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a. PTHH:
\(Zn+H_2SO_4--->ZnSO_4+H_2\uparrow\)
\(Cu+H_2SO_4--\times-->\)
b. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2SO_4}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{\dfrac{200}{1000}}=0,5M\)
c. Ta có: \(m_{Zn}=0,1.65=6,5\left(g\right)\)
\(\Rightarrow m_{Cu}=10,5-6,5=4\left(g\right)\)
a) PTHH : \(Zn+H_2SO_4-->ZnSO_4+H_2\uparrow\) (1)
\(ZnO+H_2SO_4-->ZnSO_4+H_2O\) (2)
b) Theo pthh (1) : \(n_{Zn}=n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)
=> \(m_{ZnO}=22,7-6,5=16,2\left(g\right)\)
c) \(ZnO=\dfrac{16,2}{81}=0,2\left(mol\right)\)
Theo pthh (1) và (2) : \(\Sigma n_{H2SO4}=n_{Zn}+n_{ZnO}=0,1+0,2=0,3\left(mol\right)\)
=> \(C_{M\left(ddH2SO4\right)}=\dfrac{0,3}{0,1}=1,5M\)
a) PTHH : Zn+H2SO4−−>ZnSO4+H2↑Zn+H2SO4−−>ZnSO4+H2↑ (1)
ZnO+H2SO4−−>ZnSO4+H2OZnO+H2SO4−−>ZnSO4+H2O (2)
b) Theo pthh (1) : nZn=nH2=2,2422,4=0,1(mol)nZn=nH2=2,2422,4=0,1(mol)
=> mZn=0,1.65=6,5(g)mZn=0,1.65=6,5(g)
=> mZnO=22,7−6,5=16,2(g)mZnO=22,7−6,5=16,2(g)
c) ZnO=16,281=0,2(mol)ZnO=16,281=0,2(mol)
Theo pthh (1) và (2) : ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)
=> CM(ddH2SO4)=0,30,1=1,5M
tích đúng đê
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a_______a_______a_____a (mol)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
2b______3b__________b_____3b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56a+27\cdot2b=11\\a+3b=0,2\cdot2=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{11}\cdot100\%\approx50,91\%\\\%m_{Al}=49,09\%\end{matrix}\right.\)
Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,4\left(mol\right)\\n_{FeSO_4}=0,1\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,4\cdot22,4=8,96\left(l\right)\\C_{M_{FeSO_4}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
a) nH2SO4=0,4(mol)
Đặt: nFe=x(mol); nAl=y(mol) (x,y>0)
PTHH: Fe + H2SO4 -> FeSO4 + H2
x________x______x______x(mol)
2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2
y____1,5y_______0,5y_______1,5y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}56x+27y=11\\x+1,5y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
=> mFe=0,1.56=5,6(g)
=>%mFe=(5,6/11).100=50,909%
=>%mAl= 49,091%
b) V(H2,đktc)=0,4.22,4=8,96(l)
c) nAl2(SO4)3= 0,5y=0,5.0,2=0,1(mol)
nFeSO4=x=0,1(mol)
Vddsau=VddH2SO4=0,2(l)
=>CMddAl2(SO4)3= 0,1/0,2=0,5(M)
CMddFeSO4=0,1/0,2=0,5(M)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\\%m_{Fe}=\dfrac{0,1\cdot56}{12}\cdot100\%\approx46,67\%\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\\\%m_{Cu}=53,33\%\end{matrix}\right.\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Cu không phản ứng
\(nH_2=nFe=\dfrac{2,24}{22,4}=0,1mol\)
\(\rightarrow mFe=0,1.56=5,6gam\)
\(\rightarrow\%mFe=\dfrac{5,6}{12}.100\%=46,\left(6\right)\%\)
\(\rightarrow\%mCu=100\%-46,\left(6\right)\%=53,\left(3\right)\%\)
c)
\(CM_{HCl}=\dfrac{0,1.2}{0,2}=1M\)
\(a.n_{Mg\left(OH\right)_2}=\dfrac{17,4}{58}=0,3\left(mol\right)\\ Mg\left(OH\right)_2+2HCl\rightarrow MgCl_2+2H_2O\\ n_{HCl}=2n_{Mg\left(OH\right)_2}=0,6\left(mol\right)\\ CM_{HCl}=\dfrac{0,6}{0,2}=3M\\b. n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,3\left(mol\right)\\ m_{MgCl_2}=0,3.85=25,5\left(g\right)\\c.CM_{MgCl_2}=\dfrac{0,3}{0,2}=1,5M \)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)
a)\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
0,1 0,2 0,1 0,1 0,1
b)\(m_{HCl}=0,1\cdot36,5=3,65\left(g\right)\)
\(a\%=\dfrac{3,65}{100}\cdot100\%=3,65\%\)
c)\(m_{CaCO_3}=0,1\cdot100=10\left(G\right)\)
\(\Rightarrow\%m_{CaCO_3}=\dfrac{10}{16}\cdot100\%=62,5\%\)
\(\Rightarrow\%m_{CaCl_2}=100\%-62,5\%=37,5\%\)
d)\(m_{CaCl_2}=0,1\cdot111=11,1\left(g\right)\)
\(m_{H_2O}=0,1\cdot18=1,8\left(g\right)\)
\(m_{ddsau}=10+100-0,1\cdot44-1,8=103,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{11,1}{103,8}\cdot100\%=10,7\%\)
Câu 5 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,15 0,3 0,15
a) \(n_{Mg}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Mg}=0,1.24=2,4\left(g\right)\)
\(m_{MgO}=8,4-2,4=6\left(g\right)\)
0/0Mg = \(\dfrac{2,4.100}{8,4}=28,57\)0/0
0/0MgO = \(\dfrac{6.100}{8,4}=71,43\)0/0
b) Có : \(m_{MgO}=6\left(g\right)\)
\(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{3,65}=500\left(g\right)\)
\(n_{MgCl2\left(tổng\right)}=0,1+0,15=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,15.95=14,25\left(g\right)\)
\(m_{ddspu}=8,4+500-\left(0,1.2\right)=508,2\left(g\right)\)
\(C_{MgCl2}=\dfrac{14,25.100}{508,2}=2,8\)0/0
Chúc bạn học tốt
Sửa đề: Sau phản ứng thu đc \(2240(cm^3)\) lít khí (đktc)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ b,n_{Zn}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%= 44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1(mol)\\ \Sigma n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1M\)
