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mình ghi số cân bằng thôi nhaa, 3Mg +8HNO3 -> 3(Mg(NO3)2+2NO+4H2O
b, Fe+6H2SO4 -> Fe2(SO4)3+3SO2 + 6H2O
c, 4Mg + 5H2SO4 -> 4MgSO4 + H2S + 4H2O
d, 8Al +30 HNO3 -> 8Al(NO3)3 + 3NH4NO3 + 9H2O
e, 6FeCO3 + 10H2SO4 -> 3Fe2(SO4)3 +S+ 6CO2 +10H2O
f, 8Fe3O4 +74HNO3 -> 24Fe(NO3)3 + N2O + 37H2O
g, 8Al +30HNO3 -> 8Al(NO3)3 + 3N2O + 15H2O
h,10FeSO4 + 8H2SO4 +2KMnO4 -> 5Fe2(SO4)3 + 2MnSO4 + K2SO4 +8H2O
i,2KMnO4 +16 HCl ->2 KCl + 2MnCl2 + 5Cl2 + 8H2O
j,K2Cr2O7 +14HCl -> 2KCl + 2CrCl3 + 3Cl2 + 7H2O
1) 3Mg + 8HNO3 → 3Mg(NO3)2 + 2NO + 4H2O
2) 2Fe + 6H2SO4 → Fe2(SO4)3 + 3SO2 + 6H2O
3) 4Mg + 5H2SO4 → 4MgSO4 + H2S + 4H2O
4) 8Al + 30HNO3 → 8Al(NO3)3 + 3NH4NO3 + 9H2O
5) 2FeCO3 + 4H2SO4 → Fe2(SO4)3 + SO2 + 2CO2 + 4H2O
6) 8Fe3O4 + 74HNO3 → 24Fe(NO3)3 + N2O + 37H2O
7) 8Al + 30HNO3 → 8Al(NO3)3 + 3N2O + 15H2O
8) 10FeSO4 + 8H2SO4 + 2KMnO4 → 5Fe2(SO4)3 + 2MnSO4 + K2SO4 + 8H2O
9) 2KMnO4 + 16HCl → 2KCl + 2MnCl2 + 5Cl2 + 8H2O
10) K2Cr2O7 + 14HCl → 2KCl + 2CrCl3 + 3Cl2 + 7H2O
1)
$Zn^0 \to Zn^{2+} + 2e$ x3
$N^{+5} + 3e \to N^{+2}$ x2
$3Zn + 8HNO_3 \to 3Zn(NO_3)_2 + 2NO + 4H_2O$
2)
\(Al^0 \to Al^{3+} + 3e\) x2
\(S^{+6} + 2e\to S^{+4}\) x3
$2Al + 6H_2SO_4 \to Al_2(SO_4)_3 + 3SO_2 + 6H_2O$
3)
\(Cr^{+6} + 3e \to Cr^{+3}\) x1
\(Fe^{+2} \to Fe^{+3} + 1e\) x3
$K_2Cr_2O_7 + 6FeSO_4 + 7H_2SO_4 \to 3Fe_2(SO_4)_3 + Cr_2(SO_4)_3 + K_2SO_4 + 7H_2O$
4)
\(Pb^{+4} + 2e \to Pb^{+2}\\ \) x1
\(2Cl^- \to Cl_2 + 2e\) x1
$PbO_2 + 4HCl \to PbCl_2 + Cl_2 + 2H_2O$
5)
$2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2$
6)
\((FeCu_2S_2)^0 \to Fe^{+3} + 2Cu^{+2} + 2S^{+4} + 15e\) x4
\(O_2 + 4e \to 2O^{-2}\) x15
$4FeCu_2S_2 + 15O_2 \xrightarrow{t^o} 2Fe_2O_3 + 8CuO + 8SO_2$
Câu 1:
a) 4Al + 3O2 --to--> 2Al2O3
| 2Al0 -6e --> Al2+3 | x2 |
| O20 +4e--> 2O-2 | x3 |
b) 2Fe + 6H2SO4 --> Fe2(SO4)3 + 3SO2 +6 H2O
| 2Fe0-6e-->Fe2+3 | x1 |
| S+6 +2e--> S+4 | x3 |
c) Fe3O4 + 10HNO3 --> 3Fe(NO3)3 + NO2 + 5H2O
| \(Fe_3^{+\dfrac{8}{3}}-1e->3Fe^{+3}\) | x1 |
| \(N^{+5}+1e->N^{+4}\) | x1 |
d) \(10Al+38HNO_3->10Al\left(NO_3\right)_3+2NO+3N_2O+19H_2O\)
\(\dfrac{30.n_{NO}+44.n_{N_2O}}{n_{NO}+n_{N_2O}}=19,2.2=38,4=>\dfrac{n_{NO}}{n_{N_2O}}=\dfrac{2}{3}\)
| Al0 -3e --> Al+3 | x10 |
| 38H+ + 8NO3- +30e--> 2NO + 3N2O + 19H2O | x1 |
e) \(\left(5x-2y\right)M+\left(6nx-2ny\right)HNO_3->\left(5x-2y\right)M\left(NO_3\right)_n+nN_xO_y+\left(3nx-ny\right)H_2O\)
