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\(a.n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(m_{Al}=0,2.27=5,4g\\ b.C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,45}=\dfrac{2}{3}M\\ c.2H_2+O_2\underrightarrow{t^0}2H_2O\)
0,3 0,15 0,3
\(V_{O_2}=0,15.22,4=3,36l\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Al}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ a,m_{Al}=0,2.27=5,4\left(g\right)\\ n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)\\ b,C_{MddH_2SO_4}=\dfrac{0,3}{0,45}=\dfrac{2}{3}\left(M\right)\\ 2H_2+O_2\rightarrow\left(t^o\right)2H_2O\\ n_{O_2}=\dfrac{n_{H_2}}{2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ c,V_{O_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\)
thôi thì mình làm cho bn vậy, câu a ko làm dc đâu, làm câu b thôi, làm sao biết dc chất nào dư khi chỉ có số mol 1 chất?
nK2SO3=0.1367(mol)
mddH2SO4=Vdd.D=200.1,04=208(g)
K2SO3+H2SO4-->K2SO4+H2O+SO2
0.1367----0.1367----0.1367---------0.1367 (mol)
mddspu=100+208-0,1367.64=299.2512(g) ; mK2SO4=0,1367.174=23.7858(g)
==>C%=23.7858.100/299.512=7.94%
2)pt bn tự ghi nhé
ta có hệ pt: 56a+27b=11 và a+3b/2=8.96/22.4==>a=0.1, b=0.2
==>%Fe=0.1x56x100/11=50.9%
%Al=100%-50.9%=49.1%
b)nH2SO4= 0.7(mol)==>VddH2SO4=0.7/2=0.35(L)
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
Ta có: \(n_{H_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,04\left(mol\right)\)
\(\Rightarrow\%m_{FeO}=\dfrac{5,84-0,04.56}{5,84}.100\%\approx61,64\%\)
b, Ta có: \(n_{FeO}=\dfrac{5,84-0,04.56}{72}=0,05\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Fe}+2n_{FeO}=0,18\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,18}{1}=0,18\left(l\right)=180\left(ml\right)\)
c, Theo PT: \(n_{FeCl_2}=n_{Fe}+n_{FeO}=0,09\left(mol\right)\)
Có: m dd HCl = 180.1,15 = 207 (g)
⇒ m dd sau pư = 5,84 + 207 - 0,04.2 = 212,76 (g)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{0,09.127}{212,76}.100\%\approx5,37\%\)
Đặt: \(\left\{{}\begin{matrix}x=n_{Fe}\left(mol\right)\\y=n_{Al}\left(mol\right)\end{matrix}\right.\)
\(\sum m_{hh}=11\left(g\right)\Rightarrow56x+27y=11\left(1\right)\)
\(PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\\ \left(mol\right)....x\rightarrow..2x........x......x\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\\ \left(mol\right)....y\rightarrow..3y.........y......1,5y\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ \Rightarrow x+1,5y=0,4\left(2\right)\)
\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
a) \(\%m_{Fe}=\dfrac{56.0,1}{11}=51\%\)
\(\rightarrow\%m_{Al}=49\%\)
b) \(\sum m_{ctHCl}=\left(2.0,1+3.0,2\right).36,5=29,2\left(g\right)\)
