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a)
Gọi \(\left\{{}\begin{matrix}n_{KClO_3}=a\left(mol\right)\\n_{KMnO_4}=2a\left(mol\right)\\n_{CaCO_3}=3a\left(mol\right)\end{matrix}\right.\)
=> mA = 122,5a + 316a + 300a = 738,5a (g)
\(\left\{{}\begin{matrix}\%m_{KClO_3}=\dfrac{122,5a}{738,5a}.100\%=16,588\%\\\%m_{KMnO_4}=\dfrac{316a}{738,5a}.100\%=42,789\%\\\%m_{CaCO_3}=\dfrac{300a}{738,5a}.100\%=40,623\%\end{matrix}\right.\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
a------------>a---->1,5a
2KMnO4 --to--> K2MnO4 + MnO2 + O2
2a-------------->a---------->a------->a
CaCO3 --to--> CaO + CO2
3a----------->3a---->3a
B chứa\(\left\{{}\begin{matrix}KCl:a\left(mol\right)\\K_2MnO_4:a\left(mol\right)\\MnO_2:a\left(mol\right)\\CaO:3a\left(mol\right)\end{matrix}\right.\)
=> mB = 74,5a + 197a + 87a + 168a = 526,5a (g)
=> \(\left\{{}\begin{matrix}\%m_{KCl}=\dfrac{74,5a}{526,5a}.100\%=14,15\%\\\%m_{K_2MnO_4}=\dfrac{197a}{526,5a}.100\%=37,417\%\\\%m_{MnO_2}=\dfrac{87a}{526,5a}.100\%=16,524\%\\\%m_{CaO}=\dfrac{168a}{526,5a}.100\%=31,909\%\%\end{matrix}\right.\)
b)
khí C chứa \(\left\{{}\begin{matrix}O_2:2,5a\left(mol\right)\\CO_2:3a\left(mol\right)\end{matrix}\right.\)
\(n_{Ba\left(OH\right)_2}=0,5.0,07=0,035\left(mol\right)\)
\(n_{BaCO_3}=\dfrac{4,72}{197}\approx0,024\left(mol\right)\)
TH1: Nễu kết tủa không bị hòa tan
PTHH: Ba(OH)2 + CO2 --> BaCO3 + H2O
0,024<--0,024
=> 3a = 0,024
=> a = 0,008
V = (2,5a + 3a).22,4 = 0,9856 (l)
mA = 738,5a = 5,908 (g)
TH2: Nếu kết tủa bị hòa tan 1 phần
PTHH: Ba(OH)2 + CO2 --> BaCO3 + H2O
0,035--->0,035--->0,035
BaCO3 + CO2 + H2O --> Ba(HCO3)2
0,011--->0,011
=> 3a = 0,035 + 0,011
=> a = \(\dfrac{23}{1500}\)
=> V = (2,5a + 3a).22,4 = 1,889 (l)
mA = 738,5a = 11,3237 (g)
Gọi $n_{KMnO_4} = a(mol) ; n_{KClO_3} = b(mol) \Rightarrow 158a + 122,5b = 49,975(1)$
$2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2$
$2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$
$m_{O_2} = m_{giảm} = 4(gam)$
$\Rightarrow n_{O_2} = 0,5a + 1,5b = \dfrac{4}{32} = 0,125(2)$
Từ (1)(2) suy ra a = 0,339 ; b = -0,029 < 0
(Sai đề)
Gọi số mol KMnO4, KClO3 là a, b
=> 158a + 122,5b = 49,975
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
_______a----------------------------------->a
2KClO3 --to--> 2KCl + 3O2
_b---------------------->1,5b
mO2 = mgiảm = 10,4
=> \(n_{O_2}=\dfrac{10,4}{32}=0,325\left(mol\right)\)
=> 0,5a + 1,5b = 0,325
=> a = 0,2; b = 0,15
=> \(\left\{{}\begin{matrix}\%KMnO_4=\dfrac{0,2.158}{49,975}.100\%=63,23\%\\\%KClO_3=\dfrac{0,15.122,5}{49,975}.100\%=36,77\%\end{matrix}\right.\)
Gọi số mol KMnO4, KClO3 là a, b
=> 158a + 122,5b = 49,975
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
2KClO3 --to--> 2KCl + 3O2
mO2 = mgiảm = 10,4
=> \(n_{O_2}=\dfrac{10,4}{32}=0,325\left(mol\right)\)
=> 0,5a + 1,5b = 0,325
=> a = 0,2; b = 0,15
=> \(\left\{{}\begin{matrix}\%KMnO_4=\dfrac{0,2.158}{49,975}.100\%=63,23\%\\\%KClO_3=\dfrac{0,15.122,5}{49,975}.100\%=36,77\%\end{matrix}\right.\)
Gọi n KMnO4 = a
n KClO3 = b ( mol )
--> 158a + 122,5 b = 43,3
PTHH :
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
0,9b 1,35b
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9a 0,45a
\(\%Mn=\dfrac{55a}{43,3-32\left(0,45a+1,35b\right)}=24,103\%\)
\(\rightarrow a=0,15\)
\(b=0,16\)
\(m_{KMnO_4}=0,15.158=23,7\left(g\right)\)
\(m_{KClO_3}=0,16.122,5=19,6\left(g\right)\)
2KMnO4-to>K2MnO4+MnO2+O2
0,14-------------0,07------0,07-------0,07 mol
n KMnO4=\(\dfrac{22,12}{158}\)=0,14 mol
=>a=mcr=0,07.197+0,07.87=23,82g
=>VO2=0,07.22,4=1,568l
b)
2Cu+O2-to>2CuO
0,07-----0,14
n Cu=\(\dfrac{10,24}{64}\)=0,16 mol
Cu dư :0,01 mol
m chất rắn =0,01.64+0,14.80=11,84g