| M0-ne--> M+n | x(5x-2y) |
| \(xN^{+5}+\left(5x-2y\right)e->N_x^{+\dfrac{2y}{x}}\) | xn |
4.MnO2+4HCl\(\rightarrow\)MnCl2+Cl2+2H2O
Mn+4 +2e \(\rightarrow\)Mn+2
2Cl- \(\rightarrow\)Cl2+2e
5.2KMnO4+16HCl\(\rightarrow\)2KCl+2MnCl2+5Cl2+8H2O
Mn+7+5e\(\rightarrow\)Mn+2
2Cl-\(\rightarrow\)Cl2+2e
6.8FeO+26HNO3\(\rightarrow\)8Fe(NO3)3+N2O+13H2O
Fe+2\(\rightarrow\)Fe+3 +1e
2N+5+8e\(\rightarrow\)2N+1
7.2KMnO4+3K2SO3+H2O\(\rightarrow\)3K2SO4+2MnO2+2KOH
S+4\(\rightarrow\)S+6 +2e
Mn+7+3e\(\rightarrow\)Mn+4
8.\(\text{2KMnO4+10FeSO4+8H2SO4}\rightarrow\text{5Fe2(SO4)3+2MnSO4+K2SO4+8H2O}\)
Mn+7 +5e\(\rightarrow\)Mn+2
Fe+2 \(\rightarrow\)Fe+3+1e
2KMnO4\(\rightarrow\)K2MnO4+O2+MnO2
4 ý cuối :
1)
Cu + 2H2SO4→ CuSO4+ SO2+2H2O
Cu0 →Cu+2 +2e║ x1
S+6+2e →S+4 ║ x1
2)
2Al+ 4H2SO4→ Al2(SO4)3+ S+ 4H2O
2Al0→2Al+3 +6e║x1
S+6 +6e→S0 ║x1
3)
4Zn +5H2SO4→ 4ZnSO4+ H2S+ 4H2O
Zn0\(\rightarrow\) Zn+2 +2e ║x4
S+6 +8e →S−2 ║x1
4)
8Fe+ 15H2SO4→ 4Fe2(SO4)3+3H2S+ 12H2O
2Fe0→ 2Fe+3+6e║x4
S+6 +8e →S−2 ║x3
6 ý đầu
1.\(\overset{-3}{4NH_2}+\overset{0}{5O_2}\rightarrow\overset{+2+6}{4NO}+\overset{-2}{6H_2O}\)
4 X \(||\) N-3 + 5e → N+2
5 X \(||\) 2O0 + 4e → 2O-2
2.\(\overset{-3}{4NH3}+\overset{0}{3O_2}\rightarrow\overset{0}{2N_2}+\overset{-2}{6H_2O}\)
2 X \(||\) 2N-3 + 6e → 2N0
3 X \(||\) 2O0 + 4e → 2O-2
3.\(\overset{0}{3Mg}+\overset{+5}{8NO_3}\rightarrow\overset{+2}{3Mg\left(NO_3\right)_2}+\overset{+2}{2NO}+\overset{ }{4H_2O}\)
3 X \(||\) Mg0 → Mg+2 + 2e
2 X \(||\) N+5 + 3e → N+2
4.\(\overset{0}{Al}+\overset{+5}{6NO_3}\rightarrow\overset{+3}{Al\left(NO_3\right)_3}+\overset{+4}{3NO_2}+\overset{ }{3H_2O}\)
1 X \(||\) Al0 → Al+3 + 3e
3 X \(||\) N+5 + 1e → N+4
5.\(\overset{0}{Zn}+\overset{+5}{4HNO_3}\rightarrow\overset{+3}{Fe\left(NO_3\right)_3}+\overset{+2}{NO}+\overset{ }{2H_2O}\)
1 X \(||\) Zn0 → Mg+2 + 2e
2 X \(||\) N+5 + 3e → N+4
6.\(\overset{0}{Fe}+\overset{+5}{4HNO_3}\rightarrow\overset{+3}{Fe\left(NO_3\right)_3}+\overset{+2}{NO}+\overset{ }{2H_2O}\)
1 X \(||\) Fe0 → Fe+3 + 3e
1 X \(||\) N+5 + 3e → N+2
3 ý cuối:
2KNO3 + 3C + S \(\rightarrow\)K2S + 3CO2 + N2
(5x-2y)Al +(18x-6y) HNO3 \(\rightarrow\) (5x-2y)Al(NO3)3 +3 NxOy + (9x-3y)H2O
2FexOy + (6x-2y)H2SO4\(\rightarrow\)xFe2(SO4)3 + (3x-2y)SO2 +(6x-2y) H2O
bạn cho nhiều vậy ai lm cho nổi ; thôi mk làm 1 câu khó nhất bn nhờ vào đó lm các câu còn lại nha .
