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\(a.n_{CuO}=\dfrac{40}{80}=0,5\left(mol\right)\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Vì:\dfrac{0,15}{1}< \dfrac{0,5}{1}\\ \rightarrow CuOdư\\ n_{CuO\left(p.ứ\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\\ \rightarrow n_{CuO\left(dư\right)}=0,5-0,15=0,35\left(mol\right)\\ m_{CuO\left(DƯ\right)}=0,35.80=28\left(g\right)\\ b.m_{Cu}=0,35.64=22,4\left(g\right)\\ c.m_{hh_{rắn}}=m_{Cu}+m_{CuO\left(dư\right)}=22,4+28=50,4\left(g\right)\)
\(a,PTHH:Fe_3O_4+4H_2\xrightarrow{t^o}3Fe+4H_2O\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol);n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2(mol)\)
Vì \(\dfrac{n_{H_2}}{4}<\dfrac{n_{Fe_3O_4}}{1}\) nên \(Fe_3O_4\) dư
\(n_{Fe_3O_4(dư)}=0,2-\dfrac{0,3}{4}=0,125(mol)\\ \Rightarrow m_{Fe_3O_4(dư)}=0,125.232=29(g)\\ b,n_{Fe}=\dfrac{3}{4}n_{H_2}=0,225(mol)\\ \Rightarrow m_{Fe}=0,225.56=12,6(g)\)
\(a.n_{Fe_2O_3}=\dfrac{24}{160}=0,15\left(mol\right)\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ Fe_2O_3+3H_2\underrightarrow{to}2Fe+3H_2O\\ Vì:\dfrac{0,3}{3}< \dfrac{0,15}{1}\\ \rightarrow Fe_2O_3dư\\ n_{Fe_2O_3\left(dư\right)}=0,15-\dfrac{0,3}{3}=0,05\left(mol\right)\\ m_{Fe_2O_3\left(dư\right)}=0,05.160=8\left(g\right)\\ b.n_{Fe}=\dfrac{0,3}{3}.2=0,2\left(mol\right)\\ m_{Fe}=0,2.56=11,2\left(g\right)\\ c.m_{rắn}=m_{Fe}+m_{Fe_2O_3\left(dư\right)}=11,2+8=19,2\left(g\right)\)
HgO+H2-to>Hg+H2O
0,025-0,025--0,025
n HgO=\(\dfrac{8,68}{217}\)=0,04 mol
n H2=\(\dfrac{0,56}{22,4}\)=0,025 mol
=>HgO dư
=>m Hg=0,025.201=5,025g
nH2 = 0,56/22,4 = 0,025 (mol)
nHgO = 8,68/217 = 0,04 (mol)
PTHH: HgO + H2 -> (t°) Hg + H2O
LTL: 0,025 < 0,04 => H2 dư
nH2 (p/ư) = nHg = 0,025 (mol)
VH2 = (0,04 - 0,025) . 22,4 = 0,336 (l)
mHg = 0,025 . 201 = 5,025 (g)
a) Fe3O4 + 4H2 --to--> 3Fe + 4H2O
b)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(n_{Fe_3O_4}=\dfrac{23,2}{232}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{4}\) => H2 hết, Fe3O4 dư
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
0,025<--0,1------>0,075
=> \(m_{Fe_3O_4\left(dư\right)}=\left(0,1-0,025\right).232=17,4\left(g\right)\)
c) \(m_{Fe}=0,075.56=4,2\left(g\right)\)
a) PTHH : \(FeO+H_2-t^o->Fe+H_2O\)
\(CuO+H_2-t^o->Cu+H_2O\)
Đặt \(\hept{\begin{cases}n_{FeO}=x\left(mol\right)\\n_{CuO}=y\left(mol\right)\end{cases}}\) => \(72x+80y=11,2\left(I\right)\)
Có : \(m_{O\left(lấy.đi\right)}=m_{giảm}=1,92\left(g\right)\)
=> \(n_{O\left(lấy.đi\right)}=\frac{1,92}{16}=0,12\left(mol\right)\) Vì H% = 80% => Thực tế : \(n_{O\left(hh\right)}=\frac{0,12}{80}\cdot100=0,15\left(mol\right)\)
BT Oxi : \(x+y=0,15\left(II\right)\)
Từ (I) và (II) suy ra : \(\hept{\begin{cases}x=0,1\\y=0,05\end{cases}}\)
=> \(\hept{\begin{cases}m_{FeO}=7,2\left(g\right)\\m_{CuO}=4\left(g\right)\end{cases}}\)
b) PTHH : \(Fe+H_2SO_4-->FeSO_4+H_2\)
BT Fe : \(n_{Fe}=n_{FeO}=0,1\left(mol\right)\)
Theo pthh : \(n_{H_2}=n_{Fe}=0,1\left(mol\right)\)
=> \(V_{H_2}=2,24\left(l\right)\)
BT Cu : \(n_{Cu}=n_{CuO}=0,05\left(mol\right)\)
=> \(m_{CR\left(ko.tan\right)}=0,05\cdot64=3,2\left(g\right)\)
\(n_{CuO}=4a\left(mol\right)\Rightarrow n_{FeO}=a\left(mol\right)\)
\(m_X=80\cdot4a+72a=19.6\left(g\right)\)
\(\Rightarrow a=0.05\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(FeO+H_2\underrightarrow{^{^{t^0}}}Fe+H_2O\)
\(m_{cr}=0.2\cdot64+0.05\cdot56=15.6\left(g\right)\)
\(V_{H_2}=\left(0.05\cdot4+0.05\right)\cdot22.4=5.6\left(l\right)\)
`FeO + H_2` $\xrightarrow[]{t^o}$ `Fe + H_2 O`
`a) n_[H_2] = [ 3,36 ] / [ 22,4 ] = 0,15 (mol)`
`n_[FeO] = [ 14,2 ] / 72 = 71 / 360`
Ta có: `[ 0,15 ] / 1 < [ 71 / 360 ] / 1`
`=> FeO` dư
Theo `PTHH` có: `n_[FeO_\text{(p/ứ)}] = n_[H_2] = 0,15 (mol)`
`=> n_[FeO_\text{(dư)}] = 71 / 360 - 0,15 = 17 / 360 (mol)`
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`b)` Theo `PTHH` có: `n_[Fe] = n_[H_2] = 0,15 (mol)`
`=> m_[Fe] = 0,15 . 56 = 8,4 (g)`