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a)b)c)d) mBaCl2=150.16,64%=24,96g
=>nBaCl2=0,12 mol
mH2SO4=100.14,7%=14,7g=>nH2SO4=0,15mol
BaCl2 + H2SO4 =>BaSO4 +2HCl
Bđ: 0,12 mol; 0,15 mol
Pứ: 0,12 mol=>0,12 mol=>0,12 mol=>0,24 mol
Dư: 0,03 mol
Dd ban đầu chứa BaCl2 0,12 mol và H2SO4 0,15 mol
Dd A sau phản ứng chứa HCl 0,24 mol và H2SO4 dư 0,03 mol
mHCl=0,24.36,5=8,76g
mH2SO4=0,03.98=2,94g
Kết tủa B là BaSO4 0,12 mol=>mBaSO4=0,12.233=27,96g
mddA=mddBaCl2+mddH2SO4-mBaSO4
=150+100-27,96=222,04g
C%dd HCl=8,76/222,04.100%=3,945%
C% dd H2SO4=2,94/222,04.100%=1,324%
e) HCl +NaOH =>NaCl +H2O
0,24 mol=>0,24 mol
H2SO4 +2NaOH =>Na2SO4 + 2H2O
0,03 mol=>0,06 mol
TÔNG nNaOH=0,3 mol
=>V dd NaOH=0,3/2=0,15 lit
a) nH2SO4 = 0,2 mol
nBaCl2 = 0,1 mol
H2SO4 (0,1) + BaCl2 (0,1) -----> BaSO4 (0,1) + 2HCl (0,2)
- Theo PTHH: nBaSO4 = 0,1 mol
=> mBaSO4 = 23,3 gam
b) - dd sau phản ứng gồm: \(\left\{{}\begin{matrix}HCl:0,2\left(mol\right)\\H2SO4_{dư}:0,1\left(mol\right)\end{matrix}\right.\)
mdd sau = \(100.1,2+100.1,32-23,3=228,7\left(gam\right)\)
=> \(C\%HCl=\dfrac{0,2.36,5.100}{228,7}=3,192\%\)
=> \(C\%H2SO4_{dư}=\dfrac{0,1.98.100}{228,7}=4,2851\%\)
V dd sau = 0,1 + 0,1 = 0,2 lít
=> CM HCl = 0,2/0,2 = 1M
=> CM H2SO4 dư = 0,1 / 0,2 = 0,5M
1) Ta có: \(m_{H_2SO_4}=200\cdot15\%+300\cdot25\%=105\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{105}{200+300}\cdot100\%=21\%\)
2) Ta có: \(\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{105}{98}=\dfrac{15}{14}\left(mol\right)\\V_{ddH_2SO_4}=\dfrac{500}{1,25}=400\left(ml\right)\end{matrix}\right.\) \(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{\dfrac{15}{14}}{0,4}\approx2,68\left(M\right)\)
\(n_{BaCl_2}=\frac{400.5,2\%}{208}=0,1\left(mol\right);n_{H_2SO_4}=\frac{100.1,14.19,6\%}{98}=0,228\left(mol\right)\)
PTHH: \(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)
Theo đề: 0,1.........0,228.....................................(mol)
Lập tỉ lệ: \(\frac{0,1}{1}< \frac{0,228}{1}\)=> Sau phản ứng H2SO4 dư
Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)
dd sau khi lọc bỏ kết tủa: H2SO4 dư, HCl
\(m_{ddsaup.ứ}=400+114-23,3=490,7\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4\left(dư\right)}=\frac{\left(0,228-0,1\right).98}{490,7}.100=2,56\%\)
\(C\%_{HCl}=\frac{0,1.2.36,5}{490,7}.100=1,49\%\)
MgCl2+2AgNO3->Mg(NO3)2+2AgCl
0,04-----0,08-----------0,04----------0,08
n MgCl2=0,1 mol
n AgNO3=0,08 mol
=>Mgcl2 dư
=>m AgCl=0,08.143,5=11,48g
=>CMMg(NO)2=\(\dfrac{0,04}{0,2}\)=0,2M
=>CMMgcl2 dư=\(\dfrac{0,06}{0,2}\)=0,3M
\(n_{MgCl_2}=0,1\cdot1=0,1mol\)
\(n_{AgNO_3}=0,1\cdot0,8=0,08mol\)
\(MgCl_2+2AgNO_3\rightarrow2AgCl\downarrow+Mg\left(NO_3\right)_2\)
0,1 0,08 0 0
0,04 0,08 0,08 0,04
0,06 0 0,08 0,04
\(m_{\downarrow}=0,08\cdot143,5=11,48g\)
\(C_{M_{Mg\left(NO_3\right)_2}}=\dfrac{n_{Mg\left(NO_3\right)_2}}{V_X}=\dfrac{0,04}{0,2}=0,2M\)
a/
\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,15 0,3 (mol)
\(m_{NaOH}=0,3.40=12\left(g\right)\)
\(m_A=90,7+9,3=100\left(g\right)\)
