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a,\(n_{FeCl_2}=0,25.0,2=0,05\left(mol\right);n_{NaOH}=0,25.0,5=0,125\left(mol\right)\)
PTHH: FeCl2 + 2NaOH → Fe(OH)2 + 2NaCl
Mol: 0,05 0,05 0,1
Tỉ lệ:\(\dfrac{0,05}{1}< \dfrac{0.125}{2}\) ⇒ FeCl2 pứ hết;NaOH dư
PTHH: \(Fe\left(OH\right)_2\underrightarrow{t^o}FeO+H_2O\)
Mol: 0,1 0,1
⇒ m=mFeO = 0,1.72 = 7,2 (g)
b,\(C_{MNaOHdư}=\dfrac{0,125-0,1}{0,5}=0,05M\)
\(C_{MNaCl}=\dfrac{0,1}{0,5}=0,2M\)
Bài 7 :
200ml = 0,2l
\(n_{CuCl2}=2.0,2=0,4\left(mol\right)\)
Pt : \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl|\)
1 2 1 2
0,4 0,8 0,4 0,8
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O|\)
1 1 1
0,4 0,4
a) \(n_{CuO}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
⇒ \(m_{CuO}=0,4.40=32\left(g\right)\)
b) \(n_{NaCl}=\dfrac{0,4.2}{1}=0,8\left(mol\right)\)
⇒ \(m_{NaCl}=0,8.58,5=46,8\left(g\right)\)
\(m_{ddCuCl2}=1,35.200=270\left(g\right)\)
\(m_{ddspu}=270+100=370\left(g\right)\)
\(C_{NaCl}=\dfrac{46,8.100}{370}=12,65\)0/0
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a) PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{6,2}{62}=0,2\left(mol\right)\) \(\Rightarrow C_{M_{NaOH}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)
b) PTHH: \(2NaOH+CuSO_4\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{CuSO_4}=0,2\cdot2,5=0,5\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,5}{1}\) \(\Rightarrow\) CuSO4 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{Cu\left(OH\right)_2}=0,1\left(mol\right)=n_{Na_2SO_4}\\n_{CuSO_4\left(dư\right)}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Cu\left(OH\right)_2}=0,1\cdot98=9,8\left(g\right)\\C_{M_{Na_2SO_4}}=\dfrac{0,1}{0,4+0,2}\approx0,17\left(M\right)\\C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0,4}{0,6}\approx0,67\left(M\right)\end{matrix}\right.\)
\(n_{FeCl_2}=\dfrac{150\cdot12.7\%}{127}=0.15\left(mol\right)\)
\(n_{NaOH}=\dfrac{350\cdot4\%}{40}=0.35\left(mol\right)\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
\(0.15...........0.3................0.15............0.3\)
\(m_{Fe\left(OH\right)_3}=0.15\cdot90=13.5\left(g\right)\)
\(m_{dd}=150+350-13.5=486.5\left(g\right)\)
\(C\%_{NaCl}=\dfrac{0.3\cdot58.5}{486.5}\cdot100\%=3.61\%\)
\(C\%_{NaOH\left(dư\right)}=\dfrac{\left(0.35-0.3\right)\cdot40}{486.5}\cdot100\%=0.4\%\)
\(Fe\left(OH\right)_2\underrightarrow{^{^{t^0}}}FeO+H_2O\)
\(0.15..........0.15\)
\(m_{FeO}=0.15\cdot72=10.8\left(g\right)\)
\(4Fe\left(OH\right)_2+O_2\underrightarrow{^{^{t^0}}}2Fe_2O_3+4H_2O\)
\(0.15.........................0.075\)
\(m_{Fe_2O_3}=0.075\cdot160=12\left(g\right)\)
\(m_{Fe_2\left(SO_4\right)_3}=\dfrac{200\cdot20}{100}=40\left(g\right)\Rightarrow n=0,1mol\)
\(Fe_2\left(SO_4\right)_3+6NaOH\rightarrow2Fe\left(OH\right)_3\downarrow+3Na_2SO_4\)
0,1 0,6 0,2 0,3
a)\(m_{NaOH}=0,6\cdot40=24\left(g\right)\)
b)\(m_{Fe\left(OH\right)_3}=0,2\cdot107=21,4\left(g\right)\)
c)\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
\(m_{ddsau}=200+24-21,4=202,6\left(g\right)\)
\(\Rightarrow C\%=\dfrac{42,6}{202,6}\cdot100\%=21,03\%\)
câu 1
cho 2dd trên td vs NaOH dư
có tủa => CuSO4
CuSO4 + 2NaOH => Na2SO4 + Cu(OH)2
ko hiện tượng => Na2SO4
\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) Pt : \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl|\)
1 2 1 2
0,25 0,5 0,25
b) \(n_{Fe\left(OH\right)2}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
⇒ \(m_{Fe\left(OH\right)2}=0,25.90=22,5\left(g\right)\)
c) \(n_{FeCl2}=\dfrac{0,5.1}{2}=0,25\left(mol\right)\)
100ml = 0,1l
\(C_{M_{ddFeCl2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
d) Pt : \(Fe\left(OH\right)_2\underrightarrow{t^o}FeO+H_2O|\)
1 1 1
0,25 0,25
\(n_{FeO}=\dfrac{0,25.1}{1}=0,25\left(mol\right)\)
⇒ \(m_{FeO}=0,25.72=18\left(g\right)\)
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