Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Bài 1:
a) 2CuFeS2 + \(\dfrac{13}{2}\)O2 --to--> 2CuO + Fe2O3 + 4SO2
b) \(n_{CuFeS_2}=\dfrac{3,68}{184}=0,02\left(mol\right)\)
\(n_{O_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,02}{2}< \dfrac{0,075}{\dfrac{13}{2}}\) => CuFeS2 hết, O2 dư
PTHH: 2CuFeS2 + \(\dfrac{13}{2}\)O2 --to--> 2CuO + Fe2O3 + 4SO2
0,02----->0,065------->0,02---->0,01---->0,04
=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=0,075-0,065=0,01\left(mol\right)\\n_{SO_2}=0,04\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{0,01}{0,01+0,04}.100\%=20\%\\\%V_{SO_2}=\dfrac{0,04}{0,01+0,04}.100\%=80\%\end{matrix}\right.\)
- \(\left\{{}\begin{matrix}m_{CuO}=0,02.80=1,6\left(g\right)\\m_{Fe_2O_3}=0,01.160=1,6\left(g\right)\end{matrix}\right.\)
=> mrắn = 1,6 + 1,6 = 3,2 (g)
Bài 2:
a)
2CuS + 3O2 --to--> 2CuO + 2SO2
4FeS + 7O2 --to--> 2Fe2O3 + 4SO2
b) Gọi số mol CuS, FeS là a, b (mol)
=> 96a + 88b = 22,8 (1)
\(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
=> a + b = 0,25 (2)
(1)(2) => a = 0,1; b = 0,15
=> \(\left\{{}\begin{matrix}n_{CuO}=0,1\left(mol\right)\\n_{Fe_2O_3}=0,075\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,1.80}{0,1.80+0,075.160}.100\%=40\%\\\%m_{Fe_2O_3}=\dfrac{0,075.160}{0,1.80+0,075.160}.100\%=60\%\end{matrix}\right.\)
a, Theo giả thiết ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(4P+5O_2--t^o->2P_2O_5\)
Ta có: \(n_{O_2}=\dfrac{5}{4}.n_P=0,125\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=0,125.22,4=2,8\left(l\right)\)
b, Theo giả thiết ta có: \(n_{CH_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(CH_4+2O_2--t^o->CO_2+2H_2O\)
Ta có: \(n_{O_2}=2.n_{CH_4}=0,1\left(mol\right)\Rightarrow V_{O_2\left(đktc\right)}=2,24\left(l\right)\)
\(n_S=\dfrac{3.2}{32}=0.1\left(mol\right)\)
\(n_{O_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(0.05.0.05...0.05\)
\(\Rightarrow Sdư\)
\(V_{SO_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(b.\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(0.1..0.1\)
\(V_{kk}=5V_{O_2}=5\cdot0.1\cdot22.4=11.2\left(l\right)\)
a, PT: \(S+O_2\underrightarrow{t^o}SO_2\)
Ta có: \(n_S=\dfrac{3,2}{32}=0,1\left(mol\right)\)
\(n_{O_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được S dư.
Theo PT: \(n_{SO_2}=n_{O_2}=0,05\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
b, Theo PT: \(n_{O_2}=n_S=0,1\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=2,24.5=11,2\left(l\right)\)
\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)
\(4........5\)
\(0.2.........0.4\)
Lập tỉ lệ : \(\dfrac{0.2}{4}< \dfrac{0.4}{5}\Rightarrow O_2dư\)
\(n_{P_2O_5}=0.2\cdot\dfrac{2}{4}=0.1\left(mol\right)\)
\(m_{P_2O_5}=0.1\cdot142=14.2\left(g\right)\)
\(m_{P_2O_5\left(tt\right)}=14.2\cdot80\%=11.36\left(g\right)\)
nFe = 16.8/56 = 0.3 (mol)
3Fe + 2O2 -to-> Fe3O4
0.3......0.2...........0.1
VO2 = 0.2*22.4 = 4.48 (l)
mFe3O4 = 0.1*232 = 23.2 (g)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -t°-> 2P2O5
0,1---> 0,125--->0,05
VO2 = 0,125 . 22,4 = 2,8 (l)
mP2O5 = 0,05 . 142 = 7,1 (g)
\(n_P=\dfrac{3,1}{31}=0,1mol\)
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
0,1 0,125 0,05
\(V_{O_2}=0,125\cdot22,4=2,8l\)
\(m_{P_2O_5}=0,05\cdot142=7,1g\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(2CuFeS_2+\frac{13}{2}O_2\underrightarrow{^{to}}2CuO+Fe_2O_3+4SO_2\)
\(\)b, Câu b mình đổi thành "% khối lượng chất rắn và V khí" nha.
\(n_{O2}=0,075\left(mol\right)\)
\(\Rightarrow n_{SO2}=\frac{3}{65}\left(mol\right)\)
\(\Rightarrow V_{SO2}=1,034\left(l\right)\)
\(n_{CuO}=\frac{3}{130}\left(mol\right)\Rightarrow m_{CuO}=1,85\left(g\right)\)
\(n_{Fe2O3}=\frac{3}{260}\left(mol\right)\Rightarrow m_{Fe2O3}=1,85\left(g\right)\)
\(\Rightarrow\%m_{CuO}=\%m_{Fe2O3}=50\%\)