnSO_4}=\dfrac{16,1}{208,1}.100\approx7,737\%\)
ZnO+H2SO4->ZnSO4+H2O
0,1-----0,1-------0,1-------0,1 mol
n ZnO=\(\dfrac{8,1}{81}\)=0,1 mol
m H2SO4 =39,2g =>n H2SO4=\(\dfrac{39,2}{98}\)=0,4 mol
=>H2SO4 , dư 0,3 mol
=>m H2SO4=0,3.98=29,4g
=>C%H2SO4 dư=\(\dfrac{29,4}{200+0,1.18}\).100=14,568%
=>C% ZnSO4=\(\dfrac{0,1.161}{200+0,1.18}.100=7,9781\%\)
nAl = \(\dfrac{5,4}{27}=0,2\) mol
mH2SO4 = \(\dfrac{4,9\times480}{100}=23,52\left(g\right)\)
=> nH2SO4 = \(\dfrac{23,52}{98}=0,24\) mol
Pt: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,16 mol<-0,24 mol-> 0,08 mol---> 0,24 mol
Xét tỉ lệ nol giữa Al và H2SO4:
\(\dfrac{0,2}{2}>\dfrac{0,24}{3}\)
Vậy Al dư
mAl dư = (0,2 - 0,16) . 27 = 1,08 (g)
mAl2(SO4)3 = 0,08 . 342 = 27,36 (g)
mdd sau pứ = mAl + mdd H2SO4 - mAl dư - mH2
...................= 5,4 + 480 - 1,08 - 0,24 . 2 = 483,84 (g)
C% dd Al2(SO4)3 = \(\dfrac{27,36}{483,84}.100\%=5,65\%\)
Pt: Al2(SO4)3 + 6NaOH --> 3Na2SO4 + 2Al(OH)3
0,08 mol-------> 0,48 mol
VNaOH cần = \(\dfrac{0,48}{1,25}=0,384\left(l\right)\)
a)b)c)d) mBaCl2=150.16,64%=24,96g
=>nBaCl2=0,12 mol
mH2SO4=100.14,7%=14,7g=>nH2SO4=0,15mol
BaCl2 + H2SO4 =>BaSO4 +2HCl
Bđ: 0,12 mol; 0,15 mol
Pứ: 0,12 mol=>0,12 mol=>0,12 mol=>0,24 mol
Dư: 0,03 mol
Dd ban đầu chứa BaCl2 0,12 mol và H2SO4 0,15 mol
Dd A sau phản ứng chứa HCl 0,24 mol và H2SO4 dư 0,03 mol
mHCl=0,24.36,5=8,76g
mH2SO4=0,03.98=2,94g
Kết tủa B là BaSO4 0,12 mol=>mBaSO4=0,12.233=27,96g
mddA=mddBaCl2+mddH2SO4-mBaSO4
=150+100-27,96=222,04g
C%dd HCl=8,76/222,04.100%=3,945%
C% dd H2SO4=2,94/222,04.100%=1,324%
e) HCl +NaOH =>NaCl +H2O
0,24 mol=>0,24 mol
H2SO4 +2NaOH =>Na2SO4 + 2H2O
0,03 mol=>0,06 mol
TÔNG nNaOH=0,3 mol
=>V dd NaOH=0,3/2=0,15 lit