\(m_{ddHCl}=\dfrac{29,2.100\%}{10\%}=292\left(g\right)\)
c) \(m_{H_2\uparrow}=\left(1.0,1+1,5.0,2\right).2=0,8\left(g\right)\)
\(m_{ddsaupu}=m_{hh}+m_{ddHCl}-m_{H_2\uparrow}=11+292-0,8=302,2\left(g\right)\)
\(C\%_{FeCl_2}=\dfrac{0,1.127}{302,2}.100=4,2\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{302,2}.100=8,8\%\)
Đặt: {x=nFe(mol)y=nAl(mol){x=nFe(mol)y=nAl(mol)
∑mhh=11(g)⇒56x+27y=11(1)∑mhh=11(g)⇒56x+27y=11(1)
PTHH:Fe+2HCl→FeCl2+H2↑(mol)....x→..2x........x......xPTHH:2Al+6HCl→2AlCl3+3H2↑(mol)....y→..3y.........y......1,5yPTHH:Fe+2HCl→FeCl2+H2↑(mol)....x→..2x........x......xPTHH:2Al+6HCl→2AlCl3+3H2↑(mol)....y→..3y.........y......1,5y
nH2=8,9622,4=0,4(mol)⇒x+1,5y=0,4(2)nH2=8,9622,4=0,4(mol)⇒x+1,5y=0,4(2)
(1)−→(2){x=0,1y=0,2→(2)(1){x=0,1y=0,2
a) %mFe=56.0,111=51%%mFe=56.0,111=51%
→%mAl=49%→%mAl=49%
b) ∑mctHCl=(2.0,1+3.0,2).36,5=29,2(g)∑mctHCl=(2.0,1+3.0,2).36,5=29,2(g)
mddHCl=29,2.100%10%=292(g)mddHCl=29,2.100%10%=292(g)
c) mH2↑=(1.0,1+1,5.0,2).2=0,8(g)mH2↑=(1.0,1+1,5.0,2).2=0,8(g)
mddsaupu=mhh+mddHCl−mH2↑=11+292−0,8=302,2(g)mddsaupu=mhh+mddHCl−mH2↑=11+292−0,8=302,2(g)
a, 4,48g
b,
Giải thích các bước giải:
mddCuSO4 = 200 . 1,12 = 224g
→ mCuSO4 = 224 . 10% = 22,4g
→ nCuSO4 = 22,4 : 160 = 0,14mol
nFe = 3,92 : 56 = 0,07 mol
Fe + CuSO4 → FeSO4 + Cu
nFe < nCuSO4 → Fe phản ứng hết, CuSO4 dư
nCu = nFe = 0,07 mol
→ mCu = 0,07 . 64 = 4,48g
Sau phản ứng thu được dung dịch gồm:
FeSO4: nFeSO4 = nFe = 0,07 mol
CuSO4 dư: nCuSO4 p.ứ = nFe = 0,07 mol → nCuSO4 dư = 0,14 - 0,07 = 0,07 mol
a, 4,48g
b,
Giải thích các bước giải:
mddCuSO4 = 200 . 1,12 = 224g
→ mCuSO4 = 224 . 10% = 22,4g
→ nCuSO4 = 22,4 : 160 = 0,14mol
nFe = 3,92 : 56 = 0,07 mol
Fe + CuSO4 → FeSO4 + Cu
nFe < nCuSO4 → Fe phản ứng hết, CuSO4 dư
nCu = nFe = 0,07 mol
→ mCu = 0,07 . 64 = 4,48g
Sau phản ứng thu được dung dịch gồm:
FeSO4: nFeSO4 = nFe = 0,07 mol
CuSO4 dư: nCuSO4 p.ứ = nFe = 0,07 mol → nCuSO4 dư = 0,14 - 0,07 = 0,07 mol
a) \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1dm^3=1l\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: x 1,5x
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}27x+24y=7,8\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\%m_{Al}=\dfrac{0,2.27.100\%}{7,8}=69,23\%;\%m_{Mg}=100-69,23=30,77\%\)
b)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,2 0,3 0,1
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,1 0,1 0,1
\(V_{ddH_2SO_4}=\dfrac{0,3+0,1}{2}=0,2\left(l\right)=200\left(ml\right)\)
\(\Rightarrow m_{ddH_2SO_4}=1,12.200=224\left(g\right)\)
c) \(C_{M_{ddAl_2\left(SO_4\right)_3}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ddMgSO_4}}=\dfrac{0,1}{0,2}=0,5M\)