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nNaOH=0,025mol
nH2SO4=0,015mol
2NaOH+H2SO4->Na2SO4+2H2O
Ta có 0,025/2 <0,015/1 =>H2SO4 dư
Khi nhúng quì tím vào dd thì quì tím chuyển sang màu đỏ
2NaOH+H2SO4->Na2SO4+2H2O
0,025 0,0125 0,0125
DD X: H2SO4:0,0025mol
Na2SO4: 0,0125mol
C(H2SO4)=0,00625M
C(NaOH)=0,03125M
1) $n_{NaOH} = 0,015(mol) ; n_{H_2SO_4} = 0,025(mol)$
$2NaOH + H_2SO_4 \to Na_2SO_4 + H_2O$
Ta thấy :
$n_{NaOH} : 2 < n_{H_2SO_4} : 1$ nên $H_2SO_4$ dư
Do đó quỳ tím hóa đỏ.
2)
$n_{Na_2SO_4} = \dfrac{1}{2}n_{NaOH} = 0,0075(mol)$
$n_{H_2SO_4\ dư} = 0,025 - 0,0075 = 0,0175(mol)$
$V_{dd\ X} = 0,15 + 0,25 = 0,4(lít)$
Suy ra :
$C_{M_{Na_2SO_4}} = \dfrac{0,0075}{0,4} = 0,01875M$
$C_{M_{H_2SO_4\ dư}} = \dfrac{0,0175}{0,4} = 0,04375M$
3)
$2KOH + H_2SO_4 \to K_2SO_4 + H_2O$
$n_{KOH} = 2n_{H_2SO_4\ dư} = 0,035(mol)$
$V_{dd\ KOH} =\dfrac{0,035}{1} = 0,035(lít)$
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
a+b) Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)=n_{H_2SO_4}=n_{ZnSO_4}\)
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5\left(M\right)=C_{M_{ZnSO_4}}\)
c) Theo PTHH: \(n_{H_2}=n_{Zn}=0,3mol\) \(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)
d) Theo PTHH: \(n_{Fe}=\dfrac{2}{3}n_{H_2}=0,2mol\)
\(\Rightarrow m_{Fe}=0,2\cdot56=11,2\left(g\right)\)
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2.......0.4........0.2.......0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(V_{dd_{HCl}}=\dfrac{0.4}{0.2}=2\left(l\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0.2}{2}=0.1\left(M\right)\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
$n_{H_2} = n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$V_{H_2} = 0,2.22,4 = 4,48(lít)$
b)
$n_{HCl} = 2n_{Fe} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{0,2} = 2(lít) = 2000(ml)$
c)
$n_{FeCl_2} = n_{Fe} = 0,2(mol)$
$\Rightarrow C_{M_{FeCl_2}} = \dfrac{0,2}{2} = 0,1M$
\(n_{CuO}=\dfrac{4}{80}=0.05\left(mol\right)\)
\(n_{H_2SO_4}=0.15\cdot1=0.15\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(TC:\dfrac{0.05}{1}< \dfrac{0.15}{1}\Rightarrow H_2SO_4dư\)
\(m_{CuSO_4}=0.05\cdot160=8\left(g\right)\)
\(C_{M_{CuSO_4}}=\dfrac{0.05}{0.15}=0.33\left(M\right)\)
a)
PTHH: CuO + H2SO4 -> CuSO4+ H2O
b) nCuO=0,1(mol); nH2SO4=0,15(mol)
Vì: 0,1/1 < 0,15/1
-> H2SO4 dư, CuO hết, tính theo nCuO
nCuSO4=nH2SO4(p.ứ)=nCuO=0,1(mol)
=>mCuSO4=160.0,1=16(g)
c) nH2SO4(dư)=0,05(mol)
Vddsau=VddH2SO4=0,15(l)
=>CMddH2SO4(dư)=0,05/0,15=1/3(M)
CMddCuSO4=0,1/0,15=2/3(M)
a)
$CuO + H_2SO_4 \to CuSO_4 + H_2O$
b)
$n_{CuSO_4} = n_{CuO} = \dfrac{4}{80} = 0,05(mol)$
$m_{CuSO_4} = 0,05.160 = 8(gam)$
c)
$C_{M_{CuSO_4}} = \dfrac{0,05}{0,15} = 0,33M$
a: \(n_{H_2SO_4}=0.25\cdot2=0.5\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{10.2}{27\cdot2+16\cdot3}=0.1\left(mol\right)\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,5
Vì 0,1/1<0,5/3
nên Al2O3 hết, H2SO4 dư
=>Tính theo Al2O3
b:
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1
\(m_{H_2SO_4\left(pư\right)}=0.3\cdot98=29.4\left(g\right)\)
\(m_{muối}=0.1\left(54+3\cdot96\right)=34.2\left(g\right)\)
a, \(n_{HCl}=0,15.1=0,15\left(mol_{ }\right)\)
PTHH: CuO + 2HCl → CuCl2 + H2O
Mol: 0,075 0,15 0,075
b, \(C_{M_{ddCuCl_2}}=\dfrac{0,075}{0,15}=0,5M\)