\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)
b/
m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)
\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)
\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)
bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)
pư: 0,3 0,15 0,15 0,15 (mol)
dư: 0 \(\dfrac{23}{380}\) (mol)
\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)
\(m_C=100+200-13,5=286,5\left(g\right)\)
\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)
\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)
\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)
\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)
\(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
\(n_{HCl}=2.0,2=0,4\left(mol\right)\)
PTHH :
\(CuO+2HCl\rightarrow CuCl_2+H_2\uparrow\)
trc p/ư: 0,15 0,4
p/ư : 0,15 0,3 0,15 0,15
sau p/ư : 0 0,1 0,15 0,15
--> sau p/ư : HCl dư
\(a,m_{CuCl_2}=0,15.135=20,25\left(g\right)\)
\(b,C_{M\left(CuCl_2\right)}=\dfrac{0,15}{0,2}=0,75\left(M\right)\)
\(a)n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ n_{HCl}=0,2.2=0,4\left(mol\right)\\ CuO+2HCl\xrightarrow[]{}CuCl_2+H_2\\ \dfrac{0,15}{1}< \dfrac{0,4}{2}\Rightarrow HCl.dư\\ n_{CuCl_2}=n_{CuO}=n_{H_2}=0,15mol\\ m_{CuCl_2}=0,15.135=20,25\left(g\right)\\ b)C_{MCuCl_2}=\dfrac{0,15}{0,2}=0,75\left(M\right)\\ n_{HCl\left(pư\right)}=0,15.2=0,3\left(mol\right)\\ n_{HCl\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\\ C_{MHCl\left(dư\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{HCl}=\dfrac{150.3,65\%}{36,5}=0,15\left(mol\right)\\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=\dfrac{0,15}{2}=0,075\left(mol\right)\\ b,m_{Zn}=0,075.65=4,875\left(g\right)\\c,m_{ddsau}=4,875+150-0,075.2=154,725\left(g\right)\\ m_{ZnCl_2}=0,075.136=10,2\left(g\right)\\c, C\%_{ddZnCl_2}=\dfrac{10,2}{154,725}.100\%\approx6,592\%\\ V_{ddsau}=V_{ddHCl}=\dfrac{150}{1,2}=125\left(ml\right)=0,125\left(l\right)\\ C_{MddZnCl_2}=\dfrac{0,075}{0,125}=0,6\left(M\right)\)
\(n_{CaO}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
\(0.2..........0.4.........0.2\)
\(C_{M_{HCl}}=\dfrac{0.4}{0.1}=4\left(M\right)\)
\(m_{CaCl_2}=0.2\cdot111=22.2\left(g\right)\)
\(n_{H_2SO_4}=0.1\cdot2=0.2\left(mol\right)\)
\(m_{dd_{H_2SO_4}}=100\cdot1.2=120\left(g\right)\)
\(n_{BaCl_2}=0.1\cdot1=0.1\left(mol\right)\)
\(m_{dd_{BaCl_2}}=100\cdot1.32=132\left(g\right)\)
\(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)
\(0.1................0.1.........0.1...............0.2\)
\(\Rightarrow H_2SO_4dư\)
\(m_{BaSO_4}=0.1\cdot233=23.3\left(g\right)\)
\(V_{dd}=0.1+0.1=0.2\left(l\right)\)
\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.2-0.1}{0.2}=0.5\left(M\right)\)
\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)
\(m_{\text{dung dịch sau phản ứng}}=120+132-23.3=228.7\left(g\right)\)
\(C\%_{H_2SO_4\left(dư\right)}=\dfrac{0.1\cdot98}{228.7}\cdot100\%=4.28\%\)
\(C\%_{HCl}=\dfrac{0.2\cdot36.5}{228.7}\cdot100\%=3.2\%\)
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