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Câu 3 :
\(m_{ct}=\dfrac{10.80}{100}=8\left(g\right)\)
\(n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
a) Hiện tượng : Xuất hiện kết tủa trắng
Pt : \(2NaOH+MgSO_4\rightarrow Na_2SO_4+Mg\left(OH\right)_2|\)
2 1 1 1
0,2 0,1 0,1 0,1
\(n_{Mg\left(OH\right)2}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
⇒ \(m_{Mg\left(OH\right)2}=0,1.58=5,8\left(g\right)\)
b) \(n_{MgSO4}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
\(m_{MgSO4}=0,1.120=12\left(g\right)\)
\(m_{ddMgSO}=\dfrac{12.100}{10}=120\left(g\right)\)
c) \(n_{Na2SO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{Na2SO4}=0,1.142=14,2\left(g\right)\)
\(m_{ddspu}=80+120-5,8=194,2\left(g\right)\)
\(C_{Na2SO4}=\dfrac{14,2.100}{194,2}=7,31\)0/0
Chúc bạn học tốt
Câu 4 :
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2|\)
1 1 1 1
0,2 0,2
\(n_{H2SO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(m_{H2SO4}=0,2.98=19,6\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{19,6.100}{20}=98\left(g\right)\)
\(V_{ddH2SO4}=\dfrac{98}{1,2}\simeq81,67\left(ml\right)\)
Chúc bạn học tốt
\(n_{CuCl_2}=\dfrac{60,75}{135}=0,45mol\\ a)CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
0,45 0,9 0,45 0,9
\(b)m_X=m_{Cu\left(OH\right)_2}=0,45.81=36,45g\\
c)m_{ddNaOH}=\dfrac{0,9.40}{15\%}\cdot100\%=240g\\
d)m_{ddNaCl}=60,75+240-36,45=264,3g\\
C_{\%NaCl}=\dfrac{0,9.58,5}{264,3}\cdot100\%=19,92\%\\
e)n_{H_2SO_4}=\dfrac{245.20\%}{100\%.98}=0,5mol\\
H_2SO_4+Cu\left(OH\right)_2\rightarrow CuSO_4+2H_2O\\
\Rightarrow\dfrac{0,5}{1}>\dfrac{0,45}{1}\Rightarrow H_2SO_4.dư\)
\(\Rightarrow\)Dung dịch acid \(H_2SO_4\) làm tan hết chất X\(\left(Cu\left(OH\right)_2\right)\)
a)PTHH: ZnCl2+2KOH---->Zn(OH)2+2KCl
b)
mZnCl2=204.10100=20,4(g)ZnCl2=204.10100=20,4(g)
nZnCl2=20,4136=0,15(mol)ZnCl2=20,4136=0,15(mol)
nKOH=112.20%56=0,4(mol)KOH=112.20%56=0,4(mol)
=> 0,15/1 < 0,4/1=> KOH dư
Theo pthh, ta có :
nCu(OH)2=nZnCl2=0,15(mol)Cu(OH)2=nZnCl2=0,15(mol)
mCu(OH)2=0,15.98=14,7(g)Cu(OH)2=0,15.98=14,7(g)
c) m dd sau pư=204+112=316(g)
Theo pthh
nKOH=2nZnCl2=0,3(mol)KOH=2nZnCl2=0,3(mol)
C% KOH=0,3.56326.100%=5,32%0,3.56326.100%=5,32%
nKCl=2nZnCl2=0,3(mol)KCl=2nZnCl2=0,3(mol)
C% KCl=0,3.74,5316.100%=7,07%
\(m_{FeCl_3}=\dfrac{100\cdot13\%}{100\%}=13\left(g\right)\\ \Rightarrow n_{FeCl_3}=\dfrac{13}{162,5}=0,08\left(mol\right)\\ a,\text{Hiện tượng: Màu vàng nâu của dung dịch }FeCl_3\text{ nhạt dần và xuất hiện kết tủa màu nâu đỏ }Fe\left(OH\right)_3\\ PTHH:3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3\downarrow+3NaCl\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,24\left(mol\right)\\ \Rightarrow m_{CT_{NaOH}}=0,24\cdot40=9,6\left(g\right)\\ \Rightarrow m_{dd_{NaOH}}=\dfrac{9,6\cdot100\%}{10\%}=96\left(g\right)\)\(b,n_{Fe\left(OH\right)_3}=0,08\left(mol\right);n_{NaCl}=0,24\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}m_{Fe\left(OH\right)_3}=0,08\cdot107=8,56\left(g\right)\\m_{NaCl}=0,24\cdot58,5=14,04\left(g\right)\end{matrix}\right.\\ \Rightarrow m_{dd_{NaCl}}=96+100-8,56=187,44\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{14,04}{187,44}\cdot100\%\approx7,49\%\)
\(n_{Fe_2O_3}=\dfrac{20}{160}=0,125\left(mol\right)\)
PTHH:
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,125 0,375 0,125 0,375
\(m_{ddH_2SO_4}=\dfrac{0,375.98.100}{25}=147\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,125.406}{20+147}\approx30,39\%\)
\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
