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Bài 19 :
\(a) n_{Al} = \dfrac{10,8}{27} = 0,4(mol)\\ 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2} = \dfrac{3}{2}n_{Al} = 0,6(mol)\\ V_{H_2} = 0,6.22,4 = 13,44(lít)\\ b) \text{Chất tan : }Al_2(SO_4)_3\\ n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,2(mol)\\ m_{Al_2(SO_4)_3} = 0,2.342 = 68,4(gam)\)
Bài 18 :
\(a) n_{HCl} = \dfrac{250.7,3\%}{36,5 } = 0,5(mol)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,25(mol) \Rightarrow V_{H_2} = 0,25.22,4 = 5,6(lít)\\ b) \text{Chất tan : } ZnCl_2\\ n_{ZnCl_2} = n_{H_2} = 0,25(mol)\\ m_{ZnCl_2} = 0,25.136 = 34(gam)\)
\(n_{Fe_2O_3}=\dfrac{48}{160}=0,3(mol)\\ PTHH:Fe_2O_3+3H_2SO_4\to Fe_2(SO_4)_3+3H_2O\\ \Rightarrow n_{H_2SO_4}=3n_{Fe_2O_3}=0,9(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,9.98}{19,6\%}=450(g)\)
\(a,n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ m_{H_2SO_4}=200.19,6\%=39,2\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{39,2}{98}=0,4\left(mol\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
bđ 0,3 0,4
pư 0,3 0,3
spư 0 0,1 0,3 0,3
\(\rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(b,m_{dd}=19,5+200-0,3.2=218,9\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnSO_4}=\dfrac{0,3.161}{218,9}.100\%=22,06\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,1.98}{218,9}.100\%=4,48\%\end{matrix}\right.\)
Cu(OH)2 + H2SO4 \(\rightarrow\) CuSO4 + 2H2O
nCu(OH)2 = \(\dfrac{29,4}{98}=0,3mol\)
Theo pt: nH2SO4 = nCu(OH)2 = 0,3 mol
=> mH2SO4 = 0,3.98 = 29,4g
VH2SO4 = 0,3:1 = 0,3l
PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Ta có: \(n_{CuO}=\dfrac{29,4}{80}=0,3675\left(mol\right)=n_{CuSO_4}=n_{H_2SO_4}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuSO_4}=0,3675\cdot160=58,8\left(g\right)\\m_{H_2SO_4}=0,3675\cdot98=36,015\left(g\right)\\V_{H_2SO_4}=\dfrac{0,3675}{1}=0,3675\left(l\right)=367,5\left(ml\right)\end{matrix}\right.\)
Bài 14 :
\(a) n_{CuO} = \dfrac{8}{80} = 0,1(mol)\\ CuO + 2HCl \to CuCl_2 + H_2O\\ n_{HCl} = 2n_{CuO} = 0,2(mol)\\ m_{dd\ HCl} = \dfrac{0,2.36,5}{7,3\%} = 100(gam)\\ b) \text{Chất tan : } CuCl_2\\ n_{CuCl_2} = n_{CuO} = 0,1(mol)\\ m_{CuCl_2} = 0,1.135 = 13,5(gam)\)
Bài 15 :
\(a) n_{Fe_2O_3} =\dfrac{4,8}{160} = 0,03(mol)\\ Fe_2O_3 + 3H_2SO_4 \to Fe_2(SO_4)_3 + 3H_2O\\ n_{H_2SO_4} = 3n_{Fe_2O_3} = 0,09(mol)\\ m_{dd\ H_2SO_4} = \dfrac{0,09.98}{9,8\%} = 90(gam)\\ b) \text{Chất tan : } Fe_2(SO_4)_3\\ n_{Fe_2(SO_4)_3} = n_{Fe_2O_3} = 0,03(mol)\\ m_{Fe_2(SO_4)_3} = 0,03.400 = 12(gam)\)
a, PTHH: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\uparrow\)
b, \(n_{Mg}=\dfrac{m}{M}=\dfrac{4,8}{24}=0,2( mol )\)
Theo PT: \(n_{H_2}=n_{Mg}=0,2(mol)\)
\(V=V_{H_2}=n.22,4=0,2.22,4=4,48(l)\)
c, Theo PT: \(n_{H_2SO_4}=n_{Mg}=0,2(mol)\)
Khối lượng H2SO4 đã dùng là:
\(m_{H_2SO_4}=n.M=0,2.98=19,6(g)\)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
(mol)_____0,2____0,2______0,2____0,2__
\(a.V_{H_2}=22,4.0,2=4,48\left(l\right)\)
\(b.m_{ddH_2SO_4}=\dfrac{0,2.98.100}{24,5}=80\left(g\right)\)
\(c.m_{ddspu}=13+80-0,2.2=92,6\left(g\right)\\ \Rightarrow C\%_{ddspu}=\dfrac{0,2.136}{92,6}.100=29,4\left(\%\right)\)