câu 6) ta có : \(K\overset{+7}{Mn}O_4\overset{ }{+}\overset{+2}{Fe}SO_4\overset{ }{+}\overset{ }{H_2SO_4}\overset{ }{\rightarrow}\overset{+3}{Fe}_2\left(SO_4\right)_3\overset{ }{+}\overset{ }{\overset{+2}{Mn}SO_4}\overset{ }{+}\overset{ }{K_2SO_4}\overset{ }{+}\overset{ }{H_2O}\)
\(\Rightarrow\overset{+7}{Mn}\overset{ }{+}\overset{ }{5e}\overset{ }{\rightarrow}\overset{+2}{Mn}\) ; \(\overset{+2}{Fe}\overset{ }{\rightarrow}\overset{+3}{Fe}\overset{ }{+}\overset{ }{e}\) \(\Rightarrow\) hệ số giữa \(Mn\) và \(Fe\) là \(1\backslash5\)
trong đó chất khử là \(FeSO_4\) chất OXH là \(KMnO_4\) và chất môi trường là \(H_2SO_4\)
\(\Rightarrow2K\overset{+7}{Mn}O_4\overset{ }{+}10\overset{+2}{Fe}SO_4\overset{ }{+}8\overset{ }{H_2SO_4}\overset{ }{\rightarrow}5\overset{+3}{Fe}_2\left(SO_4\right)_3\overset{ }{+}2\overset{ }{\overset{+2}{Mn}SO_4}\overset{ }{+}\overset{ }{K_2SO_4}\overset{ }{+}8\overset{ }{H_2O}\)
câu 6) ta có : K+7MnO4++2FeSO4+H2SO4→+3Fe2(SO4)3++2MnSO4+K2SO4+H2OKMn+7O4+Fe+2SO4+H2SO4→Fe+32(SO4)3+Mn+2SO4+K2SO4+H2O
⇒+7Mn+5e→+2Mn⇒Mn+7+5e→Mn+2 ; +2Fe→+3Fe+eFe+2→Fe+3+e ⇒⇒ hệ số giữa MnMn và FeFe là 1∖51∖5
trong đó chất khử là FeSO4FeSO4 chất OXH là KMnO4KMnO4 và chất môi trường là H2SO4H2SO4
⇒2K+7MnO4+10+2FeSO4+8H2SO4→5+3Fe2(SO4)3+2+2MnSO4+K2SO4+8H2O
h) 3Cu + 8HNO3 --> 3Cu(NO3)2 + 2NO + 4H2O
i) 4Zn + 10HNO3 --> 4Zn(NO3)2 + N2O + 5H2O
j) 2Al + 6H2SO4 --> Al2(SO4)3 + 3SO2 + 6H2O
k) 3Fe3O4 + 28HNO3 --> 9Fe(NO3)3 + NO + 14H2O
l) 2KMnO4 + 10FeSO4 + 8H2SO4 --> 2MnSO4 + 5Fe2(SO4)3 + K2SO4 + 8H2O
m) K2Cr2O7 + 14HCl --> 2KCl + 2CrCl3 + 3Cl2 + 7H2O