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\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right);n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\ PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,25}{1}\Rightarrow Fe.dư\\ n_{H_2}=n_{Fe\left(p.ứ\right)}=n_{H_2SO_4}=0,25\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b,n_{Fe\left(dư\right)}=0,4-0,25=0,15\left(g\right)\\ m_{Fe\left(dư\right)}=0,14.56=8,4\left(g\right)\)
a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,1.98=9,8\left(g\right)\)
b, \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\), ta được CuO dư.
Theo PT: \(n_{Cu}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
a, Ta có: \(n_{Zn}=\dfrac{0,65}{65}=0,01\left(mol\right)\)
\(n_{HCl}=\dfrac{2,3}{36,5}=\dfrac{23}{365}\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,01}{1}< \dfrac{\dfrac{23}{365}}{2}\), ta được HCl dư.
Theo PT: \(n_{HCl\left(pư\right)}=2n_{Zn}=0,02\left(mol\right)\)
\(\Rightarrow n_{HCl\left(dư\right)}=\dfrac{23}{365}-0,02=\dfrac{157}{3650}\left(mol\right)\)
\(\Rightarrow m_{HCl\left(dư\right)}=\dfrac{157}{3650}.36,5=1,57\left(g\right)\)
b, Theo PT: \(n_{H_2}=n_{Zn}=0,01\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,01.22,4=0,224\left(l\right)\)
nZn=0.01 (mol)
nHCL=0.06 (mol)
pthh: Zn + 2HCL -> ZnCL2 +H2
PT: 1 2 1 1
ĐB: 0.01 0.06 / /
pứ: 0.01 0.02 0.01 0.01
spu: 0 0.04 0.01 0.01
a)vậy chất dư spu là HCL
-> mHCL = 1.46 (g)
b) V H2 đktc = 0.224 (L)
nFe=11,2/56=0,2 mol
nH2SO4=24,5/98=0,25
PTPƯ: Fe + H2SO4 ---> FeSO4 + H2
0,2 mol ----> 0,2 mol --------------------> 0,2 mol
Ta có Fe:H2SO4=0,2/1<0,25/1 (nên H2SO4 dư)
a, mH2SO4=(0,25-0,2).98=4,9 g
b, VH2=0,2.22,4=4,48 l
PTHH: \(Fe+H_2SO_{4\left(l\right)}\rightarrow FeSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Sắt còn dư, Axit p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,25\left(mol\right)\\n_{Fe\left(dư\right)}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,25\cdot22,4=5,6\left(l\right)\\m_{Fe\left(dư\right)}=0,15\cdot56=8,4\left(g\right)\end{matrix}\right.\)
\(n_{Zn}=\dfrac{1,625}{65}=0,025mol\)
\(n_{HCl}=\dfrac{3,65}{36,5}=0,1mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,025 < 0,1 ( mol )
0,025 0,05 0,025 0,025 ( mol )
\(V_{H_2}=0,025.22,4=0,56l\)
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,1-0,05\right).36,5=1,825g\)
\(m_{ZnCl_2}=0,025.136=3,4g\)
huhu cảm ơn bạn đề dài quá nên đưa lên đây làm giúp
Zn+H2SO4->ZnSO4+H2
0,05-------------------------0,05
n Zn=\(\dfrac{4}{65}\) mol
n H2SO4=\(\dfrac{4,9}{98}\)=0,05 mol
=>Zn dư
m Zn=(\(\dfrac{4}{65}\)-0,05).65=0,75 g
VH2=0,05.22,4=1,12l