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a, \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)
b, \(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
Theo PT: \(n_{CuCl_2}=n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,125\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)
c, \(C_{M_{CuCl_2}}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)
\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)
PTHH:
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,125 0,25 0,125 0,25
\(m_{Cu\left(OH\right)_2}=0,125.98=12,25\left(g\right)\)
\(C_{M\left(CuCl_2\right)}=\dfrac{0,125}{0,1}=1,25\left(M\right)\)
\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,095 0,19 0,095 0,095
\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)
0,095 0,095
\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)
\(a,2NaOH+MgSO_4\rightarrow Mg\left(OH\right)_2+Na_2SO_4\\ n_{NaOH}=0,5.1=0,5\left(mol\right)\\ b,n_{Mg\left(OH\right)_2}=\dfrac{0,5}{2}=0,25\left(mol\right)=n_{Na_2SO_4}\\ m_{kt}=m_{Mg\left(OH\right)_2}=58.0,25=14,5\left(g\right)\\ c,V_{ddX}=V_{ddNaOH}+V_{ddMgSO_4}=0,5+0,5=1\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,25}{1}=0,25\left(M\right)\)
a)\(n_{CuSO_4}=0,4.0,5=0,2\left(mol\right)\)
\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
Mol: 0,2 0,4 0,2
⇒ \(m_{Cu\left(OH\right)_2}=0,2.98=19,6\left(g\right)\)
b)\(C_{M\left(ddNaOH\right)}=\dfrac{0,4}{0,3}=1,3\left(M\right)\)
c)\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
Mol: 0,2 0,2
=> mCuO = 0,2.80 = 16 (g)
PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Ta có: \(n_{CuCl_2}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}\\n_{NaOH}=0,4\left(mol\right)=n_{NaCl}\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu\left(OH\right)_2}=0,2\cdot98=19,6\left(g\right)\\m_{CuO}=0,2\cdot80=16\left(g\right)\\m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\\C\%_{NaOH}=\dfrac{0,4\cdot40}{200}\cdot100\%=8\%\end{matrix}\right.\)
bạn xem lại xem 13.5(g) hay 13.8g nhé ^^ ,cho tròn số ý mà
CuCl2+2NaOH->Cu(OH)2+2NaCl
nCuCl2=13.5:138=0.1(mol)
nNaOH=20:40=0.5(mol)
theo pthh:nNaOH=2nCuCl2
theo bài ra,nNaOH=5 nCuCl2->NaOH dư tính theo CuCl2
theo pthh,nCu(OH)2=nCuCl2->nCu(OH)2=0.1(mol)
mCu(OH)2=0.1*98=9.8(g)
b)PTHH:Cu(OH)2+2HCl->CuCl2+2H2O
theo pthh:nHCl=2nCu(OH)2->nHCl=0.1*2=0.2(mol)
mHCl=0.2*36.5=7.3(g)
mDD HCl=7.3*100:10=73(g)
\(a,PTHH:CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+2NaCl\\ Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\)
Hiện tượng: Dung dịch màu xanh nhạt dần, xuất hiện kết tủa màu xanh lơ
Phản ứng phân hủy Cu(OH)2 sinh ra chất rắn CuO màu đen và nước
\(b,n_{CuCl_2}=\dfrac{13,5}{135}=0,1\left(mol\right)\\ m_{NaOH}=\dfrac{200\cdot2,5\%}{100\%}=5\left(g\right)\\ \Rightarrow n_{NaOH}=\dfrac{5}{40}=0,125\left(mol\right)\)
Vì \(\dfrac{n_{CuCl_2}}{1}>\dfrac{n_{NaOH}}{2}\) nên CuCl2 dư
\(\Rightarrow\dfrac{1}{2}n_{NaOH}=n_{Cu\left(OH\right)_2}=n_{CuO}=0,0625\left(mol\right)\\ \Rightarrow m=m_{CuO}=0,0625\cdot80=5\left(g\right)\)
\(c,n_{NaCl}=n_{NaOH}=0,125\left(mol\right)\\ \Rightarrow m_{NaCl}=0,125\cdot58,5=7,3125\left(g\right)\\ m_{Cu\left(OH\right)_2}=0,0625\cdot98=6,125\left(g\right)\\ \Rightarrow m_{dd_{Cu\left(OH\right)_2}}=13,5+200-7,3125=206,1875\left(g\right)\\ \Rightarrow C\%_{Cu\left(OH\right)_2}=\dfrac{6,125}{206,1875}\cdot100\%\approx2,97\%\)
a, \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
b, \(m_{CuSO_4}=250.16\%=40\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{40}{160}=0,25\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,25\left(mol\right)\)
\(\Rightarrow a=m_{CuO}=0,25.80=20\left(g\right)\)
c, Ta có: m dd sau pư = m dd NaOH + m dd CuSO4 - mCu(OH)2 = 200 + 250 - 0,25.98 = 425,5 (g)
\(m_{NaOH}=\dfrac{100\cdot10\%}{100\%}=10g\) \(\Rightarrow n_{NaOH}=0,25mol\)
\(ZnCl_2+2NaOH\rightarrow Zn\left(OH\right)_2+2NaCl\)
0,025 0,05 0,025
\(Zn\left(OH\right)_2\underrightarrow{t^o}ZnO+H_2O\)
0,025 0,025
\(m=m_{ZnO}=0,025\cdot\left(65+16\right)=2,025g\)
\(C_{M_{ZnCl_2}}=\dfrac{0,025}{\dfrac{500}{1000}}=0,05M\)
\(n_{CuSO_4}=\dfrac{20}{160}=0,125(mol)\\ a,CuSO_4+2NaOH\to Cu(OH)_2\downarrow+2NaCl\\ \Rightarrow n_{NaOH}=0,25(mol)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{0,25}{0,2}=1,25M\\ b,n_{Cu(OH)_2}=0,125(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,125.98=12,25(g)\\ c,Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=0,125(mol)\\ \Rightarrow m_{CuO}=0,125.80=10(g)\)