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\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,3 0,3 ( mol )
\(m_{CuO}=0,3.80=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\)
\(\%m_{CuO}=\dfrac{24}{40}.100=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,3
\(\Rightarrow n_{CuO}=0,3\Rightarrow m_{CuO}=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\Rightarrow n_{Fe_2O_3}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\%m_{CuO}=\dfrac{24}{40}\cdot100\%=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
Gọi \(\left\{{}\begin{matrix}n_{Al}=x\\n_{Cu}=y\end{matrix}\right.\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
x 1/2 x ( mol )
\(2Cu+O_2\rightarrow\left(t^o\right)2CuO\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}27x+64y=18,2\\51x+80y=26,2\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,2\end{matrix}\right.\)
\(\Rightarrow m_{Al}=0,2.27=5,4g\)
\(\Rightarrow m_{Cu}=0,2.64=12,8\)
\(\%m_{Al}=\dfrac{5,4}{18,2}.100=29,67\%\)
\(\%m_{Cu}=100\%-29,67=70,33\%\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,1 ( mol )
( Cu không tác dụng với dd axit HCl )
\(m_{Fe}=0,1.56=5,6g\)
\(\rightarrow m_{Cu}=12-5,6=6,4g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{5,6}{12}.100=46,66\%\\\%m_{Cu}=100\%-46,66\%=53,34\%\end{matrix}\right.\)
a)PTHH: CuO + H2\(\rightarrow\) Cu + H2O (1)
Fe2O3 + 3H2 \(\rightarrow\)2Fe + 3H2O(2)
b) nH2= \(\dfrac{5,6}{22,4}\)=0,25mol
Gọi nH2(PT1)=a
nH2(PT2)=b
=>a+b=0,25mol
<=> a=0,25-b
Theo PT1: nCuO=nH2(PT1)=a
Theo PT2: nFe2O3=1/3nH2(PT2)=1/3b
Có mCuO+mFe2O3=16g
80a+160.1/3b=16
80(0,25-b)+160/3b=16
20-80b+160/3b=16
b=0,03mol
nFe2O3=1/3.0,15=0,03mol
mFe2O3=0,03.160=8g
%mFe2O3=\(\dfrac{8}{16}\).100%=50%
%mCuO=100%-50%=50%
c)nCuO=0,25-0,15=0,1mol
Theo PT1: nCu=nCuO=0,1mol
=>mCu=0,1.64=6,4g
Theo PT2: nFe=2nFe2O3=0,06mol
mFe=0,06.56=3,36g
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05mol\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,05 0,05 ( mol )
( Cu không tác dụng với dd axit H2SO4 loãng )
\(m_{Mg}=0,05.24=1,2g\)
\(\rightarrow m_{Cu}=8-1,2=6,8g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{1,2}{8}.200=15\%\\\%m_{Cu}=100\%-15\%=85\%\end{matrix}\right.\)
$n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)$
$n_{Fe_2O_3} = \dfrac{40}{160} = 0,25(mol)$
$Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O$
$n_{Fe_2O_3} : 1 = 0,25 > n_{H_2} : 3 = 0,1$ nên $Fe_2O_3$ dư
$n_{Fe} = \dfrac{2}{3}n_{H_2} = 0,2(mol)$
$n_{Fe_2O_3\ pư} = \dfrac{1}{3}n_{H_2} = 0,1(mol)$
$n_{Fe_2O_3\ dư} = 0,25 - 0,1 = 0,15(mol)$
Suy ra :
$\%m_{Fe} = \dfrac{0,1.56}{0,1.56 + 0,15.160}.100\% = 18,92\%$
Gọi số mol Fe3O4, PbO là a, b
=> 232a + 223b= 78,95
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
a------>4a---------->3a
PbO + H2 --to--> Pb + H2O
b--->b--------->b
=> 56.3a + 207.b = 68,55
=> a = 0,1; b = 0,25
=> \(\left\{{}\begin{matrix}\%Fe_3O_4=\dfrac{232.0,1}{78,95}.100\%=29,386\%\\\%PbO=\dfrac{0,25.223}{78,95}.100\%=70,614\%\end{matrix}\right.\)
nH2 = 4a + b = 0,65 (mol)
=> VH2 = 0,65.22,4 = 14,56 (l)
