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a) Zn + 2HCl → ZnCl2 + H2
nZn = 9,75 : 65 = 0,15 mol
Theo ptpư
nH2 = nZn = 0,15 mol
VH2 = 0,15 . 22,4 = 3,36 lit
b) CuO + H2 →H2O + Cu
nCuO = 20 : 80 = 0,25 mol
nCuO p/ư = nH2 = 0,15 mol
=> Dư CuO
nCu thu được= nH2 = 0,15 mol
mCu= 0,15 x 64 = 9,6 gam
\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 0,25.........0,5.........0,25.......0,25\left(mol\right)\\ a.V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b.m_{HCl}=0,5.36,5=18,25\left(g\right)\\ c.n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\ Fe_2O_3+3H_2\underrightarrow{^{to}}2Fe+3H_2O\\ Vì:\dfrac{0,25}{3}< \dfrac{0,1}{1}\\ \Rightarrow Fe_2O_3dư\\ n_{Fe}=\dfrac{2}{3}.0,25=\dfrac{1}{6}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{1}{6}.56\approx9,333\left(g\right)\)
a,\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,25 0,5 0,25
\(\Rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
b,\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
c,\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,25 \(\dfrac{1}{6}\)
Ta có: \(\dfrac{0,1}{1}>\dfrac{0,25}{3}\)⇒ Fe2O3 dư, H2 hết
\(m_{Fe}=\dfrac{1}{6}.56=9,33\left(g\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ n_{H_2}=n_{Fe}=0,1\left(mol\right)\\ n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\ CuO+H_2-^{t^o}\text{ }\rightarrow Cu+H_2O\\ Lậptỉlệ:\dfrac{0,2}{1}>\dfrac{0,1}{1}\\ \Rightarrow CuOdư\\n_{H_2O}=n_{H_2}=0,1\left(mol\right)\\ BTKL:m_{CuO}+m_{H_2}=m_{cr}+m_{H_2O}\\ \Leftrightarrow16+0,1.2=m_{cr}+0,1.18\\ \Rightarrow m_{cr}=14,4\left(g\right)\)
a)
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{Al} = \dfrac{10,8}{27} = 0,4(mol)$
Theo PTHH : $n_{H_2} = \dfrac{3}{2}n_{Al} = 0,6(mol)$
$V_{H_2} = 0,6.22,4 = 13,44(lít)$
b)
$Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O$
Theo PTHH : $n_{Fe} = \dfrac{2}{3}n_{H_2} = 0,4(mol)$
$m_{Fe} = 0,4.56 = 22,4(gam)$
a) PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
a_____________________\(\dfrac{3}{2}\)a (mol)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
b____________________b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}27a+56b=11\\\dfrac{3}{2}a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{11}\cdot100\%\approx49,09\%\\\%m_{Fe}=50,91\%\end{matrix}\right.\)
b) PTHH: \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\n_{H_2}=\dfrac{3}{2}a+b=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) H2 còn dư, tính theo CuO
\(\Rightarrow n_{Cu}=0,2\left(mol\right)\) \(\Rightarrow m_{Cu}=0,2\cdot64=12,8\left(g\right)\)
Gọi n Al = a ( mol ) , n Fe = b ( mol )
Có: n H2 = 0,4 ( mol )
PTHH
2AL + 6HCL ===> 2ALCL3 + 3H2
a--------------------------------------a
Fe + 2HCl ====> FeCL2 + H2
b------------------------------------b
Ta có hpt:
\(\left\{{}\begin{matrix}27a+56b=11\\1,5a+b=0,4\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> m AL = 5,4 ( g ) ; m Fe = 5,6 ( g )
b) Có : n CuO = 0,2 ( mol )
PTHH:
CuO + H2 ====> Cu +H2O
0,2----0,2-----------0,2
theo pthh: n Cu = 0,2 ( mol ) => m Cu = 12,8 ( g )
\(n_{Cu}=\dfrac{3,84}{64}=0,06\left(mol\right)\)
CTHH: FexOy
PTHH: Fe + Cu(NO3)2 --> Fe(NO3)2 + Cu
_____0,06<--------------------------------0,06
FexOy + yH2 --to--> xFe + yH2O
\(\dfrac{0,06}{x}\)<----------------0,06
=> \(M_{Fe_xO_y}=\dfrac{4,64}{\dfrac{0,06}{x}}=\dfrac{232}{3}.x\left(g/mol\right)\)
=> x = 3 => y = 4
=> CTHH: Fe3O4
đề bài là j vậy bạn