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a) PTHH: \(SO_3+H_2O\rightarrow H_2SO_4\)
Ta có: \(n_{SO_3}=\dfrac{24}{80}=0,3\left(mol\right)=n_{H_2SO_4}\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3\cdot98}{20\%}=147\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{147}{1,14}\approx128,95\left(ml\right)\)
b) PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
Theo PTHH: \(n_{Fe}=n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)=n_{FeSO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,3\cdot56=16,8\left(g\right)\\V_{H_2}=0,3\cdot24,76=7,428\left(l\right)\\m_{FeSO_4}=0,3\cdot152=45,6\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddH_2SO_4}-m_{H_2}=163,2\left(g\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{45,6}{163,2}\cdot100\%\approx27,94\%\)
Ta có: \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
______0,2_____0,4_____0,2 (mol)
a, \(m_{CuCl_2}=0,2.135=27\left(g\right)\)
b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow C\%_{HCl}=\dfrac{14,6}{300}.100\%\approx4,867\%\)
c, Ta có: m dd sau pư = 16 + 300 = 316 (g)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{27}{316}.100\%\approx8,54\%\)
\(CaCO_3+ HCl → CaCl_2+H_2O +CO_2\)
\(n_{CaCO_3}=\dfrac{10}{40+12+16.3}=0,1(mol)\)
\(n_{HCl}=\dfrac{146}{1+35,5}=4(mol)\)
\(\Rightarrow n_{HCl_{dư}}=4-0,1=3,9(mol) ; n_{CaCl_2}=0,1(mol)\\\Rightarrow m_{\text{chất tan}} = m_{HCl_{dư}}+m_{CaCl_2}\\=0,39.(35,5+1)+0,1(40+35,5.2)=25,335(g)\)
Vậy...
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)=n_{Fe}=n_{FeCl_2}\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15\cdot127}{300}\cdot100\%=6,35\%\\m_{Fe}=0,15\cdot56=8,4\left(g\right)\end{matrix}\right.\)
b) PTHH: \(Cu+2H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}CuSO_4+SO_2\uparrow+2H_2O\)
Ta có: \(n_{Cu}=\dfrac{13,2-8,4}{64}=0,075\left(mol\right)=n_{SO_2}\) \(\Rightarrow V_{SO_2}=0,075\cdot22,4=1,68\left(l\right)\)
