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\(a) n_{Fe_2O_3} = \dfrac{16.75\%}{160} = 0,075(mol)\\ n_{CuO} = \dfrac{16.25\%}{80} = 0,05(mol)\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{Fe} = 2n_{Fe_2O_3} = 0,15(mol) \Rightarrow m_{Fe} = 0,15.56 = 8,4(gam)\\ n_{Cu} = n_{CuO} = 0,05(mol) \Rightarrow m_{Cu} = 0,05.64 = 3,2(gam)\\ b) n_{H_2} = 3n_{Fe_2O_3} + n_{CuO} = 0,075.3 + 0,05 = 0,275(mol)\\ V_{H_2} = 0,275.22,4 = 6,16(lít)\)
\(m_{Fe_2O_3}=16\cdot75\%=12\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{12}{160}=0.075\left(mol\right)\)
\(n_{CuO}=16\cdot25\%=4\left(g\right)\)
\(n_{CuO}=\dfrac{4}{80}=0.05\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(n_{H_2}=3\cdot0.075+0.05=0.275\left(mol\right)\)
a,\(m_{Fe_2O_3}=16.75\%=12\left(g\right)\Rightarrow n_{Fe_2O_3}=\dfrac{12}{160}=0,075\left(mol\right)\)
\(m_{CuO}=16-12=4\left(g\right)\Rightarrow n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,075 0,225 0,15
PTHH: CuO + H2 → Cu + H2O
Mol: 0,05 0,05 0,05
\(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right);m_{Cu}=0,05.64=3,2\left(g\right)\)
b,\(n_{H_2}=0,225+0,05=0,275\left(mol\right)\)
a) \(m_{CuO}=\dfrac{20.40}{100}=8\left(g\right)\) => \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(m_{Fe_2O_3}=20-8=12\left(g\right)\) => \(n_{Fe_2O_3}=\dfrac{12}{160}=0,075\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1--->0,1------>0,1
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,075--->0,225----->0,15
=> mCu = 0,1.64 = 6,4 (g)
=> mFe = 0,15.56 = 8,4 (g)
b) \(V_{H_2}=\left(0,1+0,225\right).22,4=7,28\left(l\right)\)
\(Tacó:m_{Fe_2O_3}:m_{CuO}=3:2\\ m_{Fe_2O_3}+m_{CuO}=40\\ \Rightarrow m_{Fe_2O_3}=24\left(g\right)\Rightarrow n_{Fe_2O_3}=0,15\left(mol\right)\\ \Rightarrow m_{CuO}=16\left(g\right)\Rightarrow n_{CuO}=0,2\left(mol\right)\\ Fe_2O_3+3H_2-^{t^o}\rightarrow2Fe+3H_2O\left(1\right)\\ CuO+H_2O-^{t^o}\rightarrow Cu+H_2O\left(2\right)\\TheoPT\left(1\right): n_{Fe}=2n_{Fe_2O_3}=0,3\left(mol\right)\\ \Rightarrow m_{Fe}=16,8\left(g\right)\\TheoPT\left(2\right): n_{Cu}=n_{CuO}=0,2\left(mol\right)\\ \Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
a)
\(m_{CuO}=\dfrac{32.40}{100}=12,8\left(g\right)\) => \(n_{CuO}=\dfrac{12,8}{80}=0,16\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{32-12,8}{160}=0,12\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,16->0,16---->0,16
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,12-->0,36----->0,24
=> \(V_{H_2}=\left(0,16+0,36\right).22,4=11,648\left(l\right)\)
b)
mCu = 0,16.64 =10,24 (g)
mFe = 0,24.56 = 13,44 (g)
c)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
Xét tỉ lệ: \(\dfrac{0,24}{1}< \dfrac{0,5}{2}\) => HCl dư, Fe hết
PTHH: Fe + 2HCl --> FeCl2 + H2
0,24------------------->0,24
=> \(V_{H_2}=0,24.22,4=5,376\left(l\right)\)
nH2SO4 = 14,7: 27=0,54(mol)
PTHH : 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
theo pt , nH2 = nH2SO4=0,54(mol)
=> VH2(đktc) = 0,54. 22,4=12,096 (l)
b theo pt nAl = 3/2. nH2=0,36 (mol)
=> mAl = 0,36.27 =9,72(g)
c)theo pt n Al2(SO4)3 = 1/2nAl = 0,18(mol)
=>mAl2(SO4)3= 0,18.342=61,56(g)
nH2= 13,44 : 22,4 = 0,6 (mol)
pthh : 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4 <------------------- 0,2<-----------<0,6 (mol)
mAl = 0,4 . 27 = 10,8 ( g)
mAl2(SO4)3= 0,2 . 342 = 68,4 (g)
nFe3O4 = 46,4 : 232 = 0,2 (mol)
pthh : Fe3O4 + 4H2 -t--> 3Fe + 4H2O
LTL :
0,2/1 > 0,6 /4
=> Fe3O4 du
theo pt nFe=3/4 nH2 = ,45 (mol)
=> mFe= 0,45 . 56= 25,2 (g)
\(a,n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow2Al_2\left(SO_4\right)_3+3H_2\uparrow\\ Theo.pt:n_{Al}=n_{Al_2\left(SO_4\right)_3}=\dfrac{2}{3}n_{H_2SO_4}=\dfrac{2}{3}.0,6=0,4\left(mol\right)\\ m_{Al}=0,4.27=10,8\left(g\right)\\ b,m_{Al_2\left(SO_4\right)_3}=0,4.342=136,8\left(g\right)\\ c,n_{Fe_3O_4}=\dfrac{46,4}{232}=0,2\left(mol\right)\\ PTHH:Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\\ LTL:\dfrac{0,2}{1}>\dfrac{0,6}{4}\Rightarrow Fe_3O_4.du\\ n_{Fe}=\dfrac{3}{4}n_{H_2}=\dfrac{3}{4}.0,4=0,3\left(mol\right)\\ m_{Fe}=0,3.56=16,8\left(g\right)\)
a, mFe2O3 = 32 . 75% = 24 (g)
nFe2O3 = 24/160 = 0,15 (mol)
mCuO = 32 - 24 = 8 (g)
nCuO = 8/80 = 0,1 (mol)
PTHH:
Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O
0,15 ---> 0,45 ---> 0,3
CuO + H2 -> (t°) Cu + H2O
0,1 ---> 0,1 ---> 0,1
mFe = 0,3 . 56 = 16,8 (g)
mCu = 64 . 0,1 = 6,4 (g)
b, nH2 = 0,1 + 0,45 = 0,55 (mol)
VH2 = 0,55 . 22,4 = 12,32 (l)
c, PTHH:
2Al + 6HCl -> 2AlCl3 + 3H2
11/30 <--- 1,1 <--- 11/30 <--- 0,55
mAl = 11/30 . 27 = 9,9 (g)
mHCl = 1,1 . 36,5 = 40,15 (